CHEMISTRY Jim Hollister Definition of Terms NOTE: You will not usually be tested on definitions, but on homework problems, as calculations and nomenclature problems. Still, you must understand the basic terms to understand chemistry. Atom — The basic particle from which matter is constructed. (The smallest part of an element which can enter into a reaction (combine with other atoms) to form chemical compounds.) mixture — Pure substances which exist together without chemically combining; the relative amounts of each substance can vary. pure substance — A single chemical or one kind of matter having its own unique set of chemical and physical properties; either element or compound. element — A pure substance that can not be decomposed into other pure substances by ordinary chemical means. A pure substance that consists only of atoms with the same nuclear charge (see atomic number below). compound — A pure substance that can be decomposed into two or more other pure substances by a chemical exchange. Example: CaS => Ca + S . The relative amounts of the combined substances never varies. molecules — Two or more atoms joined by a chemical bond. (The smallest unit particle of a substance (compound or polyatomic element) which can exist independently and possess the identity of the substance.) diatomic molecules — A molecule of just two atoms. Can be heteronuclear or homonuclear. Learn " I Brought Clay From Our New Home." as a mnemonic device to memorize those elements which, when not combined with other elements, normally occur in nature as homonuclear molecules. metal — Has luster, is a good conductor of electricity and heat, and is malleable and ductile. The metals compose about two-thirds of the elements in nature. non-metal — Has no luster, is not a good conductor and is not malleable or ductile. chemical symbols — Abbreviations for elements. ion — A species that has either a deficiency of electrons ( in which case the ion is positively charged) or an excess of electrons ( in which case the ion is negatively charged). periodic table — An arrangement of the elements according to increasing atomic number, such that elements with similar properties are in the same columns (groups) of the table. period — A horizontal row of the Periodic Table. group —All elements in the same column of the Periodic Table which have similar properties. Also called a family. Newer Periodic Tables use all Arabic numbers for all groups, groups 1 through 18. (In older Periodic Tables, groups are usually indicated with Roman numerals.) Definition of Terms continued transition metals — elements belonging to groups between groups 2 and 13. (In older texts, group 13 is called group 3 or (III).) oxidation state — A common charge assigned to an atom or ion. atomic mass unit — A unit of mass that is exactly 1/12 of the mass of an atom of carbon-12. ----------------------------------Numbers Associated with Elements--------------------------------atomic mass (atomic "weight") — The average mass of the atoms of an element expressed in atomic mass units (compared to mass of atom of Carbon 12 at a value of exactly 12.) (See atomic mass unit above). atomic number(Z) — Equals the number of protons in each atom of an element. It does not change, thus, each element is characterized by its atomic number. mass number (A =Z+N) — Atomic number (Z) + number of neutrons (N). It is a whole number (integer). (You must round off the atomic mass from the periodic table to a whole number to get the mass number.) isotope — Two or more atoms of the same element which have different atomic masses because of different numbers of neutrons. molecular mass (molec. "weight") — The sum of the atomic masses of the constituent elements of a molecule or compound. (The average mass of molecules of a compound in a.m.u.s.) -----------------------------------------------------------------------------------------------------------------mole — 1) One mole of any substance has a mass in grams which equals the numerical value of its relative atomic or molecular mass. 2) One mole equals the amount of a substance that contains 6.022 x 1023 units, which is the same number of units as the number of atoms in exactly 12g of Carbon-12. (Units could be atoms, molecules, ions, etc.) (6.022 x 1023 is called Avogadro's Number and its algebraic symbol is N0 ). 3) One mole of any gas occupies 22.4 liters at Standard Temperature and Pressure (=STP: 0O C and one atmosphere).