Electrochemistry Review Quiz 1. Two cells, one containing aqueous AgNO3 and other containing CuSO4 are set up in series. In a given electrolysis that results in depositing 1.25g of silver in the first cell, how much copper should deposit simultaneously in the second cell. A. 1.47g B. 0.368g C. 0.736g D. 2.65g E. 1.25g 6. If a constant current of 8.00 amperes is passed through a cell containing Zn2+ for 2.00 hours, how many grams of zinc will plate out onto the cathode? A. 126 g B. 1.43 x 103 g C. 0.985 g D. 19.5 g E. 39.0 g 2. The equilibrium constant (K) for the reaction below is approximately: Cl2 + 2e- → 2Cl- (E0 = 1.36v) Cu+ + e- → Cu (E0 = 0.52v) A. 10-34 B. 1017 C. 1011 D. 1028 E. 102 2NaCl + 2H2SO4 + MnO2 → Na2SO4 + MnSO4 + 2H2O + Cl2 A. ClB. Mn4+ C. Na+ D. H+ E. O2- 3. A. B. C. D. Reduction potential is: measured in amperes an extensive property always positive an intensive property 4. The standard hydrogen electrode is assigned a potential of: A. v B. 0.76v C. -1.00v D. zero volts 5. How many electrons are transferred in the following reaction? 2NaCl + 2H2SO4 + MnO2 → Na2SO4 + MnSO4 + 2H2O + Cl2 A. 4 B. 1 C. 2 D. 8 E. 6 7. is: 8. A. B. C. D. E. In the reaction below, the oxidizing agent What value of E do you expect for Pb(s) → Pb2+ + 2ein 0.015m Pb2+ solution? E0 = +0.13v E = +0.27v E = 0.00v E = +0.83v E = +0.18v E = +0.13v 9. In the electrolytic decomposition of water: 2H2O → 2H2 + O2 A. hydrogen is formed at the cathode and oxygen is formed at the anode B. hydrogen is formed at the anode and oxygen is formed at the cathode C. oxygen is formed at both the anode and the cathode D. hydrogen is formed at both the anode and the cathode 10. Which of the following would be the best reducing agent? A. Na B. Cl2 Electrochemistry Review Quiz C. D. E. O2Na+ F- 11. This picture of an electrochemical cell can best be described as: A. B. C. D. E. 1.78 x 105 sec 5.35 x 105 sec 2.19 x 104 sec 3.90 x 103 sec 1.68 x 102 sec 15. The equation that represents a reaction that is not a redox reaction is: 1. 2H2 + O2 → 2H2O 2. Zn + CuSO4 → ZnSO4 + Cu 3. 2H2O2 → 2H2O + O2 4. H2O + CO2 → H2CO3 A. B. C. D. a complete galvanic cell a complete electrolytic cell a galvanic cell, but missing at least one essential component an electrolytic cell, but missing at least one essential component 12. Calculate the value of E0cell for a galvanic cell that contains the following half cells: Cl2 + 2e- → 2Cl- (E0 = 1.36v) Cu+ + e- → Cu (E0 = 0.52v) A. B. C. D. E. E0cell = 0.32 volts E0cell = 1.88 volts E0cell = -0.32 volts E0cell = 0.84 volts E0cell = -0.84 volts 13. What is the oxidation state of S in H2SO3? A. -3 B. +4 C. +6 D. 0 E. +2 14. With a current of 20 amps, how long would it take to generate 1.00 kilograms of aluminum by the reaction: Al3+ + 3e- → Al(s) A. B. C. D. E. All of these are redox reactions Reaction 4 Reaction 2 Reaction 1 Reaction 3 16. Calculate DG0 for the reaction: Cl2 + 2e- → 2Cl- (E0 = 1.36v) Cu+ + e- → Cu (E0 = 0.52v) A. B. C. D. E. -8.1 x 104 J -6.2 x 104 J -1.6 x 105 J -3.1 x 104 J 8.1 x 105 J 17. A mole of electrons has a charge of 96,485 coulombs per mole of electrons. This quantity is known to chemists as: A. B. C. D. E. 1 joule 1 ampere 1 watt 1 volt 1 faraday 18. In all electrochemical cells, the process that takes place at the anode is _________________ and the process that Electrochemistry Review Quiz takes place at the cathode is _________________. A. B. C. D. reduction, reduction oxidation, reduction oxidation, oxidation reduction, oxidation 19. For the galvanic cell described below, the correct line notation is: Cl2 + 2e- → 2Cl- (E0 = 1.36v) Cu+ + e- → Cu (E0 = 0.52v) A. Cu(s)|Cu+(aq)||Cl2(g)|2Cl-(aq)|Pt(s) B. Cu(s)|Cu+(aq)||Cl2(g)|2Cl-(aq) C. Pt(s)|Cu(s)|Cu+(aq)||Cl2(g)|2Cl-(aq)|Pt (s) D. Pt(s)|Cl2(g)|2Cl-(aq)||Cu(s)|Cu+(aq) E. Pt(s)|Cl2(g)|2Cl-(aq)||Cu(s)|Cu+(aq)|Pt (s) 20. The current in a given wire is 1.80 amp. How many coulombs will pass a given point on the wire in 1.36 minutes? A. B. C. D. E. 253 C 147 C 45.3 C 1.32 C 2.45 C