1. 1.7 g of NaNO3 (Mr = 85) is dissolved in water to prepare 0.20 dm3 of solution. What is the concentration of the resulting solution in mol dm–3? 2. How many molecules are present in a drop of ethanol, C2H5OH, of mass 2.3 × 10–3 g? (L = 6.0 × 1023 mol–1) 3. The relative molecular mass of a gas is 56 and its empirical formula is CH2. What is the molecular formula of the gas? 4. How do the bond angles in CH4, NH3 and H2O compare? 5. When 100 cm3 of 1.0 mol dm–3 HCl is mixed with 100 cm3 of 1.0 mol dm–3 NaOH, the temperature of the resulting solution increases by 5.0 °C. What will be the temperature change, in °C, when 50 cm3 of these two solutions are mixed? 6. What is the total number of hydrogen atoms in 1.0 mol of benzamide, C6H5CONH2? 7. A fixed mass of gas has a certain volume at a temperature of 50 °C. What temperature is required to double its volume while keeping the pressure constant? 8. Values for the successive ionization energies for an unknown element are given in the table below. First ionization energy / kJ mol–1 Second ionization energy / kJ mol–1 Third ionization energy / kJ mol–1 Fourth ionization energy / kJ mol–1 420 3600 4400 5900 In which group of the periodic table would the unknown element be found? 9. Which metal nitrate solution is coloured? A. Zn (NO3)2(aq) B. Ni (NO3)2(aq) C. Mg (NO3)2(aq) D. Sc (NO3)3(aq) 10. Which property decreases down group 7 in the periodic table? 11. Consider the relative abundance of the isotopes of element X. Isotope Relative abundance (%) 24 80 25 10 26 10 X X X What is the relative atomic mass of X? 12. What is the concentration of NaCl, in mol dm–3, when 10.0 cm3 of 0.200 mol dm–3 NaCl solution is added to 30.0 cm3 of 0.600 mol dm–3 NaCl solution? 13. Which molecule has a non-bonding (lone) pair of electrons on the central atom? 14. A. BF3 B. SO2 C. CO2 D. SiF4 Chloroethene, C2H3Cl, reacts with oxygen according to the equation below. 2C2H3Cl(g) + 5O2(g) → 4CO2(g) + 2H2O(g) + 2HCl(g) What is the amount, in mol, of H2O produced when 10.0 mol of C2H3Cl and 10.0 mol of O2 are mixed together, and the above reaction goes to completion? 15. Consider the following reactions. 1 O2(g) → 2CuO(s) 2 Cu2O(s) → Cu(s) + CuO(s) Cu2O(s) + ∆HO = –144 kJ ∆HO = +11 kJ What is the value of ∆HO, in kJ, for this reaction? Cu(s) + 1 O2(g) → CuO(s) 2 16. A piece of metallic aluminium with a mass of 10.044 g was found to have a volume of 3.70 cm3. A student carried out the following calculation to determine the density. Density (g cm–3) = 10.044 3.70 What is the best value the student could report for the density of aluminium? 17. What is the electron configuration of vanadium? 18. How many σ and π bonds are present in a molecule of propyne, CH3CCH? 19. The Lewis structure of SO2 is given below. .. .. : O ―S .. O: .. What is the shape of the SO2 molecule? 20. When hydrogen peroxide decomposes, the temperature of the reaction mixture increases. 2H2O2(aq) → O2(g) + 2H2O(l) What are the signs of ∆H, ∆S and ∆G for this reaction?