Molar Mass of Butane What you will need • • • • • • • • A lighter Graduated cylinder Balance Retort stand, clamp and bosshead Funnel Barometer Thermometer to measure air temperature Thermometer to measure water temperature What to do 1. Dip the lighter in water. Wipe as much water as possible from the lighter then weigh the lighter to the nearest 0.01 grams. 2. Submerge a 100mL graduated cylinder in water so that the cylinder fills completely with water. Invert the cylinder. Make sure there are no air bubbles remaining in the graduated cylinder and fix in place using a retort stand, clamp and bosshead. 3. Flip a funnel upside down and place in the opening of the graduated cylinder. 4. Carefully release the butane from the lighter and collect in the cylinder. Release enough gas to fill the tube to about 95mL. 5. Allow the butane to reach room temperature (about 5 minutes). Adjust the height of the cylinder so that the height of the water inside and outside the cylinder is the same. This makes the pressure inside and outside the cylinder the same. Record the volume of the gas in the cylinder to the nearest mL. 6. Record the air temperature. 7. Record the water temperature. 8. Record barometric pressure in the room. 9. Remove the lighter from the water. Wipe as much water as possible from the lighter then weigh the lighter to the nearest 0.01 grams. 10. Calculate molar mass. 11. Repeat the procedure 2 more times. Data Sheet Trial 1 Trial 2 Mass of lighter assembly and contents before collection Mass of lighter assembly and contents before collection Mass of the lighter assembly and contents after collection Mass of the butane gas evolved Volume of gas produced at room temperature and atmospheric pressure Barometric pressure Water temperature Vapor pressure of water at water temperature (from table) Partial pressure of dry butane (show calculation) Ptot = Pbutane + Pwater vapour Room temperature Molar mass of the butane (show calculation) M = mRT/PV True value for the molar mass _______________________ Average molar mass for the three trials _______________ Experimental error for the average (show calculation) __________________ Trial 3