March 7, 2011 Niles Lawrence Peroxides o Contains the R-O-O-R’ functional group o Breaks down spontaneously to form the ether and oxygen gas Naming o List the “yl” forms of the hydrocarbon chains in alpha order, followed by the word peroxide H3C CH3 O O O CH3 CH3 O CH3 Ethylphenyl peroxide diisopropyl peroixde Aldehydes and Ketones o Both contain carbonyl group (C=O) o Aldehydes- carbonyl is attached to end carbon O H3C butanal o Ketones carbonyl is attached to carbon not on the end O H3C CH3 butanone Physical Properties o Carbonyl group is polar and contains dipole-dipole forces o Increased intermolecular forces lead to higher melting and boiling points of aldehydes and keytones than the corresponding hydrocarbon Naming Aldehyde 1. Take the longest chain containing the carbonyl group, remove the “e” and add “al” as ending 2. Any substituents are numbered using the lowest sum CH3 O O CH2 Iupac: methanal Common: formaldehyde CH3 3-chloro-2-ethylpent-trans-2-enal Naming Ketones 1. Take the longest chain containing the carbonyl group, remove the “e” and add “one” as the ending 2. If necessary indicate the position of the carbonyl using the lowest numerical coefficient 3. Any substituents are numbered so the sum is the lowest H3C F CH3 OH H3C O O H3C CH3 I: propanone C: acetone H3C CH3 H3C O I: butanedione C: butadione cis-2-fluoro-4-isopropyloct-4-ene-5-ol-3-one Common Names O O O H CH2 Iupac: methanal Common: formaldehyde CH3 I: ethanal C: acetaldehyde H3C CH3 I: propanone C: acetone O H I: phenyl methanal C: benzaldehyde Carboxylic Acids o Contains the carboxyl functional group o Since it is polar it contains dipole-dipole forces and are able to hydrogen bond o Will have higher melting and boiling points and will be soluble in water o Weak acids that ionize slightly in water o The acidic hydrogen on the hydroxide leaves when the acid is ionized Naming Carboxylic Acids 1. Identify the longest chain containing the carboxyl group, remove the “e” and add “oic” acid. O O O H H3C OH I: methanoic acid C: formic acid OH OH I: ethanoic acid C: acetic acid I: phenylmethanoic acid C: benzoic acid CH3 O H3C H3C CHO 3 OH Cl Trans-4-chloro-3-t-butylhex-2-ene-5-onoic acid Homework pg 48 #1-5 pg 51 #1-3 pg52 #4, 5 pg60# 1, 2