WATERPROOF CONDUCTIVITY METER CC- 411 USER’S MANUAL Sp. j. 41-814 Zabrze, ul. Witosa 10, POLAND tel. +48 32 / 273 8106, tel./fax +48 32 / 2738114 www.elmetron.com.pl e-mail: info@elmetron.com.pl WATERPROOF CONDUCTIVITY METER CC-411 USERS MANUAL Before use, please read this instruction carefully! -41. EXPLOITATION NOTICES Dear User! We present you a device distinguished by accuracy according to the technical data and by a high stability of the displayed results. We believe that the measurements will not cause you any trouble and that the meter will operate without any inconvenience. Wide range of additional functions requires careful reading of the manual in other case some of the features may stay unused or using the meter may cause you a troubles. The employing of good-quality electrodes cells and probes, and their replacing after a suitable time ensures obtaining of high measuring parameters. In case of conductivity measurements it is important to choose the cell with right constant K value for the measuring range. Wrong selection may cause larger error occur, similar situation occurs during measurements with automatic temperature compensation with incorrectly introduced coefficient. The essential feature of our products is their low failure frequency. However if your meter will fail, our firm immediately performs its warranty repair. We wish meter. you a pleasant and trouble-free work with our WARRANTY The “ELMETRON” company gives 24 months of warranty for the CC-411 conductivity meter number ......................................... In case of damage the producer will repair the meter within 14 days from the day of delivery. The warranty doesn’t cover the damages caused by usage not in conformity with the users manual, using wrong power adapter, mechanical damages and damages caused by repairs made by unauthorised persons. NOTICE: Before sending the meter to us please contact the firm by phone. When sending the meter, the used cell, temperature probe and power adapter should be also included. Date of production........................... Date of sale..................................... Date of expiry.................................. Sp. j. 41-814 Zabrze - Grzybowice ul. Witosa 10 tel. (+48) 32 2738106, fax (+48) 32 2738114 POLAND —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 CONTENTS 1. Exploitation notices 2. The characteristics of the meter 3. What is the meter designed for? 4. Outside view 5. Switching the meter ON and OFF 6. Basic information about conductivity measurement 7. Preparation to work 7.1. Choosing the kind of temperature compensation 8. Choice and maintenance of conductivity cell 8.1 Choice of the cell 8.2 Cell maintenance 9. Calibration 9.1 Calibration without the sample solution 9.2 Calibration with use of the sample solution 10. Conductivity measurement 10.1. Measurement without temp. compensation 10.2. Measurement with automatic temp. compens. 10.3. Measurement with manual temp. compens. 11. Temperature measurement 12. Power source and changing the battery 13. Technical Data 14. Equipment —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 4 5 6 7 10 11 12 12 13 13 14 14 15 15 18 18 19 20 21 22 23 24 -8- -5- The keyboard (pic. 2) placed under the display is used for switching the meter on and off, choosing the measuring function, calibration, entering the parameters. 2. THE CHARACTERISTICS OF THE METER The keyboard has the keys as follows: - to switch the meter on and off. - conductivity measurement. - longer pressing of this button enters the calibration mode (CAL symbol displayed). - temperature measurement. , - buttons used for entering the parameters In upper wall of the meter there are inputs with below given symbols: F1 - BNC-50 for connecting the conductivity cell t - Chinch input to connect the temperature probe P - Power adapter input —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 The conductivity meter CC-411 belongs to the newest generation of measuring devices, the meter ensures high accuracy, stability and repeatability of the readings. Two kinds of power source: battery and power adapter enable work in field and long-lasting measurements in the laboratory. The newest generation electronic elements used in the meter made it’s memory independent to power supply and have ensured very low power consumption what greatly increases the operation time on 1 battery. The meter is equipped with large custom LCD display, which enables observing of the conductivity or temperature results. Waterproof housing makes working in difficult conditions possible. Small size and weight make the meter very handy especially during the field work. Main features of the CC-411 are: - high accuracy and stability of the reading; - automatic and manual temperature compensation; - calibration of the conductivity cell by introducing the constant K or on sample solutions; - function of determining the constant K of cell; - storing of the parameters in non-volatile memory; - cooperation with Pt-1000 temperature sensor; - information about the battery condition; - automatic switch off function. -6- -7- 3. . WHAT IS THE METER DESIGNED FOR 4. OUTSIDE VIEW. Waterproof conductivity meter CC-411 is precise and easy to use meter designed for measurements of: conductivity, in S/cm or mS/cm. The meter may be also used for accurate temperature measurement of solutions and air in °C. Waterproof housing enables work in difficult weather conditions or in humid environment. Conductivity CC-411 meter is being used in food, chemical, pharmaceutical and energetical industries, in water treatment stations, laboratories, agriculture, universities, scientific laboratories etc. The meter is prepared to work with conductivity cells, with wide constant K range, equipped with BNC-50 connector. CC-411 co-operates with Pt-1000 temperature probe with Chinch connector. On the front wall of the meter there is a LCD display (pic. 1) on which depending on the chosen function the result of the conductivity or temperature measurement is displayed; Choosing the function by pressing or buttons. Symbols of the units are displayed by the results. In case of disconnecting the temperature probe the meter switches it self to manual temperature compensation mode. By the conductivity result a blinking symbol will be displayed. If the battery should be changed a symbol is displayed. The keyboard placed under the display is used for switching the meter on and off, choosing the measuring function, calibration and entering the parameters. Pic. 1. The CAL symbol on the left side of the display informs that the meter is in calibration mode. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 - 12 - -9- 7. PREPARATION TO WORK Before starting the work one should : - join the power adapter plug to the right input (P) if work with the power adapter is planned; - to BNC-50 input (F) join the right conductivity cell; - in case of using the temperature probe connect it with the chinch temperature input (t); - switch the meter on by pressing the button. 7.1. Choosing the kind of temperature compensation The meter switches it self to the automatic temperature calibration mode automatically after joining the temperature probe. The measurement will be compensated to the temperature measured by the sensor. In case of measurements without the temperature probe, after disconnecting it the meter enters the manual temperature compensation mode. By the conductivity measurement result a blinking symbol will appear and for the compensation the value set by the user will be taken. Way of entering the temperature is described below 7.1.1. Entering the compensation temperature value for manual To enter the temperature value for the manual temperature compensation one should: - disconnect the temperature probe; - with button chose the temperature measurement function, the earlier set value will be displayed and beside it a blinking symbol; - with , buttons change it for the required value; - return to the conductivity measuring mode by pressing the button; —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 Pic. 2. - 10 - - 11 - 5. SWITCHING THE METER ON AND OFF 6. BASIC INFORMATION ABOUT THE CONDUCTIVITY MEASUREMENT The meter is switched on by pressing the button. The meter tests the memory and display on which all symbols are displayed. Pic. 3. If the test was successful, after about 1.5 s the meter switches it self automatically to the measuring mode, in which it was switched off. Displaying a sign informs that the meter has lost the manufacturer’s parameters what requires repair. Continuous displaying of the test informs about loosing the user’s calibration parameters. After pressing the button the meter will automatically provide constant K of the cell K=1.000 cm-1 and will enter the measuring mode. It is necessary to make the conductivity cell calibration after this. The meter is switched off by pressing the button. In case of working on the batteries to save them the meter switches it self automatically off after 10 minutes from the last pressing of any button. This function is switched off for the time of calibration or working with the power adapter. The conductivity measurement is based on applying a voltage with proper frequency between two electrodes and measuring it. In the CC-411 the frequency depends on the measuring range and may vary from 100 Hz up to 10 kHz. Depending on the kind of the measured liquid, it’s concentration and the temperature, the voltage flow is easier or more difficult. The conductivity result indirectly informs about the salts concentration in the measured liquid. The greater is the salt concentration the bigger is the conductivity (KCl, NaCl) This dependence doesn’t concern all of the solutions. In some cases after exceeding some salinity value the conductivity starts decreasing. The temperature has also a great influence on the results of a conductivity measurement which increases together with the temperature growth. The electrode’s surface and the distance between them have decisive influence on the so called constant K value of the cell. This value has a great influence on the accuracy of the measurement. Depending on the measured conductivity value cells with constant K = 0,1 cm-.1 up to 10 cm-.1 are used. During the measurement the meter multiplies the measured value by the constant K introduced to the meters memory and displays the result in units of conductivity (μS/cm or mS/cm). By the result a shortened symbol of the unit is displayed (μS or mS). The conductivity is changing together with temperature and salts concentration. To make the comparing of the results possible the measured value is counted by the meter to the value which responds to measurement in 25 0C. Measurement in this temperature is most accurate. In other temperatures there is so called temperature compensation used, this means that there are some counting made by the meter which take the actual measured temperature and coefficient under the consideration. This coefficient describes how much will the result change when the temperature will change for 1 0C. The coefficient in this meter is constant and is 2% / oC. This is the value closest to this which have most of the salts in 25°C temperature. It must be remembered that the most accurate measurements are obtained in 25°C temperature. The conductivity, despite the electronic precision, should always be treated as burdened with some error, which depends on the error of conductivity cell (it’s linearity), temperature and first of all depending on the coefficient during measurements in temperatures different than 25 0C. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 - 13 - - 16 9.2.1. Calibration without the temperature compensation The accurate calibration should be done without the temperature compensation. The sample solution should be brought to 25°C. During controlling it is possible to use the temperature probe. What should be done:: connect the conductivity cell and temperature probe to the meter; immerse both probes in the sample solution, hold the conductivity cell at least 1 cm away from the bottom and walls of the vessel. The measuring cell should be completely filled with the measured solution, there shouldn’t be any air bubbles and the electrodes should be evenly moistened*; - measure the temperature of solution and bring it to 25 oC; - press and hold the the CAL symbol. - with , buttons bring the displayed value to the known value of the used sample solution; - button till displaying on the screen return to the measuring mode by pressing the 8. CHOICE AND MAINTENANCE OF THE CONDUCTIVITY CELL 8.1. The cell choice The conductivity measuring range in CC-411 meter is 0 – 200 mS/cm. The meter co-operates with conductivity cells with constant K = 0.05 ÷ 1.50 cm-1 and BNC-50 connector. Depending on the required measuring range it is necessary to choose the right cell with constant K which enables receiving correct results. Beyond the range the cell looses it’s linearity and the results have greater error. Accurate measurements in the whole range are possible with use of 3 different conductivity cells. Depending on the expected measuring range one may choose the correct cell using the chart below. button. Pic. 4. Pic. 6. The meter is calibrated and ready to work. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 Dependence between the measuring range and constant K of the used conductivity cells. - 14 8.2. The conductivity cell maintenance To receive stable results it is advised to store the cell for few hours before the measurement in water, especially this is required in case of distilled water measurements. The conductivity probe maintenance mainly consists of accurate washing the inside of the measuring cell with distilled water. It is forbidden to clean the platinum electrodes mechanically, because the platinum layer may be rub of, what will result in decreasing the accuracy, may cause lowering the stability and change the constant K. Measurements of liquids with oils and heavy sediments content may cause platinum contamination, make the measurement impossible and irreparably damage the electrodes. In case of fat content in the measured liquids it is possible to clean the electrodes by immersing the cell in acetone, chloroform, fourhydrofurane or detergent. Some norms propose universal liquid for cleaning the cells. This is mixture of equal parts of isopropyl alcohol, ethyl ether and hydrocholic acid, diluted with water in 1:1 ratio. The conductivity probe with broken measuring cell can’t be used for further measurements because the constant K is greatly changed, the result is unstable and the influence of placing the cell in measuring vessel greatly changes the result. 9. CALIBRATION The calibration is done to prepare the meter for cooperation with the used conductivity probe, this is the essential condition for obtaining accurate results. The calibration may be done without the sample solution (by entering to the meter’s memory known value of the constant K of cell) or with use of standard solution with known conductivity. Constant K of the conductivity cell may change as reaction to contamination of the electrodes, that’s why periodically it is necessary to check the meters indications on the sample solution and eventually repeat the calibration. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 - 15 9.1. Calibration without the sample solution The meter has the possibility of calibration without the use of sample solution. To make this calibration it is necessary to know the constant K of the conductivity probe. This value may be given by the cell producer or may be determined using the CC-411 meter after making the calibration in the sample solution. To make the calibration one should: - in the measuring mode simultaneously press the , buttons till displaying on the screen with the k and CAL symbols and the value of the earlier introduced constant K - with , buttons enter the value of constant K; - return to the measuring mode by pressing the button. Pic. 5. 9.2. Calibration with use of sample solution The meter enables one point calibration in the freely chosen sample solution. To decrease the error it is recommended to use solutions with value close to the forecasted value of measurement. It is required to use high quality sample solutions. - 20 10.3. Conductivity measurement temperature compensation - 17 - with manual The measurement with manual temperature compensation may be done in stable work conditions, ex. during measurements in laboratory, especially with use of thermostat, or in case of the temperature probe damage. Disconnecting the temperature probe switches the meter to manual temperature compensation. In case of measurement with manual temperature compensation one should: connect the conductivity probe to the F1 connector (pic. 2); - - turn the meter on with button. if the conductivity cell wasn’t calibrated earlier make the calibration according to chapter 9; measure the temperature of the solution enter the measured temperature value for manual compensation according to chapter 7.1.1. Place the cell in the measured solution, it can’t touch the walls and bottom. The measuring cell should be completely filled with the sample solution and shouldn’t include any air bubbles, the electrode’s surface should be evenly moistened*; after the stabilisation read the result (pic. 10). 9.2.2. Calibration with manual temperature compensation To calibrate the meter it is necessary to: - - turn the meter on with the button; disconnect the temperature probe enter the 25°C value for manual temperature compensation according to point 7.1.1. immerse the conductivity cell in the sample solution and hold it at least 1cm away from the bottom and walls of the vessel. The measuring cell should be completely filled with the sample solution and shouldn’t include any air bubbles, the electrode’s surface should be evenly moistened*; with lab thermometer measure the temperature of the sample solution and bring it to 25 oC; - press and hold the on the display (Pic. 7). button till the CAL symbol will appear - With , buttons bring the displayed value to the value of used sample solution. - exit the calibration mode by pressing the button. Pic. 7. Pic. 10. * - air bubbles may be removed by moving the immersed cell. To make the moistening of the electrodes easier it is recommended to immerse the cell in distilled water with washing-up liquid, and than wash it in distilled water. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 The meter is calibrated and ready to work. * - air bubbles may be removed by moving the immersed cell. To make the moistening of the electrodes easier it is recommended to immerse the cell in distilled water with washing-up liquid, and than wash it in distilled water. - 18 10. THE CONDUCTIVITY MEASUREMENT 10.1. The conductivity measurement without temperature compensation An accurate conductivity measurement should be done without the temperature compensation. The measured solution should be brought to temperature of 25 oC. During the control it is possible to use the temperature probe. One should: - connect the conductivity and temperature probes to the right connectors F1 and t (pic. 2); - turn the meter on with button. - if the conductivity cell wasn’t calibrated earlier make the calibration according to chapter 9; - Place both probes in the measured solution, the conductivity cell can’t touch the walls and bottom. The measuring cell should be completely filled with the sample solution and shouldn’t include any air bubbles, the electrode’s surface should be evenly moistened*; - bring the temperature of the measured solution to 25 oC. - read the result after it’s stabilisation (pic. 8). - 19 10.2. Conductivity measurement with automatic temperature compensation In case of measurement with automatic temperature compensation one should: - connect the conductivity and temperature probes to the right connectors F1 and t (pic. 2); - turn the meter on with button. - if the conductivity cell wasn’t calibrated earlier make the calibration according to chapter 9; - Place both probes in the measured solution, the conductivity cell can’t touch the walls and bottom. The measuring cell should be completely filled with the sample solution and shouldn’t include any air bubbles, the electrode’s surface should be evenly moistened*; - wait till the stabilisation and read the result (pic. 9). Pic. 9. Pic. 8. Notice: in case of exceeding the value of temperature taken during compensation into consideration the result starts blinking although the conductivity measuring range wasn’t exceeded. If near the value a blinking oC symbol is displayed it informs that the temperature probe is broken. * - air bubbles may be removed by moving the immersed cell. To make the * - air bubbles may be removed by moving the immersed cell. To make the moistening of the electrodes easier it is recommended to immerse the cell in distilled water with washing-up liquid, and than wash it in distilled water. moistening of the electrodes easier it is recommended to immerse the cell in distilled water with washing-up liquid, and than wash it in distilled water. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 - 24 - - 21- 14. EQUIPMENT 11. TEMPERATURE MEASUREMENT The standard set includes: 1. Conductivity cell 2. Temperature probe Pt-1000B (standard); 3. Plastic container for meter, cell and temperature probe; 4. User’s manual with warranty. As the extra equipment one may order: 1. power adapter 12V 2. temperature probe Pt1000 1/3B – higher accuracy The temperature measurement is done as follows: - to the Chinch connector connect the temperature probe; - by pressing the button switch the meter on; - put the temperature probe to the measured solution; - wait till the stabilisation of the value and read the result. The meter co-operates with the PT-1000 probe. Depending on its class the accuracy of the measurement changes. Pic.11. The meter co-operates with platinum resistor sensor PT-1000 and the final accuracy of the temperature measurement depends on it’s class. NOTICE: break in the circuit of the temperature probe is signalised by blinking result even if the displayed value is not exceeding the result. Blinking -50°C value during measurement in positive temperatures informs about short circuit in the temperature probe. —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 - 23 – - 22 12. POWER SOURCE AND CHANGING THE BATTERY The meter is 9V battery or stabilised power adapter powered. The adapter should be joined with the right connector in the meter (P pic. 2). Joining the power adapter disconnects the battery. Displaying the symbol informs that the battery should be changed. To do this it is necessary to unscrew the two screws in the lower wall of the meter pull out the whole wall and replace the battery. The next thing is to put the battery back into the meter and mount the wall. The wall on the edge has a sealing ring. It is very important to pay attention, during closing the meter, if the ring on the whole edge was put inside the housing. If it is correct screw the screws till feeling the resistance (not to hard). Leaving the wall not correctly screwed causes loosing the waterproofnes and may cause flooding the meter and it’s destroying. This kind of failure is not repaired on the warranty conditions. 13. TECHNICAL DATA CONDUCTIVITY MEASUREMENT: ranges resolution 0.000 ÷ 199.9 S/cm 200 1999 S/cm 2.00 19.99 mS/cm 20.0 200.0 mS/cm 0.1 S/cm 1 S/cm 0.01 mS/cm 0.1 mS/cm accuracy * (±1 digit) ±0.25 % ±0.25 % ±0.25 % ±0.25 % Frequency 200 Hz 1 kHz 5 kHz 10 kHz * Accuracy given for the end value of the range. Ranges of frequency changes were given for constant K = 1. For other values of the constant K the values will change proportionally to changes of this constant. Temperature compensation: manual/automatic Compensation range: -5.0 ÷ 70.0 oC Constant K range 0.05 1.500 cm-1 α coefficient constant 2 %/ oC Cell calibration: one point 1. by introducing the constant K of cell 2. with use of calibration solution TEMPERATURE MEASUREMENT: range resolution accuracy* (±1 digit) - 50.0 ÷ 199.9 oC 0.1 oC 0.1 oC * accuracy of the meter. Final accuracy of the measurement depends on the accuracy of the used PT-1000 probe TEMPERATURE PROBE: platinum resistor Pt-1000 ACCURACY OF THE PROBE IN RANGE: FOR PT1000B RESISTOR: FOR PT10001/3B RESISTOR: 0 ÷ 100 0C: ±0.8 0C ±0.3 0C OTHER: WORKING TEMPERATURE: POWER: POWER CONSUMPTION: SCREEN: DIMENSIONS: WEIGHT: —————————————————————————————————— Instrukcja obsługi konduktometru CC-411 -5 ÷ 45 oC 1. 9V battery type 6F22 2. power adapter 12V 60 mW Custom LCD 55 x 45 mm 149 x 82 x 22 mm 222 g ( with battery)