Name Date Ionic Compounds Section 8.1 Forming Chemical Bonds Main Idea Details Skim Section 1 of your text. Read the title and subheads. List three concepts that you think will be discussed in this section. 1. 2. 3. New Vocabulary Use your text to define each term. chemical bond cation anion Academic Vocabulary Define the following term. element 94 Forming Chemical Bonds Name Date Section 8.1 Forming Chemical Bonds Main Idea Chemical Bonds Use with pages 211–214. (continued) Details Organize information about forming chemical bonds by completing the concept map below. As the number of % ) & $ ' ' " " " - ) 6 " in an atom increases, $ ) ) , or the atom’s ability to attract electrons, . ' " - & B B ( ( - C " 1 & " 6 " 6 " reactivity 1 & " 6 . 6 " " $ Electron affinity is smallest for , which in general have eight in their outermost s and p orbitals. ) $ + & 6 " $ ' - $ ) ) , which is the energy needed to remove electrons from the outer orbitals, . ( D & - ( " E ' " ) ( 6 " ) 6 " + C " ) ( & 6 6 " " Write the electron configuration of the most likely ion and the charge that is lost or gained by each of the following atoms. Indicate what the overall charge of the ion is, and whether it is a cation or an anion. @ 1 1 }}} 51 6 Cs: 1 [Xe]6s A " $ % 4 $ & ' ' " # ) ( & " " $ + 4 & - ) . ( , * < $ 7 O: [He]2s22p4 = > 6 7 > 8 . 9 : ? > }}}} 5 # $ " % , $ & ' ' " ) " : ( & ) + > " $ & " # ) . ( , * ; 1 1 }}}} 51 & Ga: 2 10 1 [Ar]4s 3d 4p 1 2 3 ! $ % $ & ' ' ! " # ) $ ( & + & " " ! - ) . ( , * 5 $ Br: 2 10 5 [Ar]4s 3d 4p 0 6 7 1 2 3 0 8 # ! $ % $ & ' ' / : , : & ) + $ & " [Kr]5s14d10 4 ) ( " Ag: . 9 }}}}} 5 4 ) " # . ( , * 1 1 }}}} 51 + / 0 1 2 3 4 $ % $ & ' ' " # ) $ ( & + & " " 4 - ) . ( , * 1 1 }}}} 51 Sc: 2 1 [Ar]4s 3d ! " # $ % $ & ' ' ) $ ( & " + & " * ! - ) . ( , Ionic Compounds 95 Name Date Section 8.1 Forming Chemical Bonds (continued) Main Idea Details Sequence the first group of elements in order of increasing ionization energy. Sequence the second group of elements in order of increasing electron affinity. First Group Second Group K Æ K1 > P Æ P51 H Fe Æ Fe21 ! Rb Æ Rb1 4 Mg Æ Mg21 0 Identify the following ions. Ag1 % 6 ' Se2– 96 Forming Chemical Bonds - ( G F $ F ( 1 " & ' ( G F 6 G ' B ( 1 " E $ $ ) ) & 6 ( 1 " H– Cd21 ( E B31 As3– * Br– S2– ' " Li1 Ca21 ( C " 1 ( 1 " * & 1 F ( G F ) 6 ' " ( " 1 " P Æ P3– ! Ne Æ Ne1 I O Æ O2– > Xe Æ Xe– I S Æ S2– 0 I Æ I– H 4 F Æ F– Name Date Ionic Compounds Section 8.2 The Formation and Nature of Ionic Bonds Main Idea Details Skim Section 2 of your text. Write three questions that come to mind from reading the headings and the illustration captions. 1. 2. 3. New Vocabulary Use your text to define each term. ionic bond J electrolyte J lattice energy Academic Vocabulary Define the following term. K conduct Ionic Compounds 97 Name Date Section 8.2 Formation and Nature of Ionic Bonds Main Idea Formation of an Ionic Compound Use with Example Problem 8-1, page 217. (continued) Details Solve Read Example Problem 8-1 in your text. You Try It Problem Describe the formation of an ionic compound from the elements boron and selenium. 1. Analyze the Problem Known: the electron configurations of the given elements 5 Æ }}} = > 6 7 > 8 2 " Unknown: the number of valence electrons for each neutral atom 5 Æ % ) & $ ' ' ! " " - " ) 6 " I Æ " % ) & $ ' ' " " - " ) 6 " 2. Solve for the Unknown Determine how many electrons need to be removed from boron and how many electrons need to be added to selenium to form noble gas configurations. L M N O N P Q R S T U Z T a Q b T c d N O V Q P W X U Y Z N [ X Q P Q W \ ] T ^ _ M T P ` T S f T V g [ Z h Q P O N Z T i e Determine how many boron atoms and how many selenium atoms must be present for the total number of electrons exchanged between the two elements to be equal. j m M T Z T W Q [ Q ` Z T n o k L N [ Q a O _ X S S p Z Q b X c T q T S T V [ Z Q P O n _ M X V M _ X S S i R T N c e 3. Evaluate the Answer The overall charge on one unit of this compound is zero. boron ions (31/boron ion) 1 selenide ions ( 2 / i l i selenide ion) 5 98 Formation and Nature of Ionic Bonds l (31) 1 i ( 2)50 i c l T c Name Date Section 8.2 The Formation and Nature of Ionic Bonds Main Idea Properties of Ionic Compounds (continued) Details Analyze the relationship between the lattice energy of an ionic compound and the force of attraction. r J Use with pages 217–220. K j Describe the relationship between the size of the ions in a compound and the compound’s lattice energy. j K K Explain the relationship between lattice energy and the charge of the ion. j K Organize the following ionic compounds from those with the least negative lattice energy to those with the most negative lattice energy. H LiCl u BeS LiBr 0 t BeO s BeCl2 RbBr ! 4 CsI I SrCl2 > CsBr Ionic Compounds 99 Name Date Ionic Compounds Section 8.3 Names and Formulas for Ionic Compounds Main Idea Details Scan Section 3 of your text. Use the checklist below as a guide. • Read all section titles. • Read all boldfaced words. • Read all tables and diagrams. • Look at all figures and read the captions. • Study the example problems and note what they are intended to solve. • Think about what you already know about the formation, formulas, and naming of ions and ionic compounds. Write three facts that you discovered about the names and formulas of ionic compounds. 1. 2. 3. New Vocabulary Use your text to define each term. formula unit v monatomic ion oxidation number polyatomic ion oxyanion 100 Names and Formulas for Ionic Compounds w K K Name Date Section 8.3 Names and Formulas for Ionic Compounds Main Idea Formulas for Ionic Compounds Determining the Formula for an Ionic Compound Use with Example Problem 8-3, page 223. (continued) Details Solve Read Example Problem 8-3 in your text. You Try It Problem Calcium can form a cation with a 2+ charge. Write the formula for the ionic compound formed from calcium ion and Chlorine. 1. Analyze the Problem Known: the ionic forms of the component elements @ & 7 1 @ and ' 2 # Unknown: 2. Solve for the Unknown The smallest number that is divisible by both ionic charges is $ $ - ) , so the compound contains y $ calcium ion(s) and " - y sulfide ion(s). The formula for the ionic compound formed is @ @ & ' 7 . 3. Evaluate the Answer The overall charge on one formula unit of this compound is zero. x i Ca ion(s) (21/Ca ion) 1 Determining the Formula for an Ionic Compound Containing a Polyatomic Ion Use with Example Problem 8-4, page 225. Cl ions (12 /Cl ion) 5 0 Solve Read Example Problem 8-4 in your text. You Try It Problem Write the formula for the ionic compound formed from the calcium ion and the bromate ion. 1. Analyze the Problem @ Known: the ionic forms of the component elements and & 7 1 < 5 # Unknown: Ionic Compounds 101 Name Date Section 8.3 Names and Formulas for Ionic Compounds Main Idea (continued) Details 2. Solve for the Unknown The smallest number that is divisible by both ionic charges is $ - y $ , so - y $ ) bromate ions combine with calcium ion. The " @ < 5 . formula for the ionic compound formed is to form & , 7 . 3. Evaluate the Answer The overall charge on one formula unit of this compound is zero. i BrO3 ions (12/BrO3 ion) 5 0 1 Ca ion (21/Ca ion) 1 Naming Ions and Ionic Compounds Use with pages 225–227. Classify the ions listed below as monatomic or polyatomic cations or anions. If the ion is a polyatomic anion, indicate whether it is an oxyanion. CN2 $ $ 8 ' C & ) - F ( & $ ) $ ) ( MnO42 $ $ 8 ' C & ) - F ( & } $ | ) ( C & C & Ba21 $ ) $ F & $ - F ( & Fe(CN)642 $ ' C & - ) - F $ ( $ & ' C & $ - F ( & $ ) - & ) - F ) ( $ F ( $ & ) ( $ $ 8 ' C & $ - F ( & S2O322 $ - ' C & ) - F ) ( $ 8 ( $ & ) } $ | ) ( ( O22 $ ) $ F & ) - F ( $ & ) ( Identify the ionic compounds listed below. $ & Hg2SO4 PtCl4 102 Names and Formulas for Ionic Compounds ( G | F ( 1 " $ ) 8 - & 6 6 ( G F 8 F ) & + & & " $ 6 - ) - ( G F ( $ & F 1 & - ) $ F ( G F C 1 | ( 1 " * $ ( ) . 6 , z z ) - G - & - { " . & 1 ) ( ' ( " . z B z ( , ' $ 1 8 " , z 6 8 & - z " * * . F G C " 6 , G ' B & - z " ) 8 ' & - ( . G $ F ' , z - " $ " Fe2S3 Pb3(PO4)2 ' KMnO4 Sn(NO3)4 ) ) ( $ 8 Hg221 NH4OH $ ) ( N32 Sr(IO3)2 ) $ 8 NH41 CaO $ ( { ( 1 " *