國立高雄師範大學 101 學年度學士班轉學生招生考試試題 系所別:化 學 系 、 生 物 科 技 系 二 年 級 科 目:普 通 化 學 ※注意:1.不必抄題,作答時請將試題題號及答案依照順序寫在答案卷上,於本試題上 作答者,不予計分。 2.限用藍色或黑色之鋼筆、原子筆作答,以鉛筆或其他顏色作答者不予計分。 1. Arrange the following in order of increasing base strength in aqueous solution: CH3S, OH, and CF3S. (6%) 2. Write noble-gas core ground-state electron configurations for the following elements: (8%) (1) chromium (2) lead (3) copper (4) calcium 3. An element has the following first through fourth ionization energies in MJ.mol1: 0.7, 1.5, 7.7, 10.5. Deduce to which group in the periodic table it probably belongs. Give your reasoning. (6%) 4. Suppose that you discovered some material from another universe that obeyed the following restrictions on quantum numbers: n0 0ln ml = + l or –l ms = + 1/2 Assume that Hund’s rule still applies. What would be the atomic numbers of the first three noble gases in that universe? (15%) (背面有題 續翻背面) 第 1 頁,共 2 頁 系所別:化 學 系 、 生 物 科 技 系 二 年 級 科 目:普 通 化 學 5. The cyanate ion, OCN, forms a stable series of salts, but many fulminates, CNO, are explosive. Explain. (15%) 6. Please write (a) the Chinese name and (b) the English name for the following elements: (10%) (1) Ag (2) Au (4) Na (5) Pt (3) Hg 7. Please explain the following terms: (10%) (1) buffer solution (2) azeotrope (4) state function (5) copolymer (3) Le Chatelier’s principle 8. Please draw Lewis structures for the following molecules ( include formal charge ): (10%) (1) HCN (2) N2O 9. Please use VSEPR theory to predict the geometric shape of the following species: (10%) (1) SF4 (2) XeF3+ 10. Please (a) draw molecular-orbital energy-level diagrams and (b) state the bond order for each species of (1) O2+ (10%) (2) O2 第 2 頁,共 2 頁