Product Name: Amyl Alcohol, (n-) (1-pentanol) Reagent
Synonyms/Generic Names: 1-Pentanol, Primary Amyl Alcohol, n-Butylcarbinol
Product Number: 0600
Product Use: Industrial, Manufacturing or Laboratory use
Manufacturer: Columbus Chemical Industries, Inc.
N4335 Temkin Rd.
Columbus, WI. 53925
For More Information Call: 920-623-2140 (Monday-Friday 8:00-4:30)
In Case of Emergency Call: CHEMTREC - 800-424-9300 or 703-527-3887 (24 Hours/Day, 7 Days/Week)
OSHA Hazards: Combustible liquid, Target organ effect, Irritant
Target Organs: Central nervous system
Signal Words: Warning
Pictograms:
GHS Classification:
Flammable liquids
Acute toxicity, Inhalation
Skin irritation
Eye irritation
Category 3
Category 4
Category 2
Category 2A
Specific target organ toxicity-single exposure Category 3
GHS Label Elements, including precautionary statements:
Hazard Statements:
H226
H315
Flammable liquid and vapor.
Causes skin irritation.
H332
H335
Harmful if inhaled.
May cause respiratory irritation.
Precautionary Statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
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P233
P240
P241
P242
P243
P261
P271
P280
Keep container tightly closed.
Ground/Bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313
P337+P313
P362+P364
P370+P378
P403+P235
P501
Potential Health Effects
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
In case of fire: Use appropriate media to extinguish.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local regulations.
Eyes
Inhalation
Skin
Ingestion
NFPA Ratings
Causes eye irritation.
May be harmful if inhaled. Causes respiratory tract irritation.
May be harmful if absorbed through skin. Causes skin irritation.
May be harmful if swallowed.
HMIS Ratings
Health
Flammability
1
3
Reactivity 0
Specific hazard Not Available
Health
Fire
Reactivity
Personal
1
3
0
H
Amyl Alcohol >99 71-41-0 200-752-1 C
5
H
12
O 88.15 g/mol
Eyes
Skin
Rinse with plenty of water for at least 15 minutes and seek medical attention if necessary.
Inhalation Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention if necessary.
Flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention if necessary.
Ingestion Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately if necessary.
Suitable (and unsuitable) extinguishing media
Product is flammable. Use alcohol foam, dry chemical, or carbon dioxide for small fires. Use large amounts of water applied as mist or
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Special protective equipment and precautions for firefighters
Specific hazards arising from the chemical spray from a distance for large fires. Cool unopened containers with water. Use appropriate media for adjacent fire.
Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots.
Emits toxic fumes (carbon oxides) under fire conditions. See also
Stability and Reactivity section.
Personal precautions, protective equipment and emergency procedures
See section 8 for recommendations on the use of personal protective equipment. Avoid breathing vapors, mist or gas. Use with adequate ventilation and remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations.
Vapors can accumulate in low areas.
Environmental precautions
Methods and materials for containment and cleaning up
Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements.
Neutralize spill with sodium bicarbonate or lime. Absorb spill with noncombustible absorbent material, then place in a suitable container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations.
Precautions for safe handling
See section 8 for recommendations on the use of personal protective equipment. Avoid contact with skin and eyes. Avoid inhalation of vapors/mists. Keep away from sources of ignition. Not smoking. Take measures to prevent the buildup of electrostatic charge. Keep container closed when not in use.
Conditions for safe storage, including any incompatibilities
Store in cool, dry well ventilated area. Keep container tightly closed. Keep away from incompatible materials
(see section 10 for incompatibilities).
Occupational exposure controls: Ventilation and appropriate grounding of containers.
Component Exposure Limits Basis Entity
Pentanol 100 ppm
150 ppm
TWA: Time Weighted Average over 8 hours of work.
TLV: Threshold Limit Value over 8 hours of work.
REL: Recommended Exposure Limit
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit during x minutes.
IDLH: Immediately Dangerous to Life or Health
WEEL: Workplace Environmental Exposure Levels
CEIL: Ceiling
WEEL
STEL
USA AIHA
USA AIHA
Personal Protection
Eyes Wear chemical safety glasses or goggles.
Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator.
Skin
Other
Wear nitrile or rubber gloves, apron or lab coat.
Not Available
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Other Recommendations
Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling.
Appearance (physical state, color, etc.)
Odor
Odor threshold pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limit
Vapor pressure
Vapor density
Relative density
Solubility (ies)
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Clear, colorless liquid
Alcohol-like, sweetish, fusel-like
Not Available
~7
-79°C (-180°F)
136-138°C (277-280°F)
49°C (120°F)
Not Available
Flammable liquid and vapor
UPPER: 10%(V) LOWER: 1.2%(V)
2.0 hPa (1.5mmHg)
3.04 (air=1)
0.81 (water=1)
Soluble in acetone. Partially soluble in water (22.8g/L).
Log Pow: 1.51
Not Available
Not Available
Chemical Stability Stable
Possibility of Hazardous Reactions Will not occur.
Conditions to Avoid
Incompatible Materials
Heat, flames, sparks.
Strong oxidizing agents, alkali metals, strong acids, halides, aldehydes.
Hazardous Decomposition Products Carbon oxides.
Acute Toxicity n-Amyl Alcohol
Skin
Eyes
Respiratory
Ingestion
LD50 Dermal – Rabbit – 2,306 mg/kg
Eyes – Rabbit – 24h – Severe eye irritation
LC50 Inhalation – Mouse – 14000 mg/m – 6hr
LD50 Oral – Mouse – 200 mg/kg - Anesthetic
LD50 Oral – Rat – 3670 mg/kg
Carcinogenicity
IARC
ACGIH
NTP
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
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Signs & Symptoms of Exposure
Skin Irritation, redness, itching.
Eyes Irritation, watering, redness.
Respiratory Burning sensation of mucous membranes, difficulty breathing.
Ingestion Nausea, vomiting, staggering gait, dizziness, drowsiness, delirium, disorientation.
Chronic Toxicity Pulmonary edema and kidney injury.
Teratogenicity Not Available
Mutagenicity Mutagenetic for bacteria and/or yeast.
Embryotoxicity Not Available
Specific Target Organ Toxicity Not Available
Reproductive Toxicity Not Available
Respiratory/Skin Sensitization Not Available
Ecotoxicity n-Amyl Alcohol
Aquatic Vertebrate LC50 – Oncorhynchus mykiss (rainbow trout) – 370mg/L – 96hr
Aquatic Invertebrate EC50 – Daphnia magna (water flea) – 341 mg/L – 48hr
Terrestrial Not Available
Persistence and Degradability Readily 97% biodegradable.
Bioaccumulative Potential Not Available
Mobility in Soil
PBT and vPvB Assessment
Other Adverse Effects
Not Available
Not Available
Not Available
Waste Product or
Residues
Product
Containers
Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue.
Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container.
The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods.
US DOT
TDG
IMDG
Marine Pollutant
IATA/ICAO
UN1105, Pentanol, 3, pg III
UN1105, PENTANOL, 3, pg III
UN1105, PENTANOL, 3, pg III
No
UN1105, Pentanol, 3, pg III
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TSCA Inventory Status
DSCL (EEC)
California Proposition 65
SARA 302
SARA 304
SARA 311
SARA 312
SARA 313
WHMIS Canada
All ingredients are listed on the TSCA inventory.
All ingredients are listed on the DSCL inventory.
Not Listed
Not Listed
Not Listed
Fire Hazard
Fire Hazard
Not Listed
Class B-2: Flammable and combustible liquid- Flammable liquid
Revision 1
Revision 2
06-12-2012
07/31/2013
Revision 3 11/04/2015
Disclaimer: Columbus Chemical Industries, Inc. (“Columbus”) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION)
WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED
HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE.
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