CHEMISTRY TEST REVIEW - ANSWERS PERIODIC TABLE, CHEMICAL BONDING, LEWIS DOT DIAGRAMS, & VSEPR GENERAL NOTES on TEST: Test Format may include multiple choice, matching, true/false, calculations, drawing You may use a calculator You may have one (1) 3 x 5 index card and can use both sides for key definitions, examples, formulas, periodic table reminders, etc. You may use a periodic table – not the color coded one NO – THE TEST WILL NOT LOOK JUST LIKE THE REVIEW 1. Be able to fill in a fictitious periodic table based on criteria related to the actual periodic table. For example – how knowing the number protons or electrons, energy level, electron configuration, family characteristics, relationship to other clues 2. Be able to identify ionic, covalent, polar covalent, and metallic bonds. Which ions bond together Ionic – anions and cations Covalent – anions Metallic -- cations Which generic element families (non-metals, metals) bond together Ionic – metals and non-metals Covalent – non-metals Metallic – metals How are ionic, covalent, polar covalent, and metallic bonds similar? Involve valence electrons, form from more than one atom (of same or different element), Lewis Dot Diagrams look the same How are ionic, covalent, polar covalent, and metallic bonds different? Ionic electrons transfer, shared in covalent, metallic free flowing. Ionic and metallic form solids… covalents often liquids and gases and form double or triple bonds the other two do not. Naming convention is different. 3, Calculate the difference in electronegativity when the following bonds form knowing ranges for each Ionic Greater than 1.7 Polar Covalent 0.3 – 1.7 Non-Polar Covalent 4. 0 – 0.3 Identify examples of ionic, covalent, and metallic bonds For Example NaS2 ionic CO covalent NiCd metallic 5. NH3 covalent Fe2O3 ionic Know that non-metals and hydrogen only form single covalent bonds and that double and triple covalent bonds occur (for example – carbon based materials such as carbon dioxide, certain fuels) Be able to draw Lewis Dot Structures for individual elements Potassium Fill one e- on each side before doubling up Bromine K Br Be able to draw Lewis Dot Structures for molecules. Identify bond pairs and lone pairs. NO2 MgF -- O–N–O can form Reasonance Structure by bonding to Oxygen on right instead You are on your own for these three PO3 LiF Be able to identify a reasonance structure -- See NO2 above Example - SO3 This reasonance structure was on the VSEPR graphic organizer we did in class. Double bond can form between sulfur atom and any one of the three oxygen atoms. 6. Know how chemical bonds form Ionic - ____transfer______________ electrons Covalent - ___share____________ electrons Metallic – electrons are ____free________ __flowing______________ 7. Identify properties of chemical bonds Ionic – valence electrons are transferred between metals (cations) and non-metals (anions). Form crystalline structures, solids. Can be conductors of electricity. Covalent – valence electrons are shared between non-metals (anions). Usually gases or liquids. Don’t conduct electricity. Form higher energy double or triple bonds Metallic – valence electrons are free flowing (sea or cloud of electrons). Solid Or crystalline structure. Conduct electricity easily, shiny 8. Know why polarity is important and cite a real world example of it Polarity is tendancy of electrons to be attracted towards one atom over another which gives a molecule solvent properties to attract other molecules. Water is an example of a great solvent. 9. What do the initials VSEPR stand for? Valence Shell Electron Pair Repulsion Explain the VSEPR Theory. Since like charges repel, electrons will repel each other to the greatest distance (angular degree) possible. Be able to draw or construct linear, trigonal planar, and tetrahedral VSEPR for various molecules. Identify the angles between pairs in the proper number of degrees. For example – CO2 BF3 Linear Trigonal planar 180° angle 120° angles CF4 Tetrahedral 109.5° angles