Material Safety Data Sheet
Azone 15, EPA No. 7870-5
24 Hour Emergency Phone: CHEMTREC 1-800-424-9300
Date of Preparation: 01/21/99
Revision: 3/10/08
Section 1 - Chemical Product and Company Identification
Synonyms:
Sodium Hypochlorite; Bleach; hypochlorous acid, sodium salt
CAS No:
7681-52-9
Molecular Weight: 74.44
Chemical Formula: NaOCl
Distributed by
Hawkins, Inc., 3100 E. Hennepin Avenue, Minneapolis, MN 55413 (612-331-6910)
Section 2 - Composition / Information on Ingredients
Ingredient
--------------------------------------Sodium Hypochlorite (as NaOCl)
Sodium Hydroxide
CAS No
-----------7681-52-9
1310-73-2
Percent
Hazardous
--------------10-15.6%
Yes
0.8%
Yes
Section 3 - Hazards Identification
Emergency Overview
-----------------DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. MAY BE FATAL IF SWALLOWED.
HARMFUL IF INHALED.
Potential Health Effects
-----------------------Inhalation:
Excessive inhalation of vapors, mists, or fumes may cause bronchial irritation,
coughing, labored breathing, nausea, and pulmonary edema. Additional effects have
included circulatory collapse and confusion, delirium, coma.
Ingestion:
May cause erosion of the mucous membranes. Symptoms include vomiting, circulatory
collapse, confusion, coma, and death. May cause edema of pharynx, glottis, and larynx
and perforation of the esophagus or stomach. Effects are less damaging at lower
concentrations.
Skin Contact:
Contact may cause severe irritation with blistering and eczema, especially at higher
concentrations.
Eye Contact:
Contact may cause severe irritation and damage, especially at higher concentration.
Chronic Exposure: A constant irritant to the eyes and throat.
Aggravation of Pre-existing Conditions:
Persons with impaired respiratory function may be more susceptible to the effects of the
substance.
Page 1 of 5
Azone 15, EPA No. 7870-5
revised: 3/10/08
24 Hour Emergency Phone: CHEMTREC 1-800-424-9300
Section 4 - First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Get medical attention immediately. Wash clothing
before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and
upper eyelids occasionally. Get medical attention immediately.
Note to Physician:
Consider oral administration of sodium thiosulfate solutions if sodium hypochlorite is
ingested. Do not administer neutralizing substances since the resultant exothermic
reaction could further damage tissue. Endotracheal intubation could be needed if glottic
edema compromises the airway. For individuals with significant inhalation exposure,
monitor arterial blood gases and chest x-ray.
Section 5 - Fire-Fighting Measures
NFPA Ratings:
Health: 3 Flammability: 0
Reactivity: 1
Fire:
Not considered to be a fire hazard. Substance releases oxygen when heated, which may
increase the severity of an existing fire. Containers may rupture from pressure buildup.
Explosion:
This solution is not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Use water spray to cool fireexposed containers, to dilute liquid, and control vapor.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other
positive pressure mode.
Section 6 - Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Collect liquid in an
appropriate container or absorb with an inert material (e. g., vermiculite, dry sand,
earth), and place in a chemical waste container. Do not use combustible materials, such
as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and
releases to soil, water and air in excess of reportable quantities. The toll free number
for the US Coast Guard National Response Center is (800) 424-8802.
Page 2 of 5
Azone 15, EPA No. 7870-5
revised: 3/10/08
24 Hour Emergency Phone: CHEMTREC 1-800-424-9300
Section 7 - Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect
against physical damage. Isolate from incompatible substances. Containers of this
material may be hazardous when empty since they retain product residues (vapors,
liquid); observe all warnings and precautions listed for the product.
Section 8 - Exposure Controls / Personal Protection
Airborne Exposure Limits:
Sodium Hypochlorite: AIHA (WEEL) - STEL - 2 mg/m3
Sodium Hydroxide: No information available
-OSHA Permissible Exposure Limit
Sodium Hypochlorite: (PEL): 0.5 ppm (TWA), 1 ppm (STEL) as Chlorine
Sodium Hydroxide: 2 mg/m3 Ceiling
-ACGIH Threshold Limit Value (TLV):
Sodium Hypochlorite: 1 ppm (TWA), 3 ppm (STEL) as Chlorine
Sodium Hydroxide: 2 mg/m3 Ceiling
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below
the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because
it can control the emissions of the contaminant at its source, preventing dispersion of
it into the general work area. Please refer to the ACGIH document, "Industrial
Ventilation, A Manual of Recommended Practices", most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with an acid gas
cartridge may be worn up to 50 times the exposure limit or the maximum use concentration
specified by the appropriate regulatory agency or respirator supplier, whichever is
lowest. For emergencies or instances where the exposure levels are not known, use a
full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying
respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or
coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible.
Maintain eye wash fountain and quick-drench facilities in work area.
Section 9 - Physical and Chemical Properties
Appearance:
Colorless to yellowish liquid.
Boiling Point:
40C (104F) Decomposes slightly
Odor:
Chlorine-like odor.
Melting Point:
–15F (12.5%)
Solubility:
100% in water.
Vapor Density (Air=1):
No information found.
Specific Gravity:
1.2 (12.5%)
Vapor Pressure (mm Hg):
Dependent on concentration
pH: > 10
Page 3 of 5
Azone 15, EPA No. 7870-5
revised: 3/10/08
24 Hour Emergency Phone: CHEMTREC 1-800-424-9300
Section 10 - Stability and Reactivity
Stability:
Slowly decomposes on contact with air. Rate increases with the concentration and
temperature. Exposure to sunlight accelerates decomposition. Sodium hypochlorite becomes
less toxic with age.
Hazardous Decomposition Products:
Emits toxic fumes of chlorine when heated to decomposition. Sodium oxide at high
temperatures.
Hazardous Polymerization: Will not occur.
Incompatibilities:
Ammonia (chloramine gas may evolve), amines, ammonium salts, aziridine, methanol, phenyl
acetonitrile, cellulose, ethyleneimine, oxidizable metals, acids, soaps, and bisulfates.
Conditions to Avoid: Light, heat, incompatibles.
Section 11- Toxicological Information
Sodium Hypochlorite:
No LD50/LC50 information found relating to normal routes of occupational exposure.
Investigated as a tumorigen and mutagen. Irritation data: eye, rabbit, 10 mg - Moderate
Sodium Hydroxide:
Irritation data: skin, rabbit: 500 mg/24H severe; eye rabbit: 50 ug/24H severe;
investigated as a mutagen.
--------\Cancer Lists\--------------------------------------------------------NTP Carcinogen--Ingredient
Known
Anticipated
IARC Category
-------------------------------------------------------------Sodium Hypochlorite (as NaOCl)
No
No
3
(7681-52-9)
Sodium Hydroxide (1310-73-2)
No
No
None
Section 12 - Ecological Information
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Section 13 - Disposal Considerations
Dilute with water and flush to sewer if local ordinances allow, otherwise, whatever
cannot be saved for recovery or recycling should be managed in an appropriate and
approved waste disposal facility. Processing, use or contamination of this product may
change the waste management options. State and local disposal regulations may differ
from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and local
requirements.
Page 4 of 5
Azone 15, EPA No. 7870-5
revised: 3/10/08
24 Hour Emergency Phone: CHEMTREC 1-800-424-9300
Section 14 - Transport Information
U.S. DOT
----------------------UN1791, HYPOCHLORITE SOLUTIONS, 8, III (Less than RQ in package)
RQ, UN1791, HYPOCHLORITE SOLUTIONS (SODIUM HYPOCHLORITE), 8, III
(Greater than RQ in package)
Section 15 - Regulatory Information
--------\Chemical Inventory Status\----------------------------------------Ingredient
TSCA EC
Japan Australia
----------------------------------------------- ---- --- ----- --------Sodium Hypochlorite (as NaOCl) (7681-52-9)
Yes Yes
Yes
Yes
Sodium Hydroxide (1310-73-2)
Yes Yes
Yes
Yes
-------\Federal, State & International Regulations - Part 1\----------------SARA 302------SARA 313-----Ingredient
RQ
TPQ
List Chemical Catg.
---------------------------------------- ---------- -------------Sodium Hypochlorite (as NaOCl)
No
No
No
No
(7681-52-9)
Sodium Hydroxide (1310-73-2)
No
No
No
No
--------\Federal, State & International Regulations - Part 2\---------------RCRA-TSCAIngredient
CERCLA
261.33
8(d)
----------------------------------------- ------------Sodium Hypochlorite (as NaOCl)
100
No
No
(7681-52-9)
Sodium Hydroxide (1310-73-2)
1000
No
No
Chemical Weapons Convention: No
TSCA 12(b): No
CDTA: No
SARA 311/312: Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactivity: No
(Mixture / Liquid)
Section 16 - Other Information
Prepared By: EHS&R Department
Revision Notes: Updated Section 1 & 14.
Disclaimer:
Please be advised that it is your responsibility to inform your employees of the
hazards of this substance, to advise them of what these properties mean and be sure
they understand exposure information.
The information presented herein, while not guaranteed, was prepared by competent
technical personnel and is true and accurate to the best of our knowledge. No warranty
or guaranty, express or implied, is made regarding performance, stability, or
otherwise. This information is not intended to be all-inclusive as to the manner and
conditions of use, handling, and storage. Other factors may require additional safety
or performance considerations. While our technical personnel will be happy to respond
to questions regarding safe handling and use procedures, the handling and use remains
the responsibility of the customer. No suggestions are intended as, and should not be
construed as, a recommendation to infringe on any existing patents or to violate any
Federal, State, or local laws.
Page 5 of 5
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IF IN EYES
IF ON SKIN OR
CLOTHING
IF SWALLOWED
IF INHALED
Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
Call a poison control center or doctor for treatment advice.
Take off contaminated clothing.
Rinse skin immediately with plenty of water for 15-20 minutes.
Call a poison control center or doctor for treatment advice.
Call poison control center or doctor immediately for treatment advice.
Have person sip a glass of water if able to swallow.
Do not induce vomiting unless told to do so by the poison control center or doctor.
Do not give anything by mouth to an unconscious person.
Move person to fresh air.
If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by
mouth-to-mouth, if possible.
Call a poison control center or doctor for further treatment advice.
Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
NOTE TO PHYSICIAN
Probable mucosal damage may contraindicate the use of gastric lavage.
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