CS_Ch7_PeriodicTbl 2/28/05 10:04 AM Page 428 The Periodic Table these sublevels are filled, the atom exhibits a higher degree of stability. In this model, the sublevels are designated by the four letters s, p, d, and f. graph, not just those elements with higher values.) b) Which elements in the second period (atomic numbers 3 through 10) of the periodic table have the most stable arrangements of electrons in their atoms? The periodic table shows the atomic number, the chemical symbol, and how many electrons in an atom of each element are in each sublevel. The total number of electrons is equal to the atomic number of the element. This is because the atoms are neutral and therefore have a number of electrons equivalent to the number of protons. This arrangement of the electrons in each sublevel will be referred to as the electron assignment or electron configuration of the element. Use this periodic table to answer the following questions: c) Which elements in the third period (atomic numbers 11 through 18) of the periodic table have the most stable arrangements of electrons in their atoms? d) Which elements in the fourth period (atomic numbers 19 through 36) of the periodic table have the most stable arrangements of electrons in their atoms? 6. As mentioned earlier, the Bohr model was not able to account for the spectrum of an element containing more than one electron. A more elaborate model was needed. In this new model, the energy levels are broken down into sublevels. When GROUP 1 2 3 4 a) In what sublevel (include number and letter) are the electrons in hydrogen (1 electron) and helium (2 electrons) found? 5 6 7 8 9 10 11 12 IA/1A 1 Periodic Table of the Elements 2.1 1 H 1 1.00794 1 1.0 H Li Be 1.00794 6.941 9.012182 Hydrogen 2 2 1s 2s 2 1 1s 2s Atomic Number Electronegativity Oxidation Number Symbol Average Atomic Mass Electron Configuration Name 1 2 1 Gases at room temperature KEY 1 1s IIA/2A Hydrogen Alkaline Earth Metals Alkali Metals 1.5 3 1.0 4 1 1s 1 Liquids at room temperature Solids at room temperature Metals 3 1 2 Na Mg 22.98977 24.3050 [Ne]3s 1 [Ne]3s 2 Transition Metals IIIB/3B Sodium Magnesium 0.8 20 1.0 21 PERIOD 19 1 2 C Al Si Ga Ge Nonmetals Beryllium Lithium 1.2 0.9 12 11 B Metalloids IVB/4B 1.3 22 3 VB/5B 1.5 23 3,4 1.6 24 2,3,4,5 V VIIB/7B 1.6 25 2,3,6 VIIIB/8B 1.5 26 2,3,4,6,7 1.8 27 2,3 IB/1B 1.9 28 2,3 1.9 29 2,3 Ni IIB/2B 1.9 30 1,2 Cu 1.6 2 K Ca Sc Cr Mn Fe Co 39.0983 40.078 44.95591 47.867 50.9415 51.9961 54.93805 55.847 58.93320 58.6934 63.546 65.39 [Ar]4s1 [Ar]4s2 [Ar]4s23d1 [Ar]4s23d2 [Ar]4s23d3 [Ar]4s23d4 [Ar]4s23d5 [Ar]4s23d6 [Ar]4s23d7 [Ar]4s23d8 [Ar]4s23d9 [Ar]4s23d10 Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Rb Sr Y Zr Nb 428Mo Tc Ru Rh Pd Ag Cd In Sn Cs Ba *La Hf Ta Re Os Ir Pt Au Hg Tl Pb 4 Ti VIB/6B Zn Active Chemistry W CS_Ch7_PeriodicTbl 2/28/05 10:04 AM Page 429 Activity 6 Atoms with More than One Electron As you move to the second period (second row on the periodic table) each new element has one more proton in its nucleus and one more electron. The electrons must find a place to reside — an energy level and a sublevel within that energy level. As you move along in the periodic table to increasing atomic numbers, you see that the additional electrons fill the sublevel. A completed sublevel is one that is holding the maximum number of electrons allowed to it before electrons must be placed in the next higher sublevel. b) In what region of the periodic table are electrons added in an s sublevel? What is the greatest number of electrons found in any s sublevel? c) In what region of the periodic table are electrons added in a p sublevel? What is the greatest 13 14 15 16 17 18 VIIIA/8A or 0 Noble Gases 2 He 4.002602 IIIA/3A 5 2.0 3 B 2 6 2.5 -4,2,4 1 1s 2s 2p 2 7 3.0 N 12.011 2 VA/5A VIA/6A VIIA/7A 1s Chalcogens Halides Helium 8 3.5 -3,2,3,4,5 C 10.811 2 IVA/4A 2 1s 2s 2p 2 4.0 10 -2 -1 O 14.00674 2 9 3 1s 2s 2p F 15.9994 2 2 2 4 1s 2s 2p Ne 18.998403 2 2 5 1s 2s 2p 20.1797 2 2 6 1s 2s 2p Boron Carbon Nitrogen Oxygen Fluorine Neon 13 1.5 14 1.8 15 2.1 16 2.5 17 3.0 18 3 2,4 -3,3,4,5 -2,2,4,6 Al Si P S -1,1,3,5,7 26.981539 28.0855 30.973762 32.066 35.4527 39.948 [Ne]3s23p1 [Ne]3s23p2 [Ne]3s23p3 [Ne]3s23p4 [Ne]3s23p5 [Ne]3s23p6 Cl Ar number of electrons found in any p sublevel? d) In what region of the periodic table are electrons added in a d sublevel? What is the greatest number of electrons found in any d sublevel? e) In what region of the periodic table are electrons added to an f sublevel? What is the greatest number of electrons found in any f sublevel? f) Select a column in the periodic table. (A column of elements on the periodic table is called a family or group.) Look at the electron configuration for each element within the column. Take special note of the last entry, the sublevel to which the last electron in an atom of each element in that column is added. What do all of these sublevels have in common? How many electrons are in these particular sublevels? g) Mendeleev assigned elements to the same column of the periodic table because the elements had similar properties, both physical and chemical. How, then, does the number and location of the electrons in the outermost sublevel relate to chemical properties? We can now acknowledge that electrons (as opposed to the nucleus) are the key to the chemical properties of elements. Aluminum Silicon Phosphorus Sulfur Chlorine Argon 1.6 32 1.8 33 2.0 34 2.4 35 2.8 36 31 Cu Zn 3 4 -3,3,5 -2,4,6 Ga Ge As Se -1,1,5,7 Br Kr 69.723 72.61 74.92159 78.96 79.904 83.80 [Ar]4s23d104p1 [Ar]4s23d104p2 [Ar]4s23d104p3 [Ar]4s23d104p4 [Ar]4s23d104p5 [Ar]4s23d104p6 Ag Cd Gallium Germanium Arsenic Selenium Bromine Krypton In Sn Sb Te I Xe 429 Coordinated Science for the 21st Century Au Hg Tl Pb Bi Po At Rn