Subduction Zone Processes EAS 302 Lecture 29 Fuego Volcano, Guatemala 1 Importance of Subduction Zone Processes Mantle-to-crust mass transfer Crust-to-Mantle transfer Principal present way in which new continental crust is created oceanic crust returned to mantle Along with it, products of reaction between seawater and oceanic crust; sediment Carbonates in the oceanic crust may either be subducted (producing loss of CO2 from the surface of the Earth) Broken down by metamorphic reactions, with CO2 released by volcanism to the atmosphere Both have important implications for long term climate regulation. Volcanism and Seismicity Subduction zones are very seismically active areas. Subduction-related volcanoes erupt violently Significant hazard to humans and their structures El Salvador, Kobi Japan, Mt. St. Helens SO2 and particulates can have important climatic effects Global cooling recorded following Tambora (1815), Krakatau (1883), El Chichon (1983) and Mt. Pinatubo (1991) Reduced stratospheric ozone. Society and Subduction Zones: Volcanic Eruptions 300,000 volcanorelated deaths in last 1000 years Tambora, 1815, 92,000 Krakatau, 1883, 36,000 Mont Pelée, 1902, 29,000 Nevado del Ruiz, 1985, 26,000 Unzen, 1792, 15,000 Laki, Iceland, 1783, 9,000 Pyroclastic Flow Augustine Volcano, Alaska 2 Climatic Impact of Large Volcanic Eruptions Atmospheric SO2 following June 19,1991 eruption of Mt. Pinatubo Climatic Impact of Large Volcanic Eruptions Summer Temperature Anomalies follow eruption of Mt. Pinatubo 3 Society and Subduction Zones: Earthquakes Seattle, 2001 Society and Subduction Zones: Earthquakes Kobi, Japan 1995 4 How do we study subduction zones? Seismology Benioff Zone earthquakes define path of subducting lithosphere Chemistry of the magmas 100120 km Reveal processes beneath subduction zone volcanoes. Chemical Characteristics of Subduction Zone Magmas Volatile (mainly water) rich Directly and indirectly responsible for explosive nature Rich in SiO2 “andesite” the most common magma type andesite is in most instances a product of fractional crystallization of basalt thicker crust, water-rich nature, cooler environment leads to more extensive fractional crystallization 5 Volcanic Eruptions in Subduction Zones High SiO2 leads to high viscosity Makes it difficult for gas to escape Combined with water-rich magmas, produces explosive eruptions, such as Mt. Pinatubo. Incompatible Element Characteristics of Subduction Zone Magmas 6 What is the role of subducting sediment? In cases where the sedimentary pile is particularly thick (West Indies, Indonesia), much of the sediment is scraped off, creating accretionary prisms. Seismic studies and drilling, however, indicate that lowermost layers (100 m in W. Indies) is subducted. In cases where sediment is thin (Marianas, S. America), much or all of the sediment “disappears down the tube”; there are no accretionary prisms. Isotopic evidence: “Sediment-like” Pb isotope ratios Presence of 10Be Accretionary Prism in Cross Section 7 Pb isotope ratios of subduction zone magmas 15.9 15.8 15.7 207 204 Sediments Banda Sunda Marianas S. Sandwich Pb 15.6 Pb 15.5 Taiwan MORB Aleutians Indian MORB Philippines 15.4 15.3 17 17.5 18 L. Antilles 18.5 Pb/204Pb 19 19.5 20 206 High 207Pb/204Pb & steep arrays on Pb isotope plots suggesting mixing between sediment and mantle 10Be : The Smoking Gun 10Be created in the atmosphere by cosmic ray spallation. Half-life of 1.6 million years Exists only on surface of the Earth. Removed from atmosphere by rain and adsorbed by clays. If it were found in subduction-related lavas, but not in other lavas, this would prove they contain material that was recently at the surface of the Earth. 8 Island Arcs A Cosmogenic 10Be in subduction zone magmas Subduction zone lavas (at least some) contain 10Be. Other lavas contain none. Therefore, subduction zone lavas contain material recently at the surface, namely sediments. A A Japan Peru Central America 24 Aleutians 0 5 10 Be 10 15 (106 atoms/g) All Others Other Non-arc Volcanos Flood basalts MORB n = 26 Average = 0.3 x 106 g–1 0 5 10 Be 10 15 (106 atoms/g) How do subduction zone magmas acquire their unique characteristics? Like MORB, subduction zone magmas are a product of melting of the mantle and not the subducting oceanic crust, except in rare circumstances. 9 How do subduction zone magmas acquire their unique characteristics? Like MORB, subduction zone magmas are a product of melting of the mantle. Derived mainly from the “mantle wedge”: region of mantle above the subducting oceanic lithosphere. How do subduction zone magmas acquire their unique characteristics? Like MORB, subduction zone magmas are a product of melting of the mantle. Derived mainly from the “mantle wedge”: region of mantle above the subducting oceanic lithosphere. Dehydration of oceanic crust (and perhaps melting of sediments) generates fluids that rise into the overlying mantle wedge. In part, this water came from ocean ridge hydrothermal activity. Hydrated minerals not stable at high temperature. 10 How do subduction zone magmas acquire their unique characteristics? Like MORB, subduction zone magmas are a product of melting of the mantle Derived mainly from the “mantle wedge”: region of mantle above the subducting oceanic lithosphere Dehydration of oceanic crust (and perhaps melting of sediments) generates fluids that rise into the overlying mantle wedge. Presence of water reduces the solidus temperature of peridotite. Thus water released by crust induces melting in overlying mantle. How do subduction zone magmas acquire their unique characteristics? Like MORB, subduction zone magmas are a product of melting of the mantle. Derived mainly from the “mantle wedge”: region of mantle above the subducting oceanic lithosphere. Dehydration of oceanic crust (and perhaps melting of sediments) generates fluids that rise into the overlying mantle wedge. Presence of water reduces the solidus temperature of peridotite. Thus water released by crust induces melting in overlying mantle. Fluids also transfer incompatible elements from the subducting oceanic crust to the magma generation zone. Most soluble elements (alkalis, alkaline earths, Pb) transferred readily. Insoluble elements, Ta, Nb, not transferred efficiently. 11 Explosive, waterrich eruptions Some fluid expelled here Fluid rises into overlying hot wedge, induce melting P & T reach point where hydrous minerals break down, release water; fluids dissolve soluble elements Sediment, and more rarely oceanic crust, May eventually partially melt Summary: Significance of Subduction-related Processes Societal impact of volcanism and seismicity Destruction, or recycling, of continental crust Transfer of crustal material to the mantle perhaps can explain some of the chemical variation observed in the mantle Significance for elemental budgets, particularly for carbon continental crust is not entirely permanent does loss of carbon in subduction zones play a role in the carbon cycle and regulating atmospheric CO2? Creation of new continental crust 12