AP Chemistry Practice Test #1 - Key Chapters 1, 2, and 3 1. In 1928, 3.3 g of a new element was isolated from 660 kg of the ore molybdenite. The percent by mass of this element in the ore was: a. b. c. d. e. 5% 6.6 % 3.3 % 5.0x10-4 % 2.2 % 2. A quantitative observation a. b. c. d. e. contains a number and a unit. does not contain a number. always makes a comparison. must be obtained through experimentation. none of these 3. Which of the following is the least probable concerning five measurements taken in the lab? a. b. c. d. e. The measurements are accurate and precise. The measurements are accurate but not precise. The measurements are precise but not accurate. The measurements are neither accurate nor precise. All of these are equally probable. 4. A scientist obtains the number 0.045006700 on a calculator. If this number actually has four (4) significant figures, how should it be written? a. b. c. d. e. 0.4567 0.4501 0.045 0.04500 0.04501 5. A piece of indium with a mass of 16.61 g is submerged in 46.3 cm3 of water in a graduated cylinder. The water level increases to 48.6 cm3. The correct value for the density of indium from these data is: a. b. c. d. e. 7.222 g/cm3 7.2 g/cm3 0.14 g/cm3 0.138 g/cm3 more than 0.1 g/cm3 away from any of these values. 6. Using the rules of significant figures, calculate the following: 4.0021 – 1.013 a. b. c. d. e. 2.989 3 2.9891 2.99 3.0 7. Convert 4324 mL to qts. (1 L = 1.06 qt) a. b. c. d. e. 4583 qts 4.079 qts 4.079e-3 qts 4079 qts 4.583 qts 8. A monolayer containing 3.15e-6 g of oleic acid has an area of 20.0 cm2. The density of oleic acid is 0.895 g/mL. What is the thickness of the monolayer (the length of an oleic acid molecule)? a. b. c. d. e. 7.04e-5 cm 5.68e6 cm 1.41e-7 cm 1.76e-7 cm 1.41e-7 cm 9. The density of gasoline is 0.7025 g/mL at 20oC. When gasoline is added to water: a. b. c. d. e. it will float on top. it will sink to the bottom. it will mix so you can’t see it. the mixture will improve the running of the motor. none of these things will happen. 10. A freighter carrying a cargo of uranium hexafluoride sank in the English Channel late August 1984. The cargo of uranium hexafluoride weighed 2.251e8 kg and was contained in 30 drums, each having a volume of 1.62x106L. What is the density (g/mL) of uranium hexafluoride? a. b. c. d. e. 1.39 g/mL 4.63 g/mL 2.25 g/mL 0.216 g/mL 46.3 g/mL 11. Which of the following pairs of compounds can be used to illustrate the law of multiple proportions? a. b. c. d. e. 12. NH4 and NH4Cl ZnO2 and ZnCl2 H2O and HCl NO and NO2 CH4 and CO2 40 2+ 20 Ca a. b. c. d. e. has 20 protons, 20 neutrons, and 18 electrons. 22 protons, 20 neutrons, and 20 electrons. 20 protons, 22 neutrons, and 18 electrons. 22 protons, 18 neutrons, and 18 electrons. 20 protons, 20 neutrons, and 22 electrons. 13. Which of the following name(s) is(are) correct? 1) sulfide S22) ammonium chloride NH4Cl 3) acetic acid HC2H3O2 4) barium oxide BaO a. b. c. d. e. all none 1, 2 3, 4 1, 3, 4 14. Which of the following statements is (are) true? a. b. 18 O 148 6C c. 18 28O and and 19 F 149 7N have the same number of neutrons. are isotopes of each other because their mass numbers are the same. has the same number of electrons as 20 10 Ne . d. a and b e. a and c 15. The formula for calcium bisulfate is a. b. c. d. e. Ca(SO4)2 CaS2 Ca(HSO4)2 Ca2HSO4 Ca2S 16. All of the following are in aqueous solution. Which is incorrectly named? a. b. c. d. e. H2SO4, sulfuric acid H3PO4, phosphoric acid H3PO4, phosphoric acid HCN, cyanic acid HCl, hydrochloric acid 17. Write the names of the following compounds: a) b) c) d) e) FeSO4 NaC2H3O2 KNO2 Ca(OH)2 NiCO3 __iron(II) sulfate_______ __sodium acetate_______ __potassium nitrite_____ _ calcium hydroxide___ __nickel(II) carbonate__ 18. You are given a compound with the formula MCl2, in which M is a metal. You are told that the metal ion has 26 electrons. What is the identity of the metal? a. b. c. d. e. Co Al Fe Cr Ni 19. The atomic mass of rhenium is 186.2. Given that 37.1% of natural rhenium is rhenium-185, what is the other stable isotope? a. 183 75 Re b. 187 75 Re c. 189 75 Re d. 181 75 Re e. 190 75 Re 20. Naturally occurring copper exists in two isotopic forms: Copper-63 and Copper-65. The atomic mass of copper is 63.55 amu. What is the approximate natural abundance of Copper63? a. b. c. d. e. 63% 90% 70% 50% 30% 21. For which compound does 0.256 mole weigh 12.8 g? a. b. c. d. e. C2H4O CO2 CH3Cl C2H6 none of these 22. A given sample of xenon fluoride contains molecules of a single type XeFn, where n is some whole number. Given that 9.03 x 1020 molecules of XeFn weigh .311 g, calculate n. a. b. c. d. 1 2 4 none of these 23. How many atoms of hydrogen are present in 5.5 g of water? a. b. c. d. e. 1.8e23 1.6e24 6.6e24 3.7e23 0.61 24. What is the molar mass of cryolite (Na3AlF6)? a. b. c. d. e. 209.9 185.3 210.0 104.2 68.97 25. What is the coefficient for water when the following equation is balanced? As(OH)3(s) + H2SO4(aq) → As2(SO4)3(aq) + H2O(l) a. b. c. d. e. 1 2 4 6 12 26. You take an aspirin tablet (a compound consisting solely of carbon, hydrogen, and oxygen) with a mass of 1.00 g, burn it in air, and collect 2.20 g of carbon dioxide and 0.400 g of water. The molar mass of aspirin is between 170 and 190 g/mol. The molecular form of aspirin is a. b. c. d. e. C6H8O5 C9H8O4 C8H10O5 C10H6O4 none of these 27. Suppose the reaction Ca3(PO4)2 + 3H2SO4 → 3CaSO4 + 2H3PO4 is carried out starting with 103 g of Ca3(PO4)2 and 26.7 g of H2SO4. How much phosphoric acid will be produced? a. b. c. d. e. 26.7 g 17.8 g 239.8 g 40.0 g 65.1 g 28. An oxide of iron has the formula Fe3O4. What mass percent of iron does it contain? a. b. c. d. e. 0.72% 28% 30.% 70.% 72% 29. A chloride of rhenium contains 63.6% rhenium. What is the formula of this compound? a. b. c. d. e. ReCl ReCl3 ReCl5 ReCl7 Re2Cl3 30. The empirical formula of styrene is CH; it molar mass is 104.1. What is the molecular formula of styrene? a. b. c. d. e. C2H4 C8H8 C10H12 C6H6 none of these 31. Adipic acid contains 49.32% C, 43.84% O, and 6.85% H by mass. What is the empirical formula? a. b. c. d. e. C3H5O2 C3H3O4 C2HO3 C2H5O4 C3HO3 32. Vitamin C contains the elements C, H, and O. It is known to contain 40.9% C and 4.58% H by mass. The molar mass of vitamin C has been found to be about 180. The molecular formula for vitamin C is: a. b. c. d. C2H3O2 C3H4O3 C4H6O4 C6H8O6 33. When 223.0 g of ethylene (C2H4) burns in oxygen to given carbon dioxide and water, how many grams of CO2 are formed? a. b. c. d. e. 699.7 g 349.9 g 174.9 g 7.95 g 286.4 g 34. Determine the coefficient for O2 when the following equation is balanced in standard form (smallest whole number integers) C4H10(g) + O2(g) → CO2(g) + H2O(g) a. b. c. d. e. 4 8 10 13 20 35. wPCl5 + xH2O → yPOCl3 + zHCl The above equation is properly balanced when a. b. c. d. e. w = 1, x = 2, y = 2, z = 4 w = 2, x = 2, y = 2, z = 2 w = 2, x = 2, y = 2, z = 1 w = 1, x = 1, y = 1, z = 2 none of these 36. A 6.35-g sample of potassium chlorate was decomposed according to the following equation: 2KClO3 → 2KCl + 3O2 How many moles of oxygen are formed? a. b. c. d. e. 2.49 g 0.0518 mol 0.0345 mol 0.0777 mol none of these 37. How many grams of H2O will be formed when 32.0 g H2 is mixed with 18.0 g of O2 and allowed to react to form water? a. b. c. d. e. 20.3 g 286 g 10.1 g 5.1 g 144 g 38. A 15-g sample of lithium is reacted with 15 g of fluorine to form lithium fluoride: 2Li + F2 → 2LiF. After the reaction is complete, what will be present? a. b. c. d. e. 2.16 moles lithium fluoride only 0.789 moles lithium fluoride only 2.16 moles lithium fluoride and 0.395 moles fluorine 0.789 moles lithium fluoride and 1.37 moles lithium none of these 39. The following two reactions are important in the blast furnace production of iron metal from iron ore (Fe2O3): 2C(s) + O2(g) → 2CO(g) Fe2O3 + 3CO(g) → 2Fe + 3CO2(g) Using these balanced reactions, how many moles of O2 are required for the production of 2.35 kg of Fe? a. b. c. d. e. 31.6 moles 14.0 moles 126 moles 42.1 moles 1.76 moles 40. The reaction of 11.9 g of CHCl3 with excess chlorine produced 13.3 g of CCl4, carbon tetrachloride: 2CHCl3 + 2Cl2 → 2CCl4 + 2HCl What is the percent yield? a. b. c. d. e. 100.% 43.4% 86.8% 112% 57.8%