Skeletal structures
Counting total electrons
Compound
4) Octet for
O Cl O
peripheral
16 - 12 = 4
atoms
5) Remain1) Skeletal
O Cl O
O Cl O
ing e–s on
Structure
center atom 4 - 4 = 0
2) Count 7x1 + 6x2 6) Create
electrons
multiple
+1 = 20
No need
bonds?
3) Electron O Cl O
Final
O Cl O
pairs in
structure
or
20 - 4 = 16
O Cl O
bonds
ClO2–
Resonance structures
• Lewis structures for certain atoms do not
match experimental observations
• For example, the bond lengths of CHO2–
predicted by the Lewis structure are incorrect
–
O
H
C
O
• The double CO bond should be shorter, and
possess a greater bond energy (due to the
higher concentration of e–s in a double bond)
• Yet, experimentally, both bonds are the same
• The reason is due to “resonance”
[
]
Compound
4) Octet for
C O
peripheral
atoms
8-6=2
5) Remain1) Skeletal
C O
C O
ing e–s on
Structure
center atom 2 - 2 = 0
2) Count 4x1 + 6x1 6) Create
electrons
multiple
C O
= 10
bonds?
3) Electron
Final
C O
C O
pairs in
structure
or
10 - 2 = 8
bonds
C O
• Try PE7 (pg. 241) (answer for HClO4 is
wrong in book - missing an O)
CO
Resonance structures
• A resonance structure can be drawn for any
molecule in which a double bond can be
formed from two or more identical choices
• Resonance structures can be drawn 2 ways…
–
–
O
1
H
C
H
C
O
–
O
2
H C
[
] [
[
O
Placing electrons around atoms
Lewis Structures
• Once we have determined the number of
total valence electrons we can start
distributing them throughout the molecule
• The rules for this are outlined in fig. 7.4 (pg.
241). These also appear on study notes
(with additional details added)
• When we represent electrons they will be in
pairs (since an orbital holds 2 electrons)
• Electron pairs can be represented with 2
dots or a solid line …
O
• Once we have determined the basic
structure of the molecule we can start
placing electrons around atoms
• The first step is to determine the total
number of electrons that are available
• We use the group number of an element to
indicate the number of valence electrons
that it contributes to the molecule.
• E.g. O in group VIA (6A), contributes 6 e–s
• Read 7.6 (pg. 237) up to PE6 (including
example). Do PE6.
O
2 peripheral Lewis’ bonded to a central Lewis
• Because there are exceptions to the octet
rule, we need a set of rules to determine
how many electrons surround atoms
• The first step is to determine how the atoms
are bonded in a molecule
• Generally, if there is only one of one
element and multiple copies of another
element, the unique element is central
• Commonly, H is peripheral, bonded to O
• Read 7.6 (pg. 236) up to PE5. Do PE5.
]
]
• Resonance implies that the bond flips back
and forth. Really, it lies between extremes
• Read 7.7 (pg. 242). Do PE 8.