嘉南中學 HOPE CHRISTIAN HIGH SCHOOL Jesus said to him, “I am the way, the truth, and the life. No one comes to the Father except through me.” 1242 Benavidez St., Sta. Cruz, Manila Tel. No. 310-80-71 to 78 ELEMENTARY SCHOOL SCIENCE DEPARTMENT GRADE 7 First Term, SY 2013 SOLUTIONS Module 2 LESSON 1 Solution and Its Properties KEY CONCEPTS / SUMMARY Solution is a homogeneous mixture Solute and solvent are the two components of solution Solute is the substance that Is dissolved; one in smaller proportion Solvent is the dissolving medium; one in larger proportion Electrolyte is a compound in an aqueous solution that conducts electricity Non electrolyte is a compound in aqueous solution that do not conducts electricity Aqueous solution is where solute dissolves in water NOTES Types of Solution • Gaseous solutions are usually homogeneous and all gaseous mixtures are gas-gas solutions. The air is a natural gas-gas solution. Air is made up primarily of nitrogen (~78%) and oxygen (~21%) with trace amounts of argon, carbon dioxide and water vapour. Nitrogen-oxygen gas-gas solution • • Liquid solutions are our most easily recognized mixtures. When molecules of gas, solid or liquid are dispersed and mixed with those of liquid, the homogeneous states are called liquid solutions. Solids, liquids and gases dissolve in liquids to form liquid solutions. Solid Solutions are much lesson common. Many alloys, ceramics, and polymer blends are solid solutions. Copper and zinc dissolve in each other and harden to give solid solutions called brass. Silver, gold, and copper form many different alloys with unique colors and appearances. Brass (alloy of copper and zinc) Types of Solution TYPE SOLID Liquid Gas SOLUTE SOLVENT EXAMPLE gas solid Oxygen gas(O2) in ice liquid solid Amalgam Hg in Ag (tooth fillings) Solid solid Tin (Sn) in Copper (Cu) - bronze gas liquid Oxygen gas(O2) in moist water liquid liquid Ethyl alcohol in water - wine solid liquid Sugar in water gas gas CO2 in N2 - air liquid gas Moisture loaded air Solid gas Naphthalene ball in air Forming a Solution A solution is only formed when two substances mix homogeneously, meaning that any portion of the solution will contain a specific amount of both the solute and the solvent. In the cases of cereal and milk or of muddy water, the two substances in the mixture will settle apart into two layers over time, so they are not homogeneously mixed. When you are dealing with a true solution, the two (or more) substances found in the solution will never settle apart. Not every combination of two substances becomes a solution. When you pour milk on your cereal in the morning, the resulting mixture is not a solution because the cereal does not become dissolved in the milk. Similarly, when mud in water causes turbidity, the mud is not part of a solution. We use the term insoluble to describe two substances which do not form a solution when they are mixed together. Solutes and Solvents In each solution, the solvent is the substance which determines the state of the finished solution. since the resulting solution is a liquid. If both the solute and the solvent have the same state, the solvent is typically the part of the solution which is present in the highest concentration. Universal Solvents Water is sometimes called the universal solvent because of its ability to dissolve a diverse array of substances. Acetone is also occasionally referred to as a universal solvent since it is able to dissolve oils, alcohols, and water. In truth, however, there is no such thing as a universal solvent because no one substance is capable of dissolving every possible solute. Even though there is no true universal solvent, you use one very good solvent every day - soap. Soap is made up of molecules which act like an oil on one end and like an alcohol on the other, so they are soluble in oils, in water, and in alcohol. WORKSHEET #1 A. Which of the following are solutions? Write Yes for solution and No if it is not a solution. _____ 1. milk _____ 2. apple juice _____ 3. the gas in a helium-filled balloon _____ 4. distilled water _____ 5. rain water _____ 6. smoke- filled air _____ 7. stainless steel B. Complete the table. SOLUTION SOLUTE SOLVENT PHYSICAL STATE (solid, liquid or gas) Vinegar ( 5.0 % acetic acid) 18 –K gold ring Brass (20% Zn, 70% Cu) Cl (chlorine gas) in swimming pool Carbonated drink/Softdrink Rubbing alcohol (70% isopropyl alcohol) WORKSHEET #2 View the item or read the description at each of the 18 samples and complete column two of the student worksheet by including both the station number and example observed at the station. It is important to consider what the constituents of the solution are (solid, liquid or gas solute in solid liquid or gas solvent). In third column, determine which substance is acting as the solute and which is acting as the solvent at the station observed. Sample Description: Sample #1: A bottle of household vinegar (5% liquid acetic acid dissolved in water) Sample #3: Solid Air Freshener subliming into the air when heated Sample #2: Sugar cubes dissolving in water Sample #4: Hydrogen dissolving in a transition metal such as platinum (a hydrogen storage strategy for releasing hydrogen for H2-powered vehicles). Sample #5: A brass candle holder (brass is an alloy of the solids copper and zinc) Sample #9: Soap suds Sample #6: A bottle of rubbing alcohol formed from liquid alcohol and water. Sample #13: A Styrofoam cup Sample #7: A mercury-gold amalgam (formed when liquid mercury is used to extract gold from gold-bearing rock) or mercury-zinc amalgam used in tooth fillings. Sample #14: The atmosphere above the water when water evaporates in a sealed water cooler container Sample #15: Smoke (solid particulates being released into the air) resulting from a fire Sample #8: Seawater Sample #10: A Car tire (made up of solid carbon in rubber) Sample #16: A bottle of antifreeze (liquid ethylene glycol in water) Sample #11: A piece of (cheap) jewelry made up of copper and gold Sample #17: Kool-Aid powder poured into water Sample #12: Methane gas released from the valve in a chemistry lab into the air Sample #18: Food coloring diffusing into water Use the SAMPLE DESCRIPTION to record your data. Type of Solution (solute-solvent) gas-solid Sample # State which substance is the solute and solvent for Station # listed gas-liquid gas-gas liquid-solid liquid-liquid liquid-gas solid-solid solid-liquid solid-gas WORKSHEET 3 A. Identify the type of solution (solid solution, liquid solution, gas solution) ____________ 1. air in solid food (ex: generic ice-cream) ____________ 2. carbon dioxide in water (Pepsi™) ____________ 3. oxygen in nitrogen (air) ____________ 4. mercury in silver-tin dental alloy ____________ 5. various hydrocarbons in each other (petroleum) ____________ 6. water vapour in air (humidity) ____________ 7. carbon in iron (steel) ____________ 8. ammonium nitrate in water (ice-packs B. Fill in the Blanks: Types of Solutions 1. 2. 3. 4. 5. 6. gas in _______________ ____________ in liquid __________ in ___________ gas in __________________ Liquid in ________________ ___________ in __________ carbonated beverages alcohol in water salt in water hydrogen in platinum mercury in silver (dental fillings) copper in silver (sterling silver) LESSON 2 Solubility KEY CONCEPTS / SUMMARY Solubility is the maximum amount of solute dissolved in a given amount of solvent at a specified temperature Liquids that are capable of forming solution is called miscible, those that do not mix to form solution are immiscible Factors that affect solubility are: Properties of solute and solvent, temperature and Pressure Factors that affect the rate at which substance dissolve are: Particle size, Agitation/stirring, Increase in temperature and Concentration of solution NOTES Solubility and Saturation A variety of units can be used to measure the concentration of solute in a solution. In general, a concentrated solution is one where the amount of solute in a given volume of solvent is great. A dilute solution is one where the amount of solute in a given volume of solvent is relatively small. But can we mix up a solution of any concentration? For example, can we produce a 90% solution of table salt in water? How about a 90% solution of table salt in gasoline? A few substances are infinitely soluble, or miscible, which means that they can be mixed together in any proportion. Ethyl alcohol and water are an example of miscible substances since they can be mixed together in concentrations ranging from pure alcohol to pure water. However, most substances are not infinitely soluble. Solubility is a term used to describe the amount of solute which can be dissolved in a solvent. The solubility of two substances will depend on the similarity of the two substances. As mentioned on the last page, some substances (such as oil and water) have a solubility of close to zero. Most substances, however, will have a solubility somewhere between complete insolubility and complete miscibility. Factors Influencing Solubility The solubility of two substances depends on several factors in addition to the identity of the substances. These factors can include characteristics of the environment and the state of the solute and solvent. In every case, these factors will influence the amount of solute which can be dissolved in a solvent. Environmental factors which influence solubility include temperature and pressure. For example, warm air is able to dissolve much more water vapor than cold air can. You may have noticed that the air is humid (full of water vapor) only on warm days. If very humid air cools suddenly, the extra water vapor will fall out of solution and will turn into liquid water. The liquid water in the air forms clouds or fog. The solubility of a solute can also depend on its oxidation state, which refers to the amount of electrons found in the substance. For example, iron and manganese tend to enter water in a low oxidation state, meaning that they have a relatively large number of electrons. But when these metals are exposed to air, they become oxidized (lose electrons) and are no longer very soluble in water. So the oxidized metals drop out of solution and cause red or black water complaints as well as stains on sinks and clothes. Saturation: Unsaturated, Saturated and Supersaturated An unsaturated solution is one that can still dissolve more solute at that temperature. A saturated solution is one in which the solute in solution is in equilibrium with the pure undissolved solute; in other words, the solution contains all of the solute it can dissolve at that particular temperature. Once a solution has reached the limit of the solute's and solvent's solubility, the solution is said to be saturated, meaning that it can hold no more solute. If additional solute is added to a saturated solution, the extra solute will settle out, forming a separate layer like the kind you would see when two substances are insoluble. A saturated solution of table salt and water. You can form your own saturated solution of table salt and water as follows. Add salt to water, stirring constantly until the salt dissolves. At first, the salt will completely dissolve in the water, discoloring the water slightly but leaving no visible solid residue. However, once you have added a certain amount of salt to the water, the solution becomes saturated. When you add more salt past the saturation point, the salt will not dissolve into the water no matter how long you mix the solution. Instead, the extra salt will settle out in a layer at the bottom of the solution as shown above. Supersaturation Whenever a solution contains more solute than it can hold, it is said to be supersaturated. We have mentioned one supersaturated solution already in this lesson the warm air which cooled and thus contained more water vapor than it could hold. A supersaturated solution contains more solute in solution than it would ordinarily hold at that temperature. Example: If in hot coffee one dissolves all the sugar it can possibly hold and carefully cools it, the coffee still holds all the sugar that was dissolved and a supersaturated solution exists. If a small crystal of sugar is introduced into this cooled coffee, some sugar will crystallize out and a saturated solution will remain Solutions can become supersaturated in a variety of ways, but in every case the supersaturated solution is unstable. If more of the solute is added or if the conditions change in any way, the extra solute will settle out of the supersaturated solution. In the water vapor and air solution, dust particles in the air provided the slight change which caused water vapor to settle out, forming clouds and rain. If you've ever made sweetened iced tea, you will have taken advantage of the characteristics of a supersaturated solution. By adding sugar to hot tea, you were able to dissolve much more sugar into the water than you would have been able to dissolve into cold tea. When the tea cooled, the additional sugar remained dissolved in the tea as a supersaturated solution. If you tried to add more sugar to the cooled tea, however, the excess solute would drop out of solution and the tea would become less sweet. WORKSHEET #3 Use the data table below to answer the following questions. Substance Sinks to the bottom Sand √ Floats on top Floats in the liquid Sodium Nitrate Disappears √ Sulfur powder √ Table salt √ Copper sulfate √ PROBLEM √ √ 1. Name two insoluble substances ________________________________________________________ 2. Name two soluble substances ________________________________________________________ 3. Name one substance which forms a suspension _______________________________________________ 4. Name two substances which dissolved _______________________________________________________ 5. What is the name given to the mixture of copper sulfate and water?______________________________________________________________________________ CHECK YOUR UNDERSTANDING Underline the letter of the correct answer. 1. If a solution can hold more solute (it isn't full yet) it is: A. Unsaturated B. Saturated C. Supersaturated 2. If a solution cannot hold any more solute (it is full) it is: A. Unsaturated B. Saturated C. Supersaturated 3. If a solution holds more solute than it should be able (its over full) it is: A. Unsaturated B. Saturated C. Supersaturated 4. A solution is saturated at 25 g per 100g of H2O. If 25 grams is dissolved in 100g of H2O, it is: A. Unsaturated B. Saturated C. Supersaturated 5. A solution is saturated at 25 g per 100g of H2O and holds 22 grams in 100g of H2O. It is: A. Unsaturated B. Saturated C. Supersaturated 6. A solution is saturated at 25 g per 100g of H2O and holds 31 grams in 100g of H2O. It is: A. Unsaturated B. Saturated C. Supersaturated 7. A solution can hold 10 grams per 100g of H2O. If 8 g is dissolved in 100g of H2O of water, it is: A. Unsaturated B. Saturated C. Supersaturated 8. A solution can hold 15 grams per 100g of H2O. If it holds 30 g in 200g of H2O of water, it is: A. Unsaturated B. Saturated C. Supersaturated 9. A solution can hold 12 grams per 100g of H2O. If it holds 35 g in 200g of H2O of water, it is: A. Unsaturated B. Saturated C. Supersaturated 10. A solution can hold 9 grams per 100g of H2O. If it holds 15 g in 200g of H2O of water, it is: A. Unsaturated B. Saturated C. Supersaturated LESSON 3 CONCENTRATIONS KEY CONCEPTS / SUMMARY Concentration of solution expresses the amount of solute dissolved in a given quantity of solvent. Concentration can be express in different ways. Percent by Mass/Weight % m/m = mass of solute / mass of solution x 100 Percent by Volume % v/v = volume of solute / volume of solution x 100 Percent by Mass / Volume % m/v = mass of solute / volume of solution NOTES Layering The layering seen in a solution which has passed its saturation point resembles the layering seen when two insoluble substances are mixed. But, as you can see in the illustration below, these two situations are actually quite different. One of the layers in the saturated solution contains both solute and solvent while the layers in the insoluble mixture contain only one substance per layer. The extra solute added to a saturated solution may settle either to the top or to the bottom of the solution. The location of the extra solute depends on its density, a concept we will discuss in a later lesson. Dilution In lab, you will often be given a stock solution which you will need to dilute to a given concentration for use in a lab exercise. Dilution consists of adding more solvent to a solution so that the concentration of the solute becomes lower. The total number of solutes in the solution remains the same after dilution, but the volume of the solution becomes greater, resulting in a lower molarity, ppm, mg/L, or % concentration. In the picture above, I've shown the solute as yellow dots and the solvent as solid blue. The 1 L beaker on the left shows the initial concentration, which we might represent as 13 dots/L. The beaker on the right is the result of dilution of the left beaker. We added more solvent so that the solution's total volume was 3 L. As a result, the concentration of the diluted beaker is (13 dots)/(3 L), or 4.3 dots/L. Predicting the factors that affect rate of dissolving How would you increase the rate at which the sugar dissolves? How would you decrease the rate at which the sugar dissolves? Temperature Factor Agitation Particle Size Increase Increase Decrease Decrease Decrease Increase Temperature and Solubility Solubility data always includes the temperature... why? → Temperature greatly affects solubility re: energy is required to break the bonds holding a solid together → higher temperature provides this energy i.e. caffeine solubility @ 25C = 2.2.g/100mL; @ 100C = 40g/100mL Temperature is less important when we discuss the solubility of a liquid... why? → Bonds holding the liquid together are not as strong How would you expect temperature to affect the solubility of a gas? → Being dissolved in a liquid limits the high kinetic energy of a gas, therefore solubility of a gas decreases with increased temperature\ Pressure and Solubility Pressure not as important in the solubility of solids and liquids as it is for gases example: why do you hear the sound of escaping gas when you open the lid of a carbonated drink? → pressure in the sealed bottle is much higher than atmospheric therefore solubility of the carbon dioxide is much higher opening it decreases the pressure to atmospheric and carbon dioxide becomes less soluble PERCENT COMPOSITION PERCENT = PART WHOLE x 100 1. Percent - Mass in a total volume (m/v) Most frequently used form of %. A 5% solution means 5 grams in 100 mL volume. Or 2.5 grams in 50 mL volume. A 5 mg% solution means 5 mg in 100 mL volume. Same as 5 mg/dL. (dL = 100 mL 2. Percent- Mass of solute and mass of solution (m/m) This refers to the amount of solute in grams in the total solution also in grams. Example: A 10% aqueous NaCl solution contains 10 g of NaCl in 90 g of water (or 10 g NaCl per 100 g of solution). 3. Percent - Volume of solute in volume of solution. (v/v) This refers to relative amounts of two liquids in solution. Example: An alcoholic beverage that is 7% alcohol contains 7 ml of alcohol per 100 ml of solution. Ratios of individual liquids is generally given rather than %. Example: A chromatography solvent was chloroform: methanol: water (6:3:1). Problems 1. How many grams of sugar are needed to make 100 ml of a 20% solution? 2. What is the concentration in mg % of 100 mg of NaCl dissolved in 500 ml of solution? 3. How many grams of sugar are needed to make 150 ml of a 30% solution: 4. I have 250 ml of a .9% NaCl solution (saline). How many grams of salt do I have ? 5. How many grams of sugar are need to make 50 grams of a 3% solution? MOLAR SOLUTIONS Molar solutions are used more frequently and are more precise than the percent solutions. Molarity = moles liters 1. How would I make up 500 mL of a 1 M solution of NaCl? moles = grams Molarity = MW moles L 1 = x moles 0.5 L x = 0.5 = 0.5 moles x grams 58.5 x = 29.25 grams Put 29.25 g NaCl in flask, stir, add H2O and bring up to 500 ml 2. How would we make up 250 mL of a 3 M solution of NaCl? 3. How much NaCl would I need to make up 10 ml of a 6 M solution? 4. How many grams of Ca(CO3) would I need for 100 ml of a 2 M solution? 5. I have 29.25 g NaCl in 500 ml. What is its molarity? LABORATORY ACTIVITY TESTING HYPOTHESIS ON DISSOLVING Your task is to create and test a hypothesis concerning what kind of solution dissolve in each other. For each of the suggested chemical systems choose two liquids as solvent. You are to complete the Hypothesis, Prediction, Analysis and Evaluation. Submit a written report of your experiment. QUESTION Do water, table salt, table sugar, kerosene, ammonia (spirit of ammonia- aromatic) and ethyl alcohol dissolve in each other? HYPOTHESIS Create a testable hypothesis about what kind (classes) of substances dissolve in each other. PREDICTION Write a prediction based on your hypothesis. For each prediction, use your hypothesis to provide reasoning behind the prediction. EXPERIMENTAL DESIGN Each of the solute is mixed with the specified liquid solvent to determine if it dissolves. Take note that the quantities of solute, solvent, the temperature and stirring are controlled variables. EVIDENCE Tabulate your result SOLVENT SOLUTE Table salt Table sugar Kerosene Ammonia Water Ethyl alcohol ANALYSIS Answer the Question using a summary of the evidence collected. EVALUATION a. Are your predictions useful, falsified or inconclusive? Justify your answer by comparing the experimental and predicted result. b. Based on your answer to (a), is your hypothesis acceptable? The Degree of Saturation of a Solution Purpose: • To prepare aqueous solutions of sodium acetate with different degrees of saturation. • To study the properties of these solutions. Introduction: A solute can dissolve in a given amount of solvent to give three different kinds of solution. The resulting solution can be unsaturated (contain less solute than the solvent is capable of holding), saturated (contain the maximum amount of solute that the solvent is capable of holding), or supersaturated (contain more than the amount of solute that the solvent is normally capable of holding under the given conditions). In this experiment, you will prepare solutions of each type, identify them, and study some of their properties. Apparatus: 150 mm test tubes (2) burner rubber stopper 250 mL beaker test tube holder glass stirring rod Materials: anhydrous sodium acetate (hydrated sodium acetate) Procedure: A. Place 10mL of distilled water in a 150 mm test tube. Add a few milligrams (a few tiny crystals) of anhydrous sodium acetate. OR Place 5.0mL of distilled water in a 150 mm test tube. Add a few milligrams (a few tiny crystals) of hydrated sodium acetate. Close the test tube with a rubber stopper and shake it vigorously for 30 s. Add a few more crystals and shake the test tube again for another 30 seconds. B. Now add 8.0 g of the sodium acetate to the solution. Stopper the test tube and shake it vigorously for 1 min. Wait 1 min to allow settling of any undissolved matter. Use a glass stirring rod to push any solid that is above the liquid down into the liquid. Pour the clear upper liquid into a dry test tube. To the clear liquid in the second test tube add a few crystals of anhydrous sodium acetate, stopper, and shake vigorously for 1 min. Make very careful observations of the test tube. C. Allow the cold-water tap to run so that at the end of part C you will have the coldest water possible. Pour the contents of the second test tube back into the first tube and add an extra 2.0 g of the sodium acetate. Holding the test tube in a nearly horizontal position and taking care not to point the open end at anyone, heat the liquid gently (by moving the test tube in and out of the flame) to dissolve the solid present. Avoid "bumping" (sudden irregular, bubbling) which might cause you to lose some of the contents of the test tube. Use a glass-stirring rod to push as much solid at the top of the test tube down into the liquid. Continue the gentle heating until all of the solid has dissolved. D. Gently place the test tube in a beaker of cold water and allow it to remain undisturbed for 5 min. If crystals appear at any point, remove the test tube, reheat it gently to re-dissolve the crystals, and place the test tube in water for another 5 minutes. Gently remove the test tube and add one or two tiny crystals of the sodium acetate. Making Sense of the DATA 1. What kind of solution did you have in part A? How do you know? 2. What kind of solution was the clear liquid that you added to the second test tube in part B? How do you know? 3. What kind of solution did you have in part D before the crystals of the sodium acetate were added? How do you know? 4. What kind of solution did you have in part D after the crystals were added? 5. What happens when a small particle of solute is added to an unsaturated solution? Explain. 6. What happens when a small particle of solute is added to a saturated solution? Explain. 7. What happens when a small particle of solute is added to a supersaturated solution? Explain. Questions to Ponder 8. Why did your second test tube in part B have to be dry? 9. Devise a test to determine whether a solution is unsaturated, saturated, or supersaturated. 10. Would it be possible to form a supersaturated solution of a compound whose solubility decreases with increasing temperature? Explain. CHAPTER TEST TYPE I MULTIPLE-CHOICE QUESTIONS In each of the following multiple-choice questions, place the letter of the correct response in the blank at the left. There is only one correct response for each question. _____1 In a solution, the solvent is ______ a) the substance being dissolved. b)always a liquid. c) the substance present in the greatest amount. d) always water. _____2 A solution may contain _______ a)only one solvent but many solutes. b) many solvents but only one solute. c) only one solvent and one solute. d)many solvents and many solutes. _____3 a Which of the following statements concerning a saturated solution is incorrect ? a)Undissolved solute must be present. b)Undissolved solute may or may not be present. c)Undissolved solute, if present, is continually dissolving. d)Undissolved solute, if present, is in equilibrium with dissolved solute. _____4 b Which of the following statements concerning factors that affect solute solubility is incorrect? a)Most solid solutes become more soluble in water with increasing temperature. b)Most solid solutes become less soluble in water with decreasing pressure. c)Gaseous solutes become less soluble in water with increasing temperature. d)Gaseous solutes become more soluble in water with increasing pressure. _____ 5. The solubility rule “like dissolves like” is not adequate for predicting solubilities when the solute is ____ a(n)a)nonpolar gas. c)nonpolar liquid. b) ionic compound. d)polar gas. _____ 6. For which of the following types of ionic compounds are most examples insoluble in water? a)nitrates b)sulfates c)phosphates d)acetates _____ 7. Which of the following statements about solutions is correct? a) A solution is a homogeneous mixture. b) It is possible to have solutions in which both solute and solvent are solids. c) Solutions readily separate into solute and solvent if left undisturbed for 24hours. d) (more than one correct response)no correct response _____ 8. A crystal of solid NaCl is placed into an aqueous NaCl solution. It is observed that most, but not all, of the crystal dissolves. This means the original solution was_______ a) supersaturated. c) dilute. b) unsaturated. d) (more than one correct response)no correct response _____ 9. Which of the following types of antiparticle attractions must be overcome in order for a solute to dissolve in a solvent? a)solute-solute b)solvent-solvent c)solute-solvent d)more than one correct responsee)no correct response Consider the following substances and their polarities: A – polar, B – polar, C – nonpolar, D – nonpolar. _____ 10. It is true that a)A is more soluble in C than in B. b)C is more soluble in D than in A. c)D is more soluble in B than in C. d)more than one correct responsee)no correct response _____ 11. Particles of the dispersed phase in a colloidal dispersion are a)small enough that they cannot be seen by the naked eye. b)large enough that they settle out under the influence of gravity. c)small enough that they cannot be filtered out using filter paper. d)more than one correct responsee)no correct response _____ 12. In which of the following pairs of properties are both members of the pair colligative properties? a)density, boiling point b)vapor pressure, osmotic pressure c)solubility, freezing point d)more than one correct responsee)no correct response8 _____ 13. In which of the following pairings of terms are the terms closely related? a)hemolysis, hypotonic solution b)hypertonic, higher osmotic pressure than within cells c)isotonic solution, crenation d)more than one correct responsee)no correct response _____ 14. Which of the following statements concerning dialysis iscorrect ? a)Only water passes through the dialyzing membrane. b)Dissolved ionic substances and small molecules are separated from colloidal particles. c)Two types of colloidal particles are separated from each other. d)more than one correct responsee)no correct response CHOICE FORMAT TRUE-FALSE QUESTIONS In each of the following multiple-choice questions, characterize EACH of the three given statementsas being TRUE or FALSE and then indicate the collective true-false status of the statements using thechoices a) All three statements are true. b) Two of the three statements are true. c) Only one of the statements is true. d) None of the statements is true. ______ 1. a. A saturated solution always contains excess undissolved solute. b. In aqueous solution Ba2+ion combines with NO3-ion to produce an insolub lesalt. c. Addition of a nonvolatile solute to a solvent produces a solution with lower vapor pressure, freezing point, and boiling point than that of pure solvent. _____ 2. a. Equal volumes of two solutions of the same molarity contain the same number of grams of solute b. Hemolysis and crenation are “opposite” processes. c. The solubility rule “like dissolves like” is not adequate for predicting thesolubility of ionic compounds in water. _____ 3. a. In a colloidal dispersion solute particles are large enough to be discernible bythe naked eye. b. The selectivity of a semi-permeable membrane is based on polarity differencesamong molecules. c. For dilute aqueous solutions, %(m/m) and %(m/v) concentration units havealmost the same magnitude because the density of water is 1.00 g/mL andthe solution is almost entirely water. _____4. a. TheTyndall effect involves light-scattering by colloidal-sized particles. b. Aqueous solutions of 0.1 M KCl and 0.1 M glucose would have the samefreezing point because the solvent is water in both cases. c. Percent by volume is a concentration unit used when both solute and solventare liquids. _____ 5. a. To find the molarity of a solution, both solution volume and the number of moles of solute must be known. b. Osmosis involves the passage of solvent from a dilute solution (or pure solvent) into a more concentrated solution. c. 5.0 %(m/v) glucose solution and 0.9 %(m/v) sodium chloride solution have the same osmolarity and are hypotonic relative to red blood cells. Prepared By: Sheila Marie R. Visda