Chapter 24
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Naming Amines
Know the structure of pyridine and aniline
Amines Form H-Bonds
Basicity of Amines – How are they Lewis Bases, what happens when they
bond to 4 atoms, etc…
Synthesis of Amines
Ammonia and other amines are good nucleophiles
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Synthesis of Amines, Reduction of nitriles and amides
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Synthesis of Amines - Reduction Aryl Nitro Compounds
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Synthesis of Amines, Reductive Amination
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Selective Preparation of Primary Amines: the Azide Synthesis
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Synthesis of Diazonium Salts: The Sandmeyer Reaction
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Diazonium Salts: Preparation of Aryl Halides
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Diazonium Salts: Aryl Nitriles and Carboxylic Acids
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Diazonium Salts: Diazonium Coupling Reactions – Azo Compounds
Chapter 25
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What are Carbohydrates, what makes them and from what, the approximate
ratios of C to H to O, what functional groups are found?
Name 2 uses of sugars in biological systems.
What are monosaccharides, disaccharides, and polysaccharides?
What is an aldohexose or a ketopentose?
Draw a carbohydrate stereo-chemically.
How do you determine the D and L configuration of a sugar?
How many possibilities are there when a sugar has 4 chiral centers?
Know acetals and hemiacetals.
What is a 1,4 addition of a disaccharide?
Why can we not use cellobiose as food even though it is glucose?
Chapter 26
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Proteins – Amides from Amino Acids
Structures of Amino Acids
Abbreviations and Codes of Amino Acids
KNOW EVERYTHING ABOUT THE AMINO ACIDS.
What are essential amino acids?
Define Zwitterionic
Charge on the Amino Acids (Isoelectric Points)
Electrophoresis
Define what is pKa and pH, explain each, and what happens to pKa when the
pH changes, what molecules are present at the point where pKa equals pH.
How is chirality described in Amino Acids
What are disulfide bond and what amino acids are used?
What is the N and C terminus?