ENERGY: REFERENCE NUMBERS POWERS OF TEN 10 deka (da) 2 10 hecto (h) 103 kilo (k) 6 10 mega (M) 9 giga (G) 10 10 I,2 tera (T) 15 10 peta (P) 18 10 exa (E) 10-1 10-2 10-3 10-6 10-9 10-12 10-15 10-18 deci(d) centi (c) milli (m) micro (11) nano (n) pico (p) femto (f) atto (a) When multiplying powers of ten, the exponents add: 103 X 106 = 103+6 = 109 (2xl04) X (4xl05 ) = (2x4)x104+5 = 8x10 9 When dividing, you have to substract the exponents: 103 / 107 103- 7 = 10-4 DISTANCE 1 meter (m) = 100 centimeters (em) = 3.281 feet (ft) 1 mile (mi) = 5280 ft = 1.609 kilometers (km) 1 micron (11) = 10-6 m 1 angstrom (A) = 10-10 m = 39.37 inches (in) Example: To convert the diameter of the Earth, which is 7900 miles to kilometers: (7900 mi) x (1 km / 0.62 mi) = 12700 km AREA 2 4 . 2 1 square meter (m ) = 100 ern x 100 cm = 10 ern 1 square meter (m") = (3.281 feet)2 = 10.8 square feet 1 square kilometer (km") = 1000 m x 1000 m = 106 m 2 = 0.4 square miles 1 hectare (ha) = 100 m x 100 m = 104 m 2 = 2.47 acres 1 acre = 43560 square feet (fr') 1 bam (b) 10-24 cm 2 Example: To express the area of the Earth, which is 500x106 km", in square miles: (500 x 106 krn") x (0.4 me / 1 krrr') = 200 X 106 mi 2 VOLUME 1 cubic meter (rrr') = 1000 liters = 264.2 US gallons = 35.31 cubic feet (fr') 1 liter (I) 103 cubic centimeters (cnr' or ml) = 1.057 US quarts 1 acre foot = 1.234 x 103 m 3 1 cord = 128 fe 1 board foot = 2.36 x 10-3 m' 1 cubic mile = 4.17 cubic kilometers (krn') 1 barrel of petroleum (bbl) = 42 US gallons = 0.159 m' Example: To find the numbers of gallons in cubic kilometers of water: (1 km') x (10 9 m'zkm") x (264 gal/rn ') = 264 x 109 gal ENERGY: REFERENCE NUMBERS MASS AND DENSITY 1 kilogr am (kg) = 2.205 pound s 3 tons 1 metric ton (tonne or MT) ='10 kg = 1.102 short tons = 0.9842 long 1 pound (lb) = 16 ounce s avoird upois (oz) = 453.6 grams (g) n/km' Densi ty of water = PWATE R = 1 g/crrr' = 1 kg/lite r = 1 ton/m' = 1 gigato PAIR AT SEA-LEV EL = 1.2 kg/rrr' PAIR-DR IED WOOD = 0.7 tons/nr' PSOIL = 2 tons/m ' PROCK = 3 tons/rrr' ENER GY 7 2/sec 2 = 10 ergs = 0.2390 calories (cal) 1 joule (1) = 1 kg m 4 I joule (1) = 9.484 X 10- British therm al units (Btu) 1 joule (1) = 1 watt-s econd (Ws) 18 1 joule (1) = 6.242 X 10 electro n volts (eV) 1 joule (1) = 1 newto n-met er (Nm) 6 1 kilowa tt-hou r (kWh ) = 3.6 x 10 J = 3414 Btu 18 15 1 quad = 10 Btu = 1.05 X 10 J 3 1 Calori e ~ 1 kiloca lorie (Kcal) = 10 cal 5 1 therm = 10 Btu 1 foot pound = 1.356 J 12 1 kiloton of TNT (KT) = 4.2 x 10 J POW ER 1 watt (W) = 1 joule/ secon d = 3.6 kJ/hou r 1 horsep ower (hp) = 0.764 kilow atts (kW) 31.5 MJ/ye ar PRESSURE 2 1 pascal (Pa) = 1 N/m 5 1 bar = 10 pascal = 0.9869 atmos pheres (atm) 2 1 atmos phere (atm) 76 em of mercu ry 14.7 Ib/in = 760 torr TEM PERA TURE Degre es Celsiu s (OC) = 5/9 [degre es Fahren heit (OF) - 32] Degre es Fahre nheit (OF) = 1.8 degree s Celsiu s (OC) + 32 s + 273.15 Kelvin or absolu te tempe rature scale, Kelvin s (K) = degree s Celsiu ENERGY: REFERENCE NUMBERS APPROXIMATE VALUES OF THE MOST COMMON MEASURES OF ENERGY AND ENERGY FLOW Reference energy measure: 1 joule (J) 1 British thermal unit (Btu) = 1 kJ 1 million Btu = 1 gigajoule (GJ) 1000 cubic feet of natural gas = 1 gigajoule 1 GJ = 1 gigajoule = 8 gallons of gasoline = 1000 fe natural gas = 33 kg of coal 1 ton of TNT = 4 gigajoules 1 barrel of oil (bbl) = 6 gigajoules 1 ton of wood = 15 gigajoules 1 ton of coal = 30 gigajoules 1 ton of oil = 45 gigajoules 1 "quad" = 1,000,000,000 gigajoules = 1 exajoule Reference energy-flow measure: 1 watt (W) = 1 joule per second 1 million bbl of oil per day = 70 gigawatts = 2 exajoules/year 1 billion tons of coal per year = 1 terawatt = 30 exajoules/year ENERGY FLOWS Flow Value (10 12 W) Energy radiated by sun into space Solar radiation incident on top of Earth's atmosphere Solar radiation reflected back to space from Earth Solar radiation reflected back to space from Earth's atmosphere Solar radiation absorbed in atmosphere Rate at which latent heat flows from Earth's surface to atmosphere Rate at which infrared radiation leaving Earth's surface flows directly to space Rate at which convective heat flows from Earth's surface to atmosphere Wind, waves, ocean currents Net primary productivity on Earth Energy conducted from Earth's interior to its surface World energy consumption (1980) U.S. energy consumption (1980) Energy content of food consumed by world's human population (1980) World electricity production (1980) U.S. electricity production (1980) 3.7 X 10 14 175,000 53,000 46,000 44,000 42,000 10,200 8,600 500-2,000 75-125 20-40 10 2.5 0.55 0.87 0.26 ENERGY: REFERENCE NUMBERS EARTH'S NON-RENEWABLE ENERGY RESOURCES Resource Petroleum Natural Gas Coal Tar sands Oil shale Uranium in non-breeding light water reactors Thorium and uranium in breeder reactors Deuterium and lithium in seawater (for fusion power) Estimated stock (1980) (l0 21 J) Consumption (1980) (10 18 J/yr) World U.S. 10 10 250 >2 2,000 135 60 90 0 0 41 20 15 0 0 20 6.3 3.1 10,000 0 0 10 0 0 10 ENERGY CONTENT OF SELECTED SUBSTANCES Substance Energy content (10 6 Jlkg) Natural gas Gasoline Petroleum (crude) Typical animal fat Coal Charcoal Paper Dry biomass Air-dried wood or dung Crop wastes (20% moisture) Bread Milk Beer 3.9 x 10 J/m3 48 43 (6.1 x 109 Jlbbl) 38 29.3 29 20 16 15 13 12 3 1.8 7 Appendices Approximate conversion factors Units Crude oil' 1 metnc tonne. 220462 Ib 1 kllolitre • 62898 barrels 1 ktlocalone (kcal). 4187 kJ • 3968 Btu 1 kilOjoule (kJ) • 0239 kcal ·0948 Btu 1 British thermal umt (Btu) = 0252 kcal • 1 055 kJ 1 kilowatt-hour (kWh) • 860 kcal • 3600 kJ • 3412 Btu To toores Tonnes (metric) Kilolltres Barrels US gallons Barrels/day tomes/ US (mellic) kilolilfes 0.858 0136 000325 1165 1 0159 00038 year gallons barrels Mutliply by 7.33 6.2898 1 00238 From 308 264 42 1 498 'Based on WOfldwlde average gravity Products Toconvert barrels 10tonnes to tonnes kltolitres tonnes to kilolitres 0542 0740 0806 0839 0939 1844 1 351 1240 1 192 1.065 toMeS to barrels Multiplyby LPG 0.086 0118 0128 0133 0149 Gasoline Kerosme Gas ou/oreser Fuel all 11.6 85 78 75 6.7 Calorific equivalents One tonne of all egulvalent eguals approKimately Heat units 10 million kilocalories 42 gigaJoules 40 million Blu Solrd luels 1.5 tonnes of hard coal 3 lonnes of lignite Gaseous fuels See Natural gas and LNG table Electncrty 12 megawatt-hours One mtllion tonnes of oil produces about 4000 91gawatt hours of electricity in a modern power station Natural gas and LNG To billioncubic metres NG billioncubic feel NG 1 0028 1.111 138 0028 016 353 1 392 487 098 561 From 1 billion eucre metres NG 1 billion cutnc feet NG 1 million tonnes all eqUivalent 1 million tonnes LNG 1 trillion British Ihermal uruts 1 million barrels oil egulvalent million iomes oil equivalent million tonnes LNG Multiply by 073 090 0021 0026 1 0805 1 1 23 0.025 0.02 014 012 trillion British thermal unltS million barrels 011 equivalent 36 103 404 520 1 58 6.29 018 7.33 868 017 1 Definitions Statistics published In this Review are taken from government sources and published data. No use East and Southern Africa Terntories on the east coast of Africa from Sudan to is made of confidential information obtained by Repubhc of South Alnca Also Madagascar, MalaWI Namibia, Uganda, Zambia. Zimbabwe BP Amoco in the course of its business. West Alrica: Nlgena Asia Pacific: lnoonesra South America: Venezuela (Srnce Ecuador and Gabon have Wllhdrawn Irom OPEC North America Asia Pacific Brunei. Cambodia. China. China Hong Kong SAR". they are excluded from all OPEC tala Is ) USA (exciudlng Puerto RICO). Canada and MeXICO South and Central America indonesia. Japan. Laos. Mafaysla. Mongolia. North Korea. Phmppmes. Srngapore. South ASia European Union members Austrra. Belqiurn. Denmark. Fmlano France Germany Canbbean (inCludIng Puerto RICO) Central and South Amerrca Western Europe European members of OECD (apart from Czech RepUblic. Hungary and Poland) plus Cyprus. Grbraltar and Malia (Afghantslan. Bangladesh. India. Myanmar. Nepal. Greece. RepubliC of Ireland. Italy. Luxembourg Pakistan and Sn Lanka]. South Korea. Taiwan. Thailand. Vietnam, Ausuana. New Zealand, Papua New GUinea Netherlands. Portugal. Spam. Sweden. UK and the SOUlh West Pacinc Islands EMEs (Emerging Market Economies) Sooth & Central America. Central Europe, Fonner Soviet 'Speciat Administrative Region Australasia Union, Arnca. Middle East and Non-DECO ASia PaolI( In ttus Review. the term 'Other EMEs excludes Cent! al Australia. New Zealand Europe and Former Soviet Union Albania. Bosnra-Herzeqovrna. Bulgaria. Croatia, Czech Republic Hungary. Former Yugoslav Republic Country groupings are made purely for statistical purposes and are not intended to Imply any Other terms of Macedorua. Poland. RomalTla. Slovakia. Slovenia. Yugoslavia judgement about political or economic standings. Tonnes: Metric tons Central Europe Western Europe and Central Europe OECO members -f Europe: Austria. Belgium Czech Republic. Denmark. Finland, France. Germany. Greece Hungary. Iceland. Middle East Republic of Ireland. Italy. Luxembourg. Nelherlands. Norway. Poland, Portugal. Sparn. Sweden. Swuzertand. Europe Arabian Peninsula Iran, Iraq. Israel. Jordan, Lebanon, Syna North Africa Temtones on the north coast of Africa from Egypt to Western Sahara West Africa Terruones on the west coast of Aluc a lrom Meuntarua 10 Angola, lflcludHlg Cape Verde Islands Turkey, Untted Kingdom Other member countries' Austraua. Canada Japan. MeXICO. New Zealand. South Korea. USA Percentages Calculated berore rounding of actuals All annual changes and shares of totals are on a weight t)aStS except on pages 16. 17 and 18 Rounding differences Because of rounding. some totals - mcludinq HIe 1998 share of total - might not agree exactly wrttt the sum of their component parts US processinq gains OPEC members Gains In volume occur In tne relining 01 crude all mto products For the USA, WhiCh accounts Ior most of tI\(; Middle East: Iran. Iraq Kuwait. Oatar Saudi Arabia Uruted Arab Emnates (Abu Dhabi Duoa.. Ra,·al world's processing qarns II Kharman and Shaqah) these gams from voiurnerr«: consumpnon level:-, to North Arrrca Algena. Libya convennonat to dee1uc! reflect more accurately the eflectrve demand all resources ntu, /zwww /)pamo((J comlwo{feJenergylappendlces IS 011 crude 499 CONVERSION TABLES Energy conversion factors CONVERSION TABLES These tables provide multiplicative factors for converting from one energy or power unit to another. For example, to convert a quantity from kcal to Btu, find the original unit at the left edge of the table on p. 499 and read across to the column headed by the desired final unit. This tells one to multiply by 3.968. Thus 4.5 kcal equals 4.5 x 3.968 Btu (17.86 Btu). Caution should be used in conversions involving the energy values offuels (coal, petroleum, and natural gas). The energy content of such fuels varies by 10% or more according to the quality of the source and the method of production. When accuracy is required in calculations involving fuels, specific data should be obtained. Watt Gigajoule (GJ)/yr Quad/yr Petroleum. tonne/yr Petroleum. bbllday Quad/yr I 3.16 x 10- 2 31.69 3.34 x 1010 1394 7.06 x 10" 2.99 X 10- 11 9.49 x 10- 10 1.05 x 10" 44.0 2.23 x 1()3 I I 4.17 x 10-' 2.11 x 10-' Petroleum, tonne/yr Petroleum, bbllday 7.17 x 10-' 2.27 X 10-2 2.40 x 107 I 50.6 1.42 X 10-5 4.49 x 10-< 4.73 x 10" 1.98 X 10-2 I kcal I 1.055 x 10-' 3.60 x 10-' 4.186 x 10-' 9.48 x 10' I 3413 3.968 278 2.93 x 10-4 I 1.163 x 10' 2.39 x I(}' 0.252 860 I Coal. tonne" (MT) Coal. ton" 28 25.4 2.65 x 10' 2.41 x 10' 7.78 x II}' 7.(}6 x II}' 6.69 x 10' 6.07 x 10' I 0.907 1.10 I Petroleum. tonne {M]") Petroleum. bbl 44 6.1 4.17 x 10' 5.8 x 10' 1.22 x 1(1' 1.70 x 10" 1.05 x 10' 1.46 x 10' 1.57 0.218 1.73 0.240 0.034 0.129 3.22 x I(}' 1.22 x I<Y' 9.45 :15.4 8.13 x J(}' :1.08 x Ill' 4.60 x 10 1.34 x 10-' .'.07 x 10 56 0.040 1.06 x 10-' 5.31 x 10' :1.79 x I(}' 1005 1.56 x I(}' 11.1 0.295 1.34 x 10' 9.56 x II}' 253 2.00 1.43 x 10-" 3.79 x 10-' 2.20 1.57 x 10-" 4.17 x 10-" Gigajoule (GJ)' Btu kW-hr kcal Gasoline. liter Gasoline. gal" Natural gas. tonne (MT) .~(\/\-t&l 498 KCI/iev' 5' I/\,{. .i'>, Wr-11l. ~ch. \/0\ '2. f'al(o in·J. A-H,: CA X 10-.1 3.94 x 10-' 4.15 x 10-' 1.42 X 10-4 1.65 x 10-' Petroleum. Gasoline. liter Gasoline. gal'' Nat. gas. Nat. gas. Nat. gas. bbl tonne (MT) m:l,- ft:l 2.27 x 10-' 8.18 x 10-' 9.51 x 10-' 0.164 1.73 x 10-' 5.90 x 10-' 6.86 x 10-' 29.4 3.10 x 10-,' 0.106 1.23 X 10- 4 7.75 8.18 x 10-' 2.79 x 10- 2 3.24 x 10-:> 0.0179 1.88 x 10-' 6.43 x 10-' 7.48 x 10-' 25.0 2.64 x 10-' 9.00 x 10-' 1.05 x 10-' 94:1 9.95 x 10-< :1.40 3.95 x 10-' Coal. tonne" (MT) Coal. torr 0.636 0.577 4.59 4.16 824 747 217 197 0.50 0.454 700 635 2.64 x 10" 2.40 x I(}' Petroleum. tonne (MT) I 0.139 7.21 I 1290 179 341 47.3 0.786 0.109 1100 152 4.15 x I(}' 5.76 x I(}' Gasoline, liter Gasoline. gal" 7.73 x 10-' 5.57 x 10-' 2. II I 3.79 0.264 I 6.07 x 10-' 2.30 x 10-" 0.850 3.22 32.1 2.93 x 10-:1 Natural gas. tonne (MT) Natural gas, rrr' 1.27 9.09 x 10-' 2.41 x 10-' 9.18 6.56 x 10-' 1.74 x 10-' I 7.14 x 10- 4 1.89 x 10-' 1.40 x II}' 1 2.65 x 10-' 5.28 x I(}' 37.7 I Gigajoule (GJ)' Btu kW-hr kcal Petroleum. bbl ~ bOne tonne M, S'; "",""'GoA S) e.tJ A/VI.....G1-l ·~~lfi~ o.u J ·fl\e")~. 1.21 x 10-' x 10-' x 10--'1 x 10-' Petroleum. 'One GJ > 3.57 3.77 1.29 1.50 tonne (MT) Natural gas, £13 \ ;';:'ltu.,Jer) j tool" kW-hr Power conversion factors GJ/yr Coal. Btu Natural gas. m3 Natural gas. ft:l Watt Coal. tonne (MT)h GJ' 2.40 x 10-11 X 10-2 1.65 x II}' 1.18 3.12 X 10-2 434 0.310 8.22 x JO-:J 10' Joules. » 1000 kilograms. The value of energy content given here is typical of a bituminous coal. COne ton = 2000 pounds. The value of energy content given here is typical of a bituminous coal. 'US gallon ~ 3.78 liters. -At ere. and a pressure of 760 mm. 'At 60"F. and a pressure of 30 inches of mercury. f 122 so • FIGURE 9.1. Example Data ~heet Physical Constants and Conversion" .undcrlinc.: \vi,h I P CONVERSION FACTORS For physical constants and conversions, there's nothing better than The Handbook of Chemistry and Physics. It comes out every year, but, because physical laws and constants rarely change, even an old version of this work is so you should pick one up at a used bookstore. Virruallv all libraries have a copy of this book on the shelf. There are certain facts that I use frequently. For example, I often need to convert English units to metric units and vice versa. To help this process along, I 1 ron {t] 1,000 1 atomic mass unit 1.6606e-24 1 m = 3.281 fr 39 ..37 in 1e6 r 1 km 0.6214 rni 0.5400 naur rm I fr = 1 m2 = 10.76 ft2 1e28 barn 1 km2 = 100 1 mi2 2.590 km2 = 640 acres" 1 ft2 = 929.0.3 cm2 m3 = 999.97 liter =.35.31 ft.3 = 264.2 gal ., 1 ac-fr = 1233 m.3 (1 liter = 1 kg of H20 at 4 C; of H20 at this T 1S 1 cord = 128 ft3 3.625 m3 1 bushel 1 m/s = 3.281 ftls 2.237 mph = 1.944 knots" 1 1 cfs 0.0283 m.3!s 449 gpm = 724 ac-ft/yr ' 1 memorize the most commonly used conversions and keep the rest on a one-page data sheet for ready reference. I recommend compiling such a sheet for your own use that contains the conversions most useful to your work. The hour or so of work needed to compile this page will be repaid many times over in the convenience of not having to dig deeply into obscure reference books whenever you need to do a calculation. See Figure 9.] for an example data sheet. EXERCISE Compile a data sheet for your own use after thinking for a week or two about the numbers you use most frequently. Pass It around to your coworkers to get their suggestions. Print for them when you're done, to share the wealth. newton (N) le5 dynes = 0.2248 lbtforce) " 1 pascal (Pa) = 1 N!m2 lc-S bar 1 arm 1.01 .325 Pa = 10.33 t(foree)!m2 = 14.696 Iblin2 = 760 mm Hg 10 = torr = 0.01 gray 1 curie tCil 3.7e10 dis/s = 3.7el0 becquerel {Bq] ., 1 rad = 100 .ur 1 gray (Gy) 1 Jlkg , 1 roentgen (R) -> 2.58e-4 coulombt-. or roentgen-equivalent-man (rem) :::; rads x quality factor ~, I sicvcrr ::: lOn rem EARTH: R km; A = 5 1O.1e6 km2 (oc .361.3. lei 14S.5, icc-free lei 1.3; Asia Africa 30.3, 22.4, S. America 17.S, Oceania S.5, 4.9); t (oc l.4d8, ice 2.geI6, arm 5.2eI5, Ikslstr 1..3e14, M= CPP 200. NPP 1001 E @ top of arm 172,000 TW (surf 88,000, evap 41 ,000, wind elev 8848 m; avg elevation = 840 m; deepest ocean = I 1,000 m. of latitude = 111 km; 1 minute e 1.85 km. Solar constant ::: 13hH W!m2. ATM: @ sea lvl 1.225 kgim3, 288 K, mol wt 28.96, 2.55e19 molecules/crn.s. sound speed 331.4 m/s; percent by vol N2 78.09%, 02 20.95%" A 0.9.3%; ppm-C02 340, Nt 18, lie CH4 2.9, Kr 1.1, N20 0.5, CO 0.1,030.01; attn water vapor & clouds 1.3e13 t. Heat can of air 1 j/g-K. Tropopause: h 11 km, p = 0.23 arm, T = 217 K. Wet-air lapse rate 6.5 K/km, dry = 10 K/km. Viscosity = 1.5e-4 dync-scc/crn.l. ~M,s~~{i;a~?;~&,>;,'~-~ Doto, Data, Dote' I heat cap = 1 cal!g-K; heat vapn = 539.6 C). Oen vol = 1.35e9 km3; (15 C) = 1.026 15, Li 0.17, P can't moke bricks without cloy! - SHERLOCK HOLMES g N = 6.022c23/!llo!L· . .-::: 2.4YHcIO . .-m!" s= W!m2-K4' K = C + 27.1.15 F = I.SxC + kg = 931.5 MeV" e = 1.602e-19 coulomb h c 0.';2';e·14 oj-