1 Hameldown Road Okehampton Devon EX20 1UB UK Phone +44 (0)1837 54446 Fax + 44 (0)1837 54544 Email info@microanalysis.co.uk Web www.microanalysis.co.uk Safety Data Sheet 1 Identification of the substance/preparation and of the company/undertaking Identification of the product Catalogue number(s) B1502, B1503, B1504 Product Name: Tungsten/Tin Accelerator. Manufacturer/supplier identification As listed above 2 Composition/information on ingredients Chemical characterisation Product name: Tungsten Tungsten >70% wt OSHA PEL(mg/m3) ACGIH TWA(mg/m3) CAS 7440-33-7 Tin <30% wt CAS 7440-31-5 Not given 2 5 (as insoluble compound) 2(as insoluble compound) 3 Hazard identification Eyes: May cause irritation Skin: May cause irritation. Inhalation: Tungsten may or may not cause transient lung damage. Ingestion: Not available. Medical Conditions Aggravated: Exposure to Tungsten dust or fume may aggravate chronic respiratory disease.. Chromic Overexposure: Not known. Periodic medical examinations are recommended for individuals regularly exposed to dust. Acute Overexposure: Inhalation and skin effects generally occur in conjunction with exposure to other dusts. Carcinogenicity: None 4 First aid measures Eye contact: Immediately wash from eyes with large amounts of water, occasionally lifting upper and lower eye lids, for at least 15 minutes. If irritation occurs seek medical attention. Inhalation: Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult give oxygen. Skin Contact: Immediately wash skin with soap & water If irritation occurs seek medical attention. Ingestion: Seek medical attention. 5 Fire-fighting measures Special risks Page 1 of 3 Non-Flammable. When tungsten burns in air, it forms Tungsten trioxide which sublimes above 750’c (1382f) Suitable extinguishing media and instructions Class D fire extinguishing agents, dry powder. Firefighting Instructions: Firefighters should wear proper protective equipment and selfcontained breathing apparatus with full-face piece, operated in positive pressure mode. 6 Accidental release measures Wear appropriate protective clothing. Clean up spills immediately. Observing precautions in the protective equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Ventilate area and wash spill site after material pickup is complete. 7 Handling and storage Handling: Avoid dust generation Storage: Keep container closed. 8 Exposure controls/personal protection As appropriate to the situation and the quantity handled. Respirator: If airborne concentration is high, a dust/mist respirator is recommended. If concentration exceeds capacity of respirator, self-contained breathing apparatus is advised. . Ventilation: Use general of local exhaust ventilation to keep dust levels as low. Skin and Hand protection: Select glove appropriate for the specific operation.. Eye protection: Safety goggles recommended. Other precautions: Not available. 9 Physical and chemical properties Form: Grey to dark grey chips/granules. Odour: None Freeze-Melting temperature: Tungsten 3410c (6170f). Tin 232c (450f) Boiling temperature: Tungsten 5900c (10652f). Tin 2770c (5018f) Solubility in water: Insoluble Specific Gravity: 10 Stability and Reactivity: Chemical stability: Stable under normal conditions. Molten metal may react violently with water. Incompatibility: Tungsten is very slightly soluble in nitric acid, sulphuric acid and aqua regia. It is soluble in a mixture of hydrofluoric acid and nitric acid. Vigorous reaction with bromine trifluoride. Lead oxide mixed with tungsten becomes incandescent upon heating. Tungsten becomes incandescent in cold fluorine. Iodine pentafluoride reacts spontaneously with tungsten with incandescence. Avoid oxidisers. Tin is incompatible with acids, bases and oxidisors. Page 2 of 3 Hazardous Decomposition Products: None. Hazardous Polymerisation: None 11 Toxicological information No data available. Further data 12 Ecological information Not available 13 Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. 14 Transport information Not regulated. (IATA, IMO & RID/ADR) Hazard class – none UN number – not listed 15 Regulatory information Risk Phrases: R7-36/37/38 May case fire. Irritating to eyes, skin and respiratory system. Safety Phrases: S7-28-38-37/39 Keep container tightly closed. After skin contact wash immediately with plenty of soap and water. In case of insufficient ventilation wear suitable respiratory equipment. Wear suitable gloves, eye/face protection. 16 Other information Revision Date: 13th April 07 Reason for change: Addition of R&S phrases in section 15. Revision number: 1 Page 3 of 3