Western Cape Education Department CURRICULUM DEVELOPMENT: FET CAPS EXEMPLARS SBA GRADE 12 PHYSICAL SCIENCES 2014 Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 EXEMPLARS CAPS GRADE 12 1. GENERAL PRINCIPLES 1.1 Teachers should do the experiment before they design the worksheet for the experiment that their learners will do. 1.2 The teacher should develop a marking memorandum that is a good guide to mark each learner’s experiment. 1.3 The experiment should be scheduled to commence after the subject content is taught in the classroom. 1.4 Learners should do the experiment on their own. 1.5 Theoretical questions on content should not be part of the experiment. However, they have value and should be asked as informal assessment or as an integral part of a control test or an examination. 1.6 Mark totals for practical tasks should be converted to a mark out of 15, correct to the first decimal place, for transfer to the mark schedule. 2. EXPERIMENT 1 EXAMPLE OF A WORKSHEET: See Annexure A, page 20 2.1 Aim: To prepare different esters and identify the esters by their smell. The following experiments have to be done: Experiment 1(a): Prepare methyl ethanoate and identify its smell Experiment 1(b): Prepare ethyl ethanoate and identify its smell Experiment 1(c): Prepare pentyl ethanoate and identify its smell Experiment 1(d): Prepare methyl salicylate and identify its smell Experiment 1(e): Prepare ethyl salicylate and identify its smell Experiment 1(f): Prepare pentyl salicylate and identify its smell These experiments can be combined into one experiment as illustrated at 2.2. Copyright reserved 2 Please turn over Physical Sciences 2.2 WCED Gr12 CAPS Exemplar Jan 2013 Write Up for Experiment 1(a) to 1(f): [27 marks] Aim: To prepare the following esters and to identify each of their smells. Methyl ethanoate Ethyl ethanoate Pentyl ethanoate Methyl salicylate Ethyl salicylate Pentyl salicylate All WCED schools should use the following headings for the Write Up and should adhere to the mark weighting and distribution for each heading. MARKING MEMORANDUM: 2.2.1 PLANNING [9 marks] The following marking scheme should be used. (a) Naming or Drawing apparatus (3) (Including chemicals) None named or Some named or All named or drawn. Drawn or Drawn & correct. Incorrect. 0 6 (b) to Identification of variables (3) (Award 1 mark for each correct variable and zero marks if none are correct.) (c) Collecting , recording and evaluating data (3) (Award zero marks if none are described or appropriate) [9] 2.2.2 RESULTS [15 marks] The following marking scheme should be used. Copyright reserved 3 Please turn over Physical Sciences (a) WCED Gr12 CAPS Exemplar Jan 2013 Table (9 marks) (One table summarizing all the results): No table is provided OR Table is incorrect/inappropriate (0) Table heading is appropriate (1) Column headings are appropriate (2) Data is appropriate , accurate and correct (3) Data was evaluated or measurements are repeated at least three times (3) Balanced chemical equation for each reaction (6) (One mark for each correctly balanced equation.) [15] 2.2.3 CONCLUSION or FINDINGS [3 marks] Results are correctly interpreted (3) [3] TOTAL MARK 2.3 /27/ METHOD [0 marks] Although the method is provided in textbooks, a suggested method is provided below. SAFETY: 1. Alcohols are flammable and organic acids are corrosive. Sulphuric acid is poisonous, dangerous and corrosive. It burns body tissue and may be fatal if swallowed. 2. Methanol, ethanol and pentanol have flashpoints of 12 oC, 16,6 oC and 49 oC respectively i.e. the lowest temperature at which their vapours ignite. These temperatures are lower than the boiling point of water which is 100 oC. Copyright reserved 4 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 3. For more information on the hazards associated with methanol, ethanol, ethanoic acid (acetic acid (glacial)) and ethyl ethanoate please consult your laboratory manual. 4. Solutions containing flammable liquids must not be heated in a test tube. Use a cotton wool plug to prevent alcohol from spilling and heat the test tube containing the solution by using a water bath. Keep the test tube vertical in the water bath. 5. All glassware used in this experiment must be heat resistant. 6. Do not overheat the reaction mixture. It must not boil. 7. Do not place your nose directly over the test tube to smell the ester produced while the water bath is being heated. 8. All chemicals are hazardous. Wear safety goggles and gloves when handling chemicals 9. Ensure that all gas taps are closed before and after the use of Bunsen burner(s). Suggested method: Step 1: Make a water bath by pouring 50 cm3 of water into a 100 cm3 beaker. Place the beaker on wire gauze that rests on a tripod stand. Place a Bunsen burner under the gauze wire. Step 2: Add 10 drops of ethanol to 10 drops of ethanoic acid (acetic acid (glacial)) in a dry test tube. Add 5 to 10 drops of concentrated sulphuric acid to this mixture. Step 3: Place cotton wool in the mouth of the test tube. Lower the test tube into the water bath using tongs. Step 4: Heat the water in the water bath using the Bunsen burner. Cool the test tube under running water. Copyright reserved 5 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 Step 5: Pour the contents of the test tube into a 100 cm3 beaker containing 50 cm3 of cold water. Now identify the smell of the ester by wafting the escaping gas from the test tube towards your nose using your hand. Repeat steps 1 to 5 for the other esters. In the preparations involving salicylic acid, Step 2 is as follows: Mix 1 g of salicylic acid with 2 drops of concentrated H2SO4 and 2 cm3 of the alcohol. NOTES: The smell of carboxylic acid may interfere with the smell of the ester formed. If this is the case, make a Na2CO3(aq) solution of concentration 0,5 mol.dm-3, and then pour the contents of the test tube in Step 4 into 50 cm3 of the Na2CO3 solution. The Na2CO3 neutralises the ethanoic acid. In general, esters are not miscible with water. When added to water two layers form, one is water and the other is the ester. This allows the ester to be separated from the water for identification. 2.4 MARK CONVERSION The mark out of 27 is reduced to a mark out of 15, expressed correct to the first decimal place, for transfer to the mark schedule. Copyright reserved 6 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 3. EXPERIMENT 2 3.1 Aim: To determine the concentration of a solution of sodium hydroxide using a standard solution of oxalic acid. In this experiment a standard solution of oxalic acid of concentration 0,06 mol.dm-3 and a solution of sodium hydroxide of concentration approximately 0, 03 mol.dm-3, is prepared in advance for the titration by the teacher. 3.2 Write Up for Experiment 2: Use a standard solution of oxalic acid of concentration 0,06 mol. dm-3 to determine the concentration of a sodium hydroxide solution of concentration approximately 0,03 mol.dm-3 . [30 marks] All WCED schools should use the following headings for the Write Up and should adhere to the mark weighting and distribution for each heading. MARKING MEMORANDUM: 3.2.1 PLANNING [6 marks] The following marking scheme should be used. (a) Naming or Drawing apparatus (3) (Including chemicals) None named or Some named or All named or Drawn. Drawn or Drawn & correct. 0 3 Copyright reserved Incorrect. to 7 Please turn over Physical Sciences (c) WCED Collecting Gr12 CAPS Exemplar , recording and evaluating Jan 2013 data (3) (Award zero marks if none are described or appropriate) [6] 3.2.2 RESULTS [24 marks] The following marking scheme should be used. (a) Table (9 marks): No table is provided OR Table is incorrect/inappropriate (0) Heading is appropriate (1) Data is appropriate , accurate Data was evaluated and correct (6) or measurements are repeated at least three times (2) [9] CALCULATION OF CONCENTRATION OF NAOH If no calculation or calculation incorrect (0) Appropriate balanced equation (1) Correct formula: LHS (2) = RHS (mol ratio) Substitution: (2) [5] SLIDING SCALE [10] [NaOH] obtained is marked with a sliding scale (10) The following sliding scale will be used to assess the accuracy and correctness of the [NaOH] solution you obtained. 0 1 100% 50% 2 3 4 5 Mark s 6 7 8 Correct value (10 marks) marks) Values below correct value 9 30% 20% 12% 10% 8% 6% 4% 2% Copyright reserved Values above correct value Mark 9 8 2% 4% 6% %age 8 Error 7 6 5 4 3 2 8% 10% 12% 20% 30% 1 50% Please turn over 0 100% Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 [10] Total mark: /30/ 3.3 Method Although the method is provided in textbooks, a suggested method is provided below. SAFETY: 1. Oxalic acid is corrosive. It can be fatal if swallowed. 2. Sodium hydroxide is poisonous, harmful if inhaled, burns the skin and it may be fatal if swallowed. 3. All chemicals are hazardous. Please consult your laboratory manual for more information about why oxalic acid, sodium hydroxide and sulphuric acid are hazardous. 4. Wear safety goggles and gloves when handling chemicals. Suggested method: Set up the apparatus that will be used to do this experiment. Use a 25 cm3 pipette to transfer 25 cm3 of the oxalic acid provided to a 250 cm3 Erlenmeyer flask. Add 5 drops of phenolphthalein indicator to the oxalic acid in the Erlenmeyer flask. Fill the burette up to the 50 cm 3 mark with the sodium hydroxide solution provided. Titrate until the colour of the solution turns pink. Record your results. Repeat the experiment at least three times. 3.4 MARK CONVERSION The mark out of 30 is reduced to a mark out of 15, expressed correct to the first decimal place, for transfer to the mark schedule. Copyright reserved 9 Please turn over Physical Sciences 4. WCED Gr12 CAPS Exemplar Jan 2013 EXPERIMENT 3 This experiment consists of two parts viz. 4.1 Part l Aim: To determine the internal resistance of a battery Part ll Aim: To determine the equivalent resistance of: 4.2 (a) Resistors in series (b) Resistors in parallel Write Up for Experiment 3 - Part l: To determine the internal resistance of a battery. [40 marks] All WCED schools should use the following headings for the Write Up and should adhere to the mark weighting and distribution for each heading. MARKING MEMORANDUM: 4.2.1 PLANNING [9 marks] The following marking scheme should be used. (a) Naming or Drawing apparatus None named or Some named or All named or Drawn/Inappropriate Drawn or Drawn & Incorrect. correct. 0 3 (b) (3) Or Identification of variables (3) (Award 1 mark for each correct variable and zero marks if none are correct.) Copyright reserved 10 Please turn over Physical Sciences (c) WCED Collecting Gr12 CAPS Exemplar , recording Jan 2013 and evaluating data (3) (Award zero marks if none are described or appropriate) [9] 4.2.2 RESULTS [28 marks] The following marking scheme should be used. (a) Table (9 marks): No table is provided OR Table is incorrect/inappropriate (0) Heading is appropriate (1) Data is appropriate , accurate Data was evaluated and correct (6) or measurements are repeated at least three times (2) [9] (b) Graph (9 marks) No graph is provided OR Graph is incorrect/inappropriate (0) Heading is appropriate (1) Scale is appropriate (2) Axes correctly labelled (2) Appropriate type of graph chosen (2) Points plotted correctly (2) [9] (c) Accuracy of the answer (10 marks) The answer for r is marked with a sliding scale 0 1 100% 50% 2 3 4 5 Mark s 6 7 8 Correct value (10) marks) Values below correct value 9 30% 20% 12% 10% 8% 6% 4% 2% Copyright reserved Values above correct value Mark 9 8 2% 4% 6% %age Error 11 7 6 5 4 3 2 8% 10% 12% 20% 30% 1 50% Please turn over 0 100% Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 [10] 4.2.3 EXPLAINING HOW THE RESULTS WERE OBTAINED [3 marks] No explanation is Explanation is Complete given incomplete explanation is 0 3 given. Or [3] Total mark for Part l: 4.3 /40/ METHOD Although the method is provided in textbooks, a suggested method is provided below. SAFETY: 1. Prevent electrical shock. Use a torch cell. 2. Do not use mains voltage or operate any device that needs mains voltage to work. Suggested method: Set up a circuit as follows: V A S Take a reading on the voltmeter and ammeter when the switch S is open. Copyright reserved 12 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 Close the switch S. Set the rheostat at various resistance values starting at a low resistance. Record the ammeter and voltmeter reading in each case. Repeat the experiment at least three times. Record your results in a table and in a graph of V (voltmeter readings) versus I (ammeter readings). Measure the gradient of the graph. Write your answer as a positive value. This is the internal resistance of the battery. 4.4 Write Up for Experiment 3 - Part ll: To determine the equivalent resistance of: (a) (b) (i) Two resistors in series [36 marks] (ii) Three resistors in series [10 marks] (iii) Four resistors in series [10 marks) (i) Two resistors in parallel [36 marks] (ii) Three resistors in parallel [10 marks] (iii) Four resistors in parallel [10 marks] All WCED schools should use the following headings for the Write Up and should adhere to the mark weighting and distribution for each heading. PART ll (a) (i): To determine the equivalent resistance of Two resistors in series. MARKING MEMORANDUM: 4.4.1 PLANNING [9 marks] The following marking scheme should be used. (a) Naming or Drawing apparatus None named or Copyright reserved (3) Some named or 13 All named or Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Drawn. Drawn or Drawn & correct. Incorrect. 0 3 (b) Jan 2013 to Identification of variables (3) (Award 1 mark for each correct variable and zero marks if none are correct.) (c) Collecting , recording and evaluating data (3) (Award zero marks if none are described or appropriate) [9] 4.4.2 RESULTS [24 marks] The following marking scheme should be used. (a) Table (9 marks): No table is provided OR Table is incorrect/inappropriate (0) Heading is appropriate (1) Data is appropriate , accurate Data was evaluated and correct (6) or measurements are repeated at least three times (2) [9] (b) Calculations (Calculated and measured values) None done OR Are incorrect OR Are inappropriate (0) Incomplete OR Partly correct (3) (1 to 3 marks) Complete and correct (2) [5] (c) Accuracy of the answer obtained through measuring (10 marks) Use the sliding scale 0 1 2 3 4 5 Mark s 6 7 8 Correct value (10marks) marks) Values below correct value Copyright reserved Values above correct value Please turn over 14 Mark 9 9 8 7 6 5 4 3 2 1 0 Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 [10] 4.4.3 EXPLAINING COMPARISON BETWEEN EXPERIMENTAL AND THEORETICAL ANSWERS [3 marks] No explanation is Explanation is Complete given incomplete explanation is 0 3 given. Or [3] Total mark for experiment 3 (a) (i): 4.5 /36/ METHOD (Experiment 3 (a) (i)) Although the method is provided in textbooks, a suggested method is provided below. SAFETY: 1. Prevent electrical shock. Use a torch cell. 2. Do not use mains voltage or operate any device that needs mains voltage to work. Suggested method: Set up a circuit as follows, using two resistors in series: Copyright reserved 15 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 S A V Close the switch S and write down the reading on the ammeter and voltmeter. Use these readings to calculate the total resistance of the two resistors in series. Calculate the theoretical value of their total resistance. Repeat this part of the experiment three times. PART ll (a) (ii): To determine the equivalent resistance of three resistors in series. MARKING MEMORANDUM: (c) Accuracy of the answer obtained through measuring (10) Use the same sliding scale in 4.4.2 (c) [10] Total mark for experiment 3 (a) (ii): PART ll (a) (iii): /10/ To determine the equivalent resistance of four resistors in series. MARKING MEMORANDUM: (c) Accuracy of the answer obtained through measuring (10) Use the same sliding scale in 4.4.2 (c) [10] Total mark for experiment 3 (a) (iii): Copyright reserved 16 /10/ Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Total mark for experiment 3 (a): 4.6 Jan 2013 /56/ Write Up for Experiment 3 - Part ll (b): To determine the equivalent resistance of: (b) (i) Two resistors in parallel [36 marks] (ii) Three resistors in parallel [10 marks] (iii) Four resistors in parallel [10 marks] This experiment is similar to Part ll (a). The main difference is that the resistors are now connected in parallel. Otherwise the Method, the Write Up and the mark allocation is the same. 4.7 MARK CONVERSION Experiment 3 Part l is assessed out of 40 marks. Part ll (a) and (b) are assessed out of 56 marks. The total mark obtained, viz. 40 + (2 x 56) = 152, is reduced to a mark out of 15, expressed correct to the first decimal place for transfer to the mark schedule. Copyright reserved 17 Please turn over Physical Sciences 5. WCED Gr12 CAPS Exemplar Jan 2013 EXPERIMENT 4 Aim: To verify that momentum is conserved during an explosion. 5.1 Write Up for Experiment 4: To verify that momentum is conserved during an explosion if the: (a) Two trolleys carry the same mass [26] (b) One trolley carries twice the mass of the other trolley [10] (c ) One trolley carries a mass that is three times that of the other trolley [10] The Write Up is the same as that for Experiment 3 – Part ll (a) [56 marks] 5.2 METHOD Although the method is provided in textbooks, a suggested method is provided below. SAFETY: Suggested method Take two identical trolleys and place a brick of the same mass m on each of them. At least one of the trolleys must have a spring plunger. Place the trolleys on a level horizontal frictionless surface. Clamp two wooden blocks at equal distances x from each trolley. Release the knob. Press the knob x Copyright reserved m m 18 x Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 Each trolley must strike the wooden block at the same time t. Repeat three times. Repeat the experiment by placing another brick on one trolley. Repeat the experiment by placing another brick on the trolley that has the two bricks. Record your results in a table. 5.3 MARK CONVERSION The total mark out of 56 is reduced to a mark out of 15, expressed correct to the first decimal place for transfer to the mark schedule. Copyright reserved 19 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 ANNEXURE A EXAMPLE OF A CAPS GRADE 12 WORKSHEET: SCHOOL: …………………………………. DATE: …………………………… SBA: PRESCRIBED EXPERIMENT: PHYSICAL SCIENCES NAME OF LEARNER: ………………………… GRADE: …………………… GROUP: …………………… KNOWLEDGE AREA: Chemical Change TOPIC: Acids and Bases DUE DATE: ………………………………. TOTAL MARK: ………/30 AIM: To determine the concentration of a solution of sodium hydroxide using a standard solution of oxalic acid. In this experiment you will be provided with: A standard solution of oxalic acid of concentration 0,06 mol.dm -3 A sodium hydroxide solution of concentration approximately 0,03 mol.dm-3 METHOD: Suggested method: Set up the apparatus that will be used to do this experiment. Use a 25 cm 3 pipette to transfer 25 cm3 of the oxalic provided to a 250 cm3 Erlenmeyer flask. Add 5 drops of phenolphthalein indicator to the oxalic acid in the Erlenmeyer flask. Fill the burette up to the 50 cm3 mark with the sodium hydroxide solution provided. Titrate until the colour of the solution turns pink. Record your volume readings. Repeat the experiment at least three times. Copyright reserved 20 Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 INSTRUCTIONS (a) Read and understand the method to: Determine the concentration of the sodium hydroxide solution using the standard solution of oxalic acid provided by your teacher. (b) You will be penalised if: o The work you submit is not your own o You do not hand in this assessment task by the due date (c) Report your investigation using the headings below (marks are written in brackets) PLANNING THE INVESTIGATION [6 marks] The following should be reported on: (a) Apparatus (3) (Naming or drawing each item of apparatus used) (b) Data (3) (Collecting, recording and evaluating data) [6] RESULTS [24 marks] (a) Table (Recording results in a table) (9) (b) Calculations (5) [14] (10) SLIDING SCALE (Marking the [NaOH] with a sliding scale) [10] Total mark: Copyright reserved 21 /30/ Please turn over Physical Sciences WCED Gr12 CAPS Exemplar Jan 2013 NOTES FOR THE TEACHER (a) Safety: 1. Oxalic acid is corrosive. It can be fatal if swallowed. 2. Sodium hydroxide is poisonous, harmful if inhaled, burns the skin and it may be fatal if swallowed. 3. All chemicals are hazardous. Please consult your laboratory manual for more information about why oxalic acid and sodium hydroxide are hazardous. 4. (b) Wear safety goggles and gloves when handling chemicals Accuracy of the results: In this experiment accuracy should be exploited to achieve a spread of marks. Accuracy can be judged by the value of the [NaOH] which will be marked with the sliding scale. Do the following to obtain accurate results: All glassware/apparatus used must be clean The measuring flask should only be held at its mouth Wash the beaker that contained the oxalic acid solution with distilled water. Pour this solution into the measuring flask The burette must be greased appropriately so that it works and does not leak when the tap is opened and closed. NaOH absorbs water and CO2 from the air. This changes the concentration of the NaOH(aq). Make a fresh sample for the titration but use it immediately. Do not exceed the endpoint of the titration (c) Other methods: The double burette method can also be used. (d) Assessment: Each learner should do this investigation on their own. Do not assess group work. Each learner should sign a declaration of authenticity. Copyright reserved 22 Please turn over