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國立高雄師範大學 101 學年度學士班轉學生招生考試試題
系所別:化 學 系 、 生 物 科 技 系 二 年 級
科
目:普 通 化 學
※注意:1.不必抄題,作答時請將試題題號及答案依照順序寫在答案卷上,於本試題上
作答者,不予計分。
2.限用藍色或黑色之鋼筆、原子筆作答,以鉛筆或其他顏色作答者不予計分。
1. Arrange the following in order of increasing base strength in aqueous solution:
CH3S, OH, and CF3S. (6%)
2. Write noble-gas core ground-state electron configurations for the following
elements: (8%)
(1) chromium
(2) lead
(3) copper
(4) calcium
3. An element has the following first through fourth ionization energies in
MJ.mol1:
0.7, 1.5, 7.7, 10.5.
Deduce to which group in the periodic table it probably belongs. Give your
reasoning. (6%)
4. Suppose that you discovered some material from another universe that obeyed
the following restrictions on quantum numbers:
n0
0ln
ml = + l or –l
ms = + 1/2
Assume that Hund’s rule still applies. What would be the atomic numbers of the
first three noble gases in that universe? (15%)
(背面有題
續翻背面)
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系所別:化 學 系 、 生 物 科 技 系 二 年 級
科
目:普 通 化 學
5. The cyanate ion, OCN, forms a stable series of salts, but many fulminates,
CNO, are explosive. Explain. (15%)
6. Please write (a) the Chinese name and (b) the English name for the following
elements: (10%)
(1) Ag
(2) Au
(4) Na
(5) Pt
(3) Hg
7. Please explain the following terms: (10%)
(1) buffer solution
(2) azeotrope
(4) state function
(5) copolymer
(3) Le Chatelier’s principle
8. Please draw Lewis structures for the following molecules ( include formal
charge ): (10%)
(1) HCN
(2) N2O
9. Please use VSEPR theory to predict the geometric shape of the following species:
(10%)
(1) SF4
(2) XeF3+
10. Please (a) draw molecular-orbital energy-level diagrams and (b) state the bond
order for each species of
(1) O2+
(10%)
(2) O2
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