Chemical Principles I, First Exam Name:______________________ All calculations must be CLEARLY shown to receive ANY credit for questions. 1. (6 pts) Carry out the following operations. a. 2.453 + 13.21 + 0.0268 b. 89.03 / 34.86783 c. 3.41 – 0.23 x 0.405 2. (6 pts) Indicate the number of significant figures. a. 0.0002030 g b. 2.000000 cm c. 8.00600 mL 3. (6 pts) Give the number of electrons, protons, and neutrons for the following atoms or ions. electrons protons neutrons – 81 35 Br 39 19 K 99 43Tc 4. (12 pts) Name the following ionic compounds: a. (NH4)2SO4 b. Mg(ClO4)2 c. Cu(NO3)2 d. K2CO3 e. Hg2S f. Fe(OH)3 Test 1, Chapters 1-3, Chemical Principles I, Fall 03 1 5. (10 pts)Write the chemical formulas for the following compounds: a. silver oxide b. zinc phosphate c. aluminum sulfate d. sodium hypobromite e. lithium sulphate 6. (10 pts) Balance the following equations: a. Hg(NO3) 2 b. C5H10 + HgO + O2 NO2 + CO2 + O2 H2O Test 1, Chapters 1-3, Chemical Principles I, Fall 03 2 7. A compound’s mass is found to be 24.5% Na, 14.9% Si, and 60.6% F. Calculate its empirical formula. (10 pts) Test 1, Chapters 1-3, Chemical Principles I, Fall 03 3 8. Butyne C4H6 is combusted to form CO2 and H2O. Calculate the maximum mass of CO2 formed when 1.00g of butyne is combusted. (12 pts) Test 1, Chapters 1-3, Chemical Principles I, Fall 03 4 9. 50.0g of ethylene oxide are mixed with 100.0g of oxygen and allowed to react according to the chemical equation: 2 C2H4O + 5 O2 4 CO2 + 4 H2O Calculate the maximum mass of CO2 produced. (18 pts) Test 1, Chapters 1-3, Chemical Principles I, Fall 03 5 10. Aluminum sulfide, Al2S3 reacts with water to form aluminum hydroxide, Al(OH)3 and hydrogen sulfide gas, H2S according to the following chemical equation: Al2S3 (s) + 6 H2O (l) 2 Al(OH)3 (s) + 3 H2S (g) Calculate the percent yield when 45.7 g of Al(OH)3 are recuperated after 50.0 g of Al2S3 are completely reacted (9 pts.). State two factors which affect the percent yield. (1 pt.) Test 1, Chapters 1-3, Chemical Principles I, Fall 03 6 Test 1, Chapters 1-3, Chemical Principles I, Fall 03 7