Chemistry 60/68 Mock Exam #1 ANSWERS pp. 1 Los Angeles City College Chemistry 60/68 Mock Exam #1 ANSWER KEY Professor Torres Multiple Choice 1. If you have a sample of aluminum (density = 2.70 g/cm3) and a sample of iron (density = 7.87 g/cm3) and the samples have equal masses, then the following inference can be made about the relative volumes of these two samples. A. B. C. D. 2. A student took a beaker containing a colorless liquid and evaporated the liquid. After the liquid was evaporated, she observed a white residue in the beaker. From these observations, she would conclude that the original liquid was a _______. A. B. C. D. 3. compound element mixture pure substance Melting is to freezing as boiling is to _________. A. B. C. D. 4. The volumes of the metal samples cannot be compared due to lack of information. The volume of the iron sample is greater than the volume of the aluminum sample. The volume of the aluminum sample is greater than the volume of the iron sample. The volumes of the metal samples are equal. sublimation solidification evaporation condensation How many cubic centimeters are in one cubic meter? A. B. C. D. 1 x 10-6 1 x 10-3 100 1 x 106 Chemistry 60/68 Mock Exam #1 ANSWERS pp. 2 5. Which of the following is NOT an example of an extensive property? A. B. C. D. 6. When an 80 mg sample of iron is allowed to sit in the air in an open container, a reddish powder forms on its surface. The sample now weighs more than the original iron because A. B. C. D. 7. They are solutions. They are mixtures. They are always composed of only one element. They have a constant boiling point. Which of the following is an example of the law of multiple proportions? A. B. C. D. 10. condensation of steam rusting of iron shredding a piece of paper dissolving sugar in water Which of the following is characteristic of pure substances? A. B. C. D. 9. the law of conservation of mass does not directly apply. a portion of the air has combined chemically with the iron. the element iron has changed to a more dense phase. the iron has decomposed into simpler components. An example of a chemical change is A. B. C. D. 8. density volume weight mass two compounds of carbon and oxygen with different amounts of each element in each compound a mixture of 20 g Fe, 10 g Cu, and 40 g Al a solution of NH3 and H2O that cannot be completely separated a compound containing 4 atoms of H, 2 atoms of C, and 2 atoms of O The modern periodic table contains elements arranged by increasing A. B. C. D. atomic number atomic mass mass number metallic character Chemistry 60/68 Mock Exam #1 ANSWERS pp. 3 11. Which of the following is NOT characteristic of most nonmetals? A. B. C. D. 12. Which of the following is characteristic of all metals? A. B. C. D. 13. gain protons gain electrons lose protons lose electrons Anions are formed when atoms ______________. A. B. C. D. 16. metals transition metals metalloids noble gases Cations are formed when atoms ______________. A. B. C. D. 15. poor conductors of heat and electricity form ionic compounds do not reflect light have low malleability Elements that can possess multiple oxidation states are ____________. A. B. C. D. 14. poor conductors of heat and electricity low melting points do not reflect light can be bent or hammered flat gain protons gain electrons lose protons lose electrons What idea(s) did Rutherford propose about atoms after his alpha-particle scattering experiment? A. B. C. D. Nearly all the mass of an atom is concentrated at the center of the atom. The positive charge of the atom is located in the nucleus. Electrons orbit the nucleus. All of the above were proposed by Rutherford. Chemistry 60/68 Mock Exam #1 ANSWERS pp. 4 17. Which of the following is NOT part of Dalton’s original theory of atoms? A. B. C. D. 18. Atoms that have an atomic mass of 93 and contain 40 electrons make up one isotope of what element? A. B. C. D. 19. number electrons 25 25 30 30 Atomic Number 25 30 25 30 Atomic Mass 55 55 55 60 Which of the following statements is true? A. B. C. D. 21. I Nb Th Zr What are the number of electrons, atomic number, and atomic mass of atoms known to contain 25 protons and 30 neutrons? A. B. C. D. 20. Atoms of different elements are different. Compounds are formed by the joining of atoms of two or more elements. All atoms of the same element are exactly alike; they all have the same mass. Elements are composed of atoms which are divisible and indestructible particles. The atomic number is always greater than the mass number. The mass number is the same for all atoms of the same element. The difference between the atomic number and the mass number is the number of neutrons. The atomic number is the sum of the number of particles in the nucleus. Which of the following chemists was credited with discovering the electron? A. B. C. D. John Dalton William Crookes J.J. Thomson Ernest Rutherford Chemistry 60/68 Mock Exam #1 ANSWERS pp. 5 For Questions 22 – 25, classify each of the following as a chemical change or a physical change. Select “A” for chemical change or “B” for physical change. 22. A solid is combined with hot water to produce a brown liquid. B 23. Through exposure to air and moisture, iron turns reddish and cannot conduct electricity. A 24. Iron is heated. It turns red, then white, and then melts. B 25. Sugar is heated to produce steam and a black solid. A For Questions 26 – 31, determine which characteristics are physical properties and which are chemical properties for an unknown substance. Select “A” for physical property or “B” for chemical property. 26. This substance is a silvery-white, lustrous metal. A 27. It melts at 649 ºC and boils at 1105 ºC. A 28. Its density at 20 ºC is 1.738 g/cm3. A 29. The substance burns in air, producing an intense white light. B 30. It reacts with chlorine to give a brittle, white solid. B 31. The substance can be pounded into thin sheets or drawn into wires. A 32. The total number of nonmetal atoms in Ca3(PO4)2 is: A. B. C. D. 33. 7 9 10 13 Write 0.000004506 in scientific notation. A. B. C. D. 4.5 x 1010 4.506 x 10-6 0.000005 5 x 106 Chemistry 60/68 Mock Exam #1 ANSWERS pp. 6 34. How many significant figures are there in 0.010210 L? A. B. C. D. 35. Convert 100.0 ºC to Kelvin. A. B. C. D. 36. easily shattered dull in appearance conducts electricity low melting points Which one of the following elements is a metalloid? A. B. C. D. 39. 1500 mL 1560 mL 1559 mL 1559.1 mL Which of the following properties is characteristic of most metals? A. B. C. D. 38. 173 K 273 K 373 K 212 K The answer that should be reported for the total number of milliliters of a silver nitrate solution when 39.10 mL of AgNO3 is added to 1.52 L of solution is A. B. C. D. 37. 1 3 5 6 Mg Ne C Sb An ion is: A. B. C. D. an atom with a charge an atom without a charge a molecule a neutron Chemistry 60/68 Mock Exam #1 ANSWERS pp. 7 40. What volume of alcohol (density = 0.800 g/mL) is needed to obtain 0.704 lb? (note: 1 lb = 0.454 kg) A. B. C. D. 41. When 8.44 g of calcium are heated in air, 11.82 g of calcium oxide are formed. The percentage of oxygen in the compound is: A. B. C. D. 42. KF H2S Na2O MgS Substance “X” has 13 protons, 14 neutrons, and 10 electrons. Determine its identity. A. B. C. D. 45. 63.2 amu 64.8 amu 63.8 amu 64.1 amu Which of the following is a molecular compound? A. B. C. D. 44. 28.6% 40.0% 71.4% 1.40% The average atomic mass of copper is 63.5 amu. Copper has two naturally occurring isotopes. One of the isotopes has an atomic mass of 62.9 amu and an abundance of 69.1%. What is the atomic mass of the other isotope of copper? A. B. C. D. 43. 256 mL 400 mL 80 mL 320 mL 27 Mg2+ Ne 27 Al3+ 27 Al 27 Which of the following compounds is ionic? A. B. C. D. N2O3 SO2 ClF3 KCl Chemistry 60/68 Mock Exam #1 ANSWERS pp. 8 46. The correct name for Cu2SO3 is: A. B. C. D. 47. copper(I) sulfate dicopper sulfur trioxide copper(I) sulfite copper(II) sulfite Which group of elements is most likely to react with calcium to form ionic compounds with the general formula Ca3X2? A. B. C. D. Group VII Group VI Group V Group IV Free Response 48. What is the density (g/mL) of a rectangular block of wood if it measures 4.0 cm thick, 120 mm long, and 0.57 in wide and has a mass of 0.720 kg? Will it sink or float in water? Briefly explain. (note: 1 in = 2.54 cm) To solve this problem, first obtain the volume of the rectangular block using consistent units: V = 4 cm x 12 cm x 1.45 cm (converted from in.) = 70. cm3 Density = mass/volume = 720 g/70. cm3 = 10 g/mL → SINK since the density of water at room temperature is 1.0 g/mL! 49. A piece of aluminum foil measuring 12.0 in by 15.5 in has a mass of 5.175 g. Aluminum has a density of 2.70 g/mL. What is the thickness of the foil in millimeters? Density = Mass/Volume; Volume = Mass/Density ⇐ Solve for V! Volume = 5.175 g/2.70 g/cm3 = 1.92 cm3 Volume (in3) = 1.92 cm3 x (1 in/2.54 cm)3 = 0.117 in3 Therefore, (12.0 in)(15.5 in)(thickness) = 0.117 in3 Thickness = 6.29 x 10-4 in Thickness (mm) = 6.29 x 10-4 in x (2.54 cm/1 in) x (10 mm/1 cm) = 0.0160 mm 50. Convert 81 kilometers per hour to meters per second. m = 81 km x 1000 m x 1 hr x 1 min s hr 1 km 60 min 60 s = 22 m/s ⇐ Be careful with significant figures/rounding! Chemistry 60/68 Mock Exam #1 ANSWERS pp. 9 51. Naturally occurring bromine consists of two isotopes, 79Br and 81Br, whose atomic masses are 78.918 and 80.916, respectively. Given that the observed atomic mass of bromine is 79.904, calculate the percentages of 79Br AND 81Br in naturally occurring bromine. x = % abundance of 79Br; 1 – x = % abundance 81Br 79.904 = 78.918 x + 80.916 (1 – x) x = 0.5065 or 50.7% 79Br; therefore, 49.3% 81Br 52. Discuss Rutherford’s gold-foil experiment (use a schematic for detail if necessary, but also explain). Is this model depicting the atom consistent with modern physics? Explain why or why not. Rutherford used a thin sheet of gold as a target, and alpha particles emitted from a radioactive substance were directed towards the foil. This foil is surrounded by a fluorescent screen coated with zinc-sulfide. Each time an alpha particle hits this zinc-sulfide coating, a flash of light was produced at the point of contact. By observing these flashes of light, it was possible to see whether the alpha particles that passed through the foil had been deflected from their straight-line path. Rutherford’s model depicted the atom as having a positively charged nucleus of relatively great mass. Moreover, traveling around the nucleus were one or more negatively charged electrons of very small mass. According to classical physics of the time, since an electron loses energy by giving off light, it would eventually fall toward the nucleus. This apparent anomaly goes contrary to the fact that atoms appear very stable. Therefore, an adequate atomic model must be postulated to explain why the electrons do not give off energy and collapse into the nucleus. 53. A 27.7 g sample of ethylene glycol loses 688 J of heat. What was the initial temperature of the ethylene glycol if the final temperature is 32.5 ºC (specific heat of ethylene glycol is 2.42 J/g K)? q = mC∆T -688 J = (27.7 g)(2.42 J/g ºC)(32.5 – Ti) Solve for Ti to obtain an initial temperature of 42.8 ºC. 54. Write formulas for the following compounds: A. B. C. D. lithium oxalate ammonium sulfate sodium acetate xenon tetrafluoride Li2C2O4 (NH4)2SO4 NaC2H3O2 XeF4 Chemistry 60/68 Mock Exam #1 ANSWERS pp. 10 E. F. G. 55. cobalt(III) permanganate copper(II) hydroxide hydrofluoric acid Co(MnO4)3 Cu(OH)2 HF(aq) Name each of the following compounds: A. B. C. D. E. F. G. H. FeNO3 CrClO2 BrI5 H2O2 AlPO4 HClO4(aq) (NH4)2S H2CO3(aq) Iron(I) nitrate Chromium(I) chlorite Bromine pentiodide Hydrogen peroxide Aluminum phosphate Perchloric acid Ammonium sulfide Carbonic acid