Chemistry 130
Final Exam
Spring 2007
June 13,2007
Oregon State University
Dr. Richard Nafshun
Fill in the front page of the Scantron answer sheet with your last name, first name, middle initial, and
student identification number. Leave the class section number and the test form number blank.
This exam consists of 22 multiple-choice questions. Each multiple-choice question has five points
associated with it. Select the best multiple-choice answer by filling in the corresponding circle on the
rear page of the answer sheet.
benzene
to1uen e
aniline
styrene
chlorobenzene
nitro benze ne
phenol
benzaldehyde
benzoic acid
bromobenzene
benzonitrile
benzenesulfonic
acid
Alcohols
R-OH
Am i nes
O
R-NH2
O
II
II
Aldehydes
R-C-H
Ketones
R-C- Rr
Ethers
R-0-R'
-Thioalcohols R S H
-
O
II
Carboxylic Acids R - C - O H
D i s ~ ~ l f i d e sR-S-S-
O H
O
II
1.
Rr
II
I
Esters
R-C-0-R'
Amides
R-C-N-Rr
Al kenes
C H 2 =CH2
Al kynes
H CG C H
What is the name of the following structure?
2.
The molecular formula of
\4
I
d
tt
(A)
(B)
;
(E)
3.
r t
4
', /
/
-
I
t-l
isC10H15N
is CloHllN
a
is C8H15N
Which of the following is NOT an isomer of 2,2,3,3-tetramethylheptane?
(A)
(B)
2,2,3,4-tetramethylheptane
4-Propyloctane
c c
\
'
C - C - c - c - c- c - c
\
1
c
c
C,,H,q
4.
Identify the products of the following substitution reaction:
(A)
(B)
(c>
(D)
(E)
6.
CH3CH3
CH30H
an acetal
tal
Which of the following is true?
(A)
CH3CH2CH3has a higher boiling point than CH3CH20CH3because of hydrogen
bonding.
(B)
CH3CH2CH3has a higher boiling point than CH3CH2CH20Hbecause of dipole-dipole
forces.
(C)
CH3CH20CH3has a higher boiling point than CH3CH2CH20Hbecause of dipole-dipole
forces.
(D)
CH3CH20CH3has a higher boiling point than CH3CH2CH20Hbecause of hydrogen
bonding.
:;*..:,
- ,.,-*,.&&-.%,.,iu".
.-;.',..,..,.
, .,
+. .,**
boiling point than CH3CH20CH3because of h
a&
.<.
,
-,.I
7.
.
"."x;.-
_,^__l.l__j__.:.__.,_
.; . ;
,,
.. , ,, .. ,,:.., ~
_ -.-
-9i-w %
.*
9,
. ..>=.>
d
.
?
.
.
.
=
,
"-/-T,...---o-.-rl~'.=.~-.3-*.~"=*
,"..-,::>.:%:-.Wx:
,%.
<.-:;
I,.;I,..,.,-.,
In a condensation reaction, an arnine and a carboxylic acid produce:
(A)
(B)
(C)
(D)
(E)
an ether
an ester
an aldehyde
a ketone
:,.
-,. -**,--%v
... *;.:
a
i
qs...,v
.,~.."-" ,<., ~-,4fld..7
8.
I
In a CH 130 Lab you isolated an analgesic drug. It was either acetaminophen or ibuprofen.
-rc.=-----".a-
(A)
(B)
9.
.--miE,
%_
,
,,
,
,
,
_mxB$
..--,
*G&.tam&09he2_"haS,a,hjg&l:
ibuprofen has a higher melting point
Thenarneof
(A)
is 1-methyl-3-bromocycloheaxane
(B)
is 1,3-bromobenzene
(C)
is o-bromotoluene
(D)
is m&caa@gluene
(E) e m *
10.
Consider the formation of hemiacetals, acetals, hemiketals and ketals. The molecule below can
be formed from:
0
and
dCH3
v
HO
and
0
(El
0
II
and
vc\
H
11.
Complete the following addition reaction:
,"o
12.
+
HCl
Which of the following functional groups is not present in Penicillin-G?
13.
The oxidation number of HCOOH is:
14.
Pro-Ala-Ala-Met-Leu-Gly-Pro-Ala-Pro-Phe is an example of
(A)
(B)
(C)
quaternary structure
secondary structure
(D) tertiary structure
(E)
soap
15.
The pH of a sample of California orange juice is measured to be 3.48. Therefore, the juice is:
(A)
(B)
(C)
16.
basic
neutral
Identify the number of chiral carbons and whether the sedoheptulose shown is L- or D-.
HO-C-H
I*
I*
IP
H-C-OH
H-C-OH
5 chiral carbons and L5 chiral carbons and D4 chiral carbons and Lr;T?"
chiral carbons a
m
6 chiral carl%ns and
(E)
(A)
(B)
(c)
(D,
f
17.
Which pair of compounds can react to form a hemiacetal?
(A)
(B)
(C)
(D)
(E)
18.
b
a\dchydc +
a\roL.o
\
CH3CH2CH0 and CH3COOH
CH3COCH3and CH3CH20H
CH3COOH and CH3CH20H
Which of the following statements is false?
6'3
,,&,
-,
.,+s..
, ,.:,
,.:.,,. , ?,.,g.x.,,. ,
*.k.c:
=.."- -..*+-
L.:=7.
-'.'.-~-=--~
(A
(B) a chiral molecule is
(C) the following
(D) a chiral carbon has 4 different groups bound to it T rue
(E) m-chlorotoluene is not chiral 7-rCLI
19.
The following is the structure of a carbohydrate. Which of the following statements is false:
I
Ei-
C -OH
I
HO-
(D)
It is an aldehyde r
C -N
20.
Consider the fat molecule below. Which of the following is false?
(A)
(B)
(c)
(D)
(E)
21.
fat /
nds J
it contains trans bonds
could undergo hydrogenation /
In DNA, the base pairs are G and C; A and T. It can be said that this selective pairing is due to:
(A)
the aldohexose.
(B)
omega-3 fats.
(C)
enzyme liquidizing.
carkn-m
(D)
(E) 6 d r o g e n
22.
Which of the following is FALSE?
DNA is a double helix
(A)
A strand of DNA is 5 x 10' bases in length
(B)
A
strand of DNA is 1.7 meters in length
(C)
Ad~,nine,f~ms..a,b.&s~.~air,wi!h.t1y-~~~,e
, . g u a n jwith
~ ~ cfiosine.innDeA
(Dl
(E) p m ' e a s e s a phosphate group to release energy and become ATP
J)
-----_&Y-_-_%.
,L,-,.--~-*-
,,..l.ir,..~-zd
:-"
-II-~-~*s