Chemistry Honors Review Name_____________________________ Multiple Choice Portion: 20 questions at 4 points each. Circle the one best answer to each question 1) How many valence electrons in an atom of sulfur? (a) 1 (b) 2 (c) 3 (d) 4 (e) 6 2) Which of the following has two valence electrons? (a) Ca2+ (b) K+ (c) O2- (d) F- (e) none of these 3) Which of the following has the electron configuration of a noble gas? (a) H- (b) K+ (c) Sr2+ (d) P3- (e) all of these 4) What is the correct Lewis dot structure of an atom of silicon? (a) Si (b) Si (c) Si (d) Si (e) none of these 5) The octet rule states that atoms form ions to: (a) (b) (c) (d) (e) obtain 8 electrons in the outer shell obtain the electron configuration of a noble gas obtain half-full s or p sublevels obtain 18 electrons in the outer shell none of the above 6) The first step in ionic bonding is the: (a) sharing of electrons (b) creation of electrons (c) transfer of protons (d) transfer of electrons to obtain stable configurations (e) none of the above 7) What is the formula when aluminum and sulfur form an ionic compound? (a) AlS (b) Al2S (c) Al3S2 (d) Al2S3 8) What is the formula of copper(I)sulfate? (a) CuSO4 (b) Cu(SO4)2 (c) Cu2SO4 (d) Cu2(SO4)3 9) Which of the metals below has the same charge whenever it forms ionic compounds? (a) Co (b) Cr (c) Ni (d) Zn (e) Fe (d) SO2 (e) none of these 10) Which of the compounds below is ionic? (a) H2O (b) NaOH (c) H2O2 11) What is the correct name for CrO3? (a) (b) (c) (d) (e) chromium oxide chromium(I) oxide chromium(I) trioxide chromium(III) oxide chromium(VI) oxide 12) What is the correct formula for silver sulfate? (a) (b) (c) (d) (e) Ag2S Ag2SO4 AgS AgSO4 AgS2 13) What is the correct name for Fe2O3? (a) (b) (c) (d) iron oxide iron(II) oxide iron(III) oxide iron trioxide 14) When will an ionic compound typically conduct electricity? (a) (b) (c) (d) (e) when in the molten state when dissolved in water when in the solid state both (a) and (b) both (a) and (c) 15) Which of the following is not a property of ionic compounds? (a) (b) (c) (d) (e) low melting point high boiling point conduct electricity in aqueous solution solids at room temperature shatter easily when struck with a hammer 16) Which of the following would you expect to have the highest melting point? (a) CaS (b) CaCl2 (c) SrBr2 (d) KI 17) Which of the following is not a property of metals? (a) (b) (c) (d) (e) malleable ductile conducts electricity brittle lustrous 18) The model of metallic bonding is best described as: (a) (b) (c) (d) (e) alternating positive and negative charges in an ordered array cations embedded in a sea of mobile valence electrons alternating protons and electrons alternating anions and cations anions floating amidst many protons 19) A mixture of mercury and another metal is called: (a) an amalgalm (b) brass (c) bronze (d) sterling 20) Choose the term that best completes the second relationship: pipe:water (a) (b) (c) (d) metal: _______ ions ionic bond electrons conductor (e) none of these Chapter 14 Portion: Essay/Short Answer Part I Draw the Lewis structure for each of the following molecules. Make sure to include all lone pairs. Draw and state the shape for each molecule, and show the approximate angles that exist within the molecule. (4 each) 1) H2O 2) PH3 3) COCl2 4) CO 5) BF3 6) CCl4 7) SO4-2 8) CO3-2 9) NH4+ 10) PO3-3 Part II Draw the Lewis structures for each of the following: (5 each) 1) XeF3+ 2) PBr5 Part III – Short Answer (10 each) 1) The carbonate ion (CO3-2) demonstrates resonance. Draw all possible resonance structures for this ion, and explain (in a sentence or two) what is meant by the term resonance. 2) Both compounds below violate the octet rule. Draw a structure for each, and state why each violates the octet rule. (a) NO2 (b) BeH2 3) The hydronium ion (H3O+) can be formed from water and a hydrogen ion. Use this ion to explain the meaning of a coordinate covalent bond. Part IV In the chart below, draw the Lewis Dot Structure, state the shape, state whether the molecule has polar bonds or not, and state whether the molecule is polar or not. A table of electronegativity values appears below. MOLECULE LEWIS STRUCTURE OF2 NF3 BCl3 CS2 BeCl2 Table of Electronegativities SHAPE (NAME) POLAR BONDS? (YES or NO) POLAR MOLECULE? (YES or NO) Part V (Essay) Compare and contrast ionic, covalent, and metallic bonding. (20 points)