SCH 3U1 Unit 6 Assign 2 – ACID-BASE pH measurements 1. a) In pure water, what is a) [H+] =...................................pH=......... b) [OH–] =.................................... pOH =....... b) Is water a weak or strong electrolyte (poor/good conductor) 2. a) If you add acids to water what would happen to [H+] ? .............................................. b) If you add bases to water what would happen to [OH–] ? 3. + * pH = –log10[H ] .............................................. – and .............................................. pOH = -log10[OH ] and pH + pOH = 14 a) In a 1.0 x 10–1 M HCl sol’n, what is i) [H+] =........................................ ii) pH = .................... b) In a 4.0 x 10–1 M HCl sol’n, what is i) [H+] =........................................ ii) pH = .................... c) In a 1.0 x 10–3 M H2SO4 sol’n, what is i) [H+] =....................................... ii) pH = .................... d) In a 4.0 x 10–3 M HC2H3O2 sol’n, what is i) [H+] =........................................ ii) pH = .................... e) In a 1.5 x 10–4 M HNO3 sol’n, what is i) [H+] =........................................ ii) pH =.................... f) In a 1.0 x 10–1 M NaOH sol’n, what is i) [OH–] =..................................... ii) pOH =........... pH = ........... g) In a 4.0 x 10–1 M KOH sol’n, what is i) [OH–] =.................................... ii) pOH =........... pH = ........... h) In a 2.5 x 10–2 M NaOH sol’n, what is i) [OH–] =.................................... ii) pOH =........... pH = ........... i) In a 1.5 x 10–4 M Ba(OH)2 sol’n, what is i) [OH–] =.................................... ii) pOH =........... pH = ........... 4. ** if pH = -log10[H+] then [H+] = 10–pH [H+] [OH–] pH if pOH = -log10[OH–] then [OH–] = 10–pOH pOH [H+] [OH–] 1 x 10–2 2 x 10–1 2 x 10–3 4 x 10–2 1 x 10–6 5 x 10–5 1.8 pH POH 13.4 2.8 10.8 5. Calculate the pH of the following sol'ns ( all mol/L ) a) [H+] = 7 x 10–9 pH= ...................... b) [H+] = 5.2 x 10–3 pH= ...................... c) [OH–] = 0.18 pH= ..................... d) [OH–] = 7 x 10–4 pH= ......................e) [OH–] = 5.2 x 10–5 pH= ..................... f) [H+] = 0.18 pH= ...................... g) [H+] = 3 x 10–2 pH= ...................... h) [OH–] = 2.6x10–13 . pH= .................... 6. Calculate [H+] in solutions whose c) pH =1.8 a) pH = 3.0 [H+] = .......................... b) pH = 4.6 . [H+] = .............................. [H+] = ....................... d) pOH =11.5 [H+] = ........................ e) pH =7.315 [H+] = .........……............. 7. 5.0 g of HClO4 are dissolved in 200 mL of water, calculate the pH of this solution. (do on the back & show all your work) 8. 5.0 g of potassium hydroxide are dissolved in 200 mL of water, calculate the pH of this solution (do on the back & show all your work)