Hiram College, Chem. 161 Fall 2007 Chemistry 161 Final Exam November 19 , 2007 Name:____________________________________ Part 1: Multiple Choice Place the letter of the best answer in the space provided. ____1. An acid is defined as A. B. C. D. E. a sour tasting substance. a proton donor. a compound that makes H3O+ in water. All of the above statements (A-C) describe an acid. None of the above statements (A-C) describe an acid. ____2. A student mixed 4.6 g copper (II) sulfate in 49 mL of methanol. Which of the following is true regarding the solvent and the solute.? A. B. C. D. E. Copper (II) sulfate is the solute and methanol is the solvent. Copper (II) sulfate is the solvent and methanol is the solute. Copper (II) sulfate is the solvent and the solute. Methanol is the solvent the solute. None of the above are true. ____3. 5.2 104 expressed in standard notation is written in the form A. B. C. D. E. 52 520 5200 52000 520000 ____4. Choose the answer that contains a metal, a non-metal and a metalloid. A. B. C. D. E. He, Al, Li Cl, O, N Ca, Si, C K, As, Mg B, S, Br ____5. How many electrons are in the valence shell of carbon? A. B. C. D. E. 4 6 8 12 14 1 Hiram College, Chem. 161 Fall 2007 ____6. Alpha-linolenic acid, ALA, (pictured below) is an omega-3 fatty acid. Which of the following is not true about ALA? A. B. C. D. E. ALA has a hydrophobic end and a hydrophilic end. ALA has a carboxylic acid group. ALA is a polyunsaturated compound. ALA has a degree of unsaturation of 3. ALA has London forces acting on it. ____7. Nuclear fusion is described as A. B. C. D. E. the process by which atoms are split on the nuclear level. the process by which atoms are combined on the nuclear level. the process by which atoms of opposite charges are combined. the process by which neutral atoms share electrons. the process by which abnormal atoms melt into new atoms. ____8. How many protons, neutrons and electrons are in 127-iodine? A. B. C. D. E. 127 protons, 127 electrons, 127 neutrons 53 protons, 53 electrons, 53 neutrons 74 protons, 74 electrons, 74 neutrons 74 protons, 74 electrons, 53 neutrons 53 protons, 53 electrons, 74 neutrons ____9. Which of the following is true regarding the acid/base reaction below? H2SO4 + NaOH H2O + NaHSO4 A. B. C. D. E. The acid/conjugate acid is H2SO4 / H2O. The acid/conjugate base is H2SO4 / H2O. The acid/conjugate acid is H2O / NaHSO4. The acid/conjugate base is H2O / NaHSO4. The base/conjugate base is H2SO4 / H2O. ____10. What volume of gas is occupied by 6.30 g of propane (C3H8) at 25.0oC and 1.15 atm? A. B. C. D. E. 78.6 L 0.255 L 3.04 L 0.328 L 3.7 L 2 Hiram College, Chem. 161 Fall 2007 ____11. The half life of a radioactive element is described as A. B. C. D. E. The time it takes for half of the sample to increase. The time it takes for half of the sample to decompose. The time it takes for half of the sample to explode. The time it takes for half of the sample to liquify. The time it takes for half of the sample to regenerate itself. ____12. A gas is compressed from 7.6 L to 5.2 L. The final pressure is 13.5 atm. What was the original pressure? A. B. C. D. E. 2.9 atm 3.0 atm 6.8 atm 9.2 atm 19 atm ____13. What is the maximum number of electrons available to an element in the second period? A. B. C. D. E. 2 8 10 12 18 ____14. The correct Lewis Structure for CCl4 is A. B. C. D. E. ____14. Avagadro’s number is A. B. C. D. E. 6.92 1024 6.00 10-23 6.02 1023 6.02 10-23 2.02 1023 ____15. What is the molecular weight of 2,3,4,5-tetramethylhexane? A. B. C. D. E. 128 amu 132 amu 136 amu 142 amu 150 amu 3 Hiram College, Chem. 161 Fall 2007 ____16. Concentrated hydrochloric acid is 12 M. What volume of concentrated hydrochloric acid is required to make 750 mL of a 2.5 M solution? A. B. C. D. E. 0.156 mL 1.56 mL 15.6 mL 156 mL 1560 mL ____17. How many moles are there in 92 mg of glucose (C6H12O6)? A. B. C. D. E. 5.1 mol 0.51 mol 0.051 mol 0.0051 mol 0.00051 mol ____18. A sample of 15.0 L of ammonia (NH3) gas at 5.0oC is heated under constant pressure to a volume of 20.0 L. What is the final temperature? A. B. C. D. E. 3.8oC 6.7oC 7.5oC 8.4oC 9.5oC ____18. The most electronegative element on the periodic table is A. F B. Cs C. Fr D. H E. He ____19. Two properties that affect the state of matter of a compound are A. temperature and pressure B. temperature and volume C. volume and pressure D. volume and density E. mass and volume ____20. The w/v % of a solution made from 0.425 mol of sodium nitrate in 185 mL of water is A. B. C. D. E. 12.3 % 16.4 % 18.6 % 19.5 % 21.6 % 4 Hiram College, Chem. 161 Fall 2007 ____21. Which of the following best describes the combustion of a compound? A. B. C. D. E. A physical change. A chemical change. A physical property. A chemical property. None of these describe combustion. ____22. Complete the following equation: A. B. C . D. E . ____23. Which of the following represents a balanced equation? A. B. C. D. E. PCl5 + 4 H2O 5 H3PO4 + 3 HCl 2 PCl5 + 4 H2O 2 H3PO4 + 3 HCl PCl5 + 4 H2O 4 H3PO4 + 5 HCl PCl5 + 4 H2O H3PO4 + 5 HCl PCl5 + 5 H2O H3PO4 + 5 HCl ____24. London forces are described as A. B. C. D. E. weak intermolecular forces. the result of instantaneous dipole moments. forces that are hard to break resulting in high melting points. A and B A and C ____25. What grade do you think you’ll get in this class? A. B. C. D. E. A B C D F 5 Hiram College, Chem. 161 Fall 2007 Part 2 Matching Place the letter of the description in column 2 with the best item in column 1. Column 1 Column 2 ____Gravy* a. Pure substance ____Melting candles b. An organic compound ____Table salt c. Physical change ____Protein from turkey d. Chemical change ____Turkey dressing e. Ionic compound ____Water f. Homogeneous mixture ____Cooking turkey g. Heterogeneous mixture * Gravy made from broth that was properly strained and from a proper rue so that it is free of lumps. Part 3 Short Answer Write the answers to the following questions in the space provided. If doing a calculation, be sure to show all your work for full credit. 1. Consider the chemical reaction : MW (g/mol) Zn + 2 HCl 65.38 36.46 ZnCl2 + H2 136.23 2.02 If 6.98 g Zn is reacted with 25 mL of 3.00 M HCl to produce H2 gas, what is the limiting reagent? 2. Circle the two ends of the following amino acids that react to form a peptide bond. Arginine Isoleucine 6 Hiram College, Chem. 161 Fall 2007 3. Tell whether the following vitamins are lipid soluble or water soluble. 4. A student was taken to the urgent care center after eating dinner in the college cafeteria. The driver was traveling at 78 mi/h. a. The urgent care center was 16 km from the college. How long did it take the student to get there from the college? (1 mi = 1.609 km) b. Normal body temperature is 98.6F. The student’s temperature was 39.8C. Did the student have a fever? 7 Hiram College, Chem. 161 Fall 2007 c. The student was found to have an E. coli infection and was administered amoxicillin (pictured below). Circle and label the functional groups. d. The antipyretic (a drug that lowers body temperature) acetaminophen was prescribed with a dosage of 50 mg/kg three times a day. The student weighed 137 lb. How much acetaminophen should the student take in a day? (1 lb = 0.454 kg) 5. Draw 3 isomers with the formula C4H9Br. 8