1. A piece of stainless steel weighing 1.55 g absorbs 141 J of heat energy when its temperature increases by 178oC. What is the specific heat of stainless steel? q = m C Δ T so C = q . = 141 J . = 0.511 J o mΔT 1.55 g (178 C) g oC 2. The specific heat of olive oil is 2.0 J/g oC. When 435 J of heat is added to the olive oil in a pan the temperature increases from 25oC to 110oC. What amount (mass) of olive oil was placed into the saucepan? q=mCΔT so m = q . = 435 J . = 2.6 g the unit g is in the o CΔT 2.0 J (85 C) denominator of the g oC denominator so it is really in the numerator. 3. How many kilojoules (kJ) of heat are absorbed when 0.46 g of chloromethane (C4H5Cl, boiling point 12.3oC) vaporizes at its boiling point? Chloromethane, ∆Hvap = 26.4 kJ/mol. Change the liquid to gas/vapor, use the Hvap number q = m Hvap 4. 5. q = (0.46 g) • (26.4 kJ) x ( 1 mol ) = 0.14 kJ mol 88.5 g How much energy in Calories (Cal) is needed to raise the temperature 49.32 g of copper metal from 23.0oC to 137.0oC? q = m C Δ T so q = 49.32 g x 0.385 J x 114.0oC x 1 cal = 517 Cal g oC 4.18 J What amount of energy is require to 40.0 grams of liquid water at room temperature (23.0oC) and change it into 40.0 g of steam at 145.0oC? Formula q = m C Δ T and q = m H?? and need values for . . . specific heat(C) Cice= 2.01 J/goC Cliquid= 4.18 J/goC C steam= 2.01 J/goC and the phase heats (H) Hfus= 6.02 kJ/mol Hvap=40.7 kJ/mol Starting with the T = 23.0oC the water is liquid need to use the Cliquid = 4.18 J/goC, to change it to liquid water at 100.0oC (Δ T = 77.0oC). q = (40.0 g) • (4.18 J) • (77.0oC) x ( 1 kJ ) = 12.9 kJ g oC 1000 J Change the liquid water to steam (gas), use the Hvap number q = m Hvap q = (40.0 g) • (40.7 kJ) x ( 1 mol ) = 90.4 kJ mol 18.0 g Now gas at a T = 100.0oC and need to use the Csteam = 1.67 J/goC, to change it to steam at 145oC (Δ T = 45.0oC). q= mCΔT q = (40.0 g) • (2.01 J) • (45.0oC) x ( 1 kJ ) = 3.6kJ g oC 1000 J To determine the total energy the values need to be added together: 12.9 kJ + 90.4 kJ + 3.6 kJ = 106.9 kJ need correct sig figs and unit q= mCΔT