Chemistry Lesson 2 What are things made of? (Introduction to Organic Chemistry) Learning Objectives: In this chapter you will learn about: What are organic compounds Alkanes: physical and chemical properties, chemical structures and applications Isomerism of organic compounds The geometrical isomerism and optical properties of alkenes The delocalization of electrons in conjugated organic compounds. Some simple functional group transformations between alcohols, alkyl halides, ethers, carboxylic acids, and esters. Some simple oxidation and reduction reactions in organic chemistry. Two important applications of organic compounds in daily life: polymers and detergents. Suggested Time Allocation: Part Theme Powerpoint Slides Suggested time allocation: 1 Introduction – What is organic chemistry? 2–6 20 mins 2 Simple hydrocarbons - alkanes 7 – 15 45 mins 3 Simple hydrocarbons - alkenes 16 - 23 45 mins 4 Aromatic compounds and delocalization 24 – 27 30 mins 5 Some examples of functional group transformations 28 – 35 45 mins 6 Isomerism 36 – 39 30 mins 7 More examples of functional group transformations 40 - 50 50 mins 8 Polymers and plastics 51 – 57 50 mins 9 Detergents 58 - 64 45 mins Total time suggested: 360 mins (6 hours) Teachers Notes: 1. 2. This module covers some of the important basic concepts in organic chemistry. It allows students to get a brief overview about organic chemistry. Because of the limited time available for the IJSO course, this module cannot cover all the topics that are listed in the HKCEE / HKALE / NSS Chemistry curriculum. If sufficient classroom sessions can be allocated, teachers are advised to further enrich this module by referring to the related topics in the HKCEE / HKALE / NSS Chemistry curriculum. Knowledge prerequisites – it is recommended that the students have previously learnt the following concepts: - 3. 4. 5. 6. 7. 7. 8. Atomic structure and molecule structure Chemical bonding (ionic bond, covalent bond) Shape of some common molecules - Different types of intermolecular forces (Part 1) Students should recognize that because each carbon atom is capable of forming four stable covalent bonds with other carbon, oxygen, nitrogen and or hydrogen atoms, a huge number of organic compounds can be formed. Some organic compounds have simple structures, while some compounds’ structures are extremely complicated. It helps students to appreciate why the chemistry of carbon compounds is often studied separately. (Part 2) Students should recognize that compounds that belong to the same homologous series have very similar chemical property. Their physical properties, on the other hand, depend on the size and geometry of the molecules. (Part 2) Students should recognize the existence of isomers in organic chemistry, i.e., many structurally different compounds have the same molecular formula. (Part 3) Students should recognize that alkenes can form geometrical isomers. A C=C double bond cannot undergo bond rotation without breaking the bond. (Part 3) Students should recognize that the light absorption properties of an organic compound often depend on the number of conjugated double bonds that present in the compound. (Part 4) Students should recognize that aromaticity and electron delocalization provide extra stabilization for a compound. Students should know how to use resonance structures to represent some simple delocalization system. (Part 5) Students should recognize that organic compounds are often classified by the functional groups that they possess. Function groups determine the chemical properties of organic molecules. 9. (Part 5 & 7) Students should be familiarized with some common/simple functional group transformations. These type of problems are frequently found in examinations and tests. 10. (Part 8 & 9) Students should recognize the close relation between molecular structures (form) and properties (functions). The structure of a polymer molecule determines its chemical and physical properties. Detergents have cleaning power because their molecules possess the dual hydrophobic-hydrophilic properties. Suggested Web-resources for Further Study: 1. 2. 3. 4. 5. http://www.cem.msu.edu/~reusch/VirtualText/intro1.htm - A comprehensive virtual textbook of Organic Chemistry http://ocw.mit.edu/OcwWeb/Chemistry/5-12Spring-2005/CourseHome/index.ht m - MIT OpenCourseWare – Organic Chemistry I http://en.wikipedia.org/wiki/Organic_chemistry - Wikipedia – Organic Chemistry http://www.haverford.edu/wintnerorganicchem/ - Online lectures and related texts on organic chemistry (advanced) http://www.organicworldwide.net/ - Organic Chemistry Resource Worldwide