A4 Harnessing chemicals advance planning page 1 TWENTY FIRST CENTURY SCIENCE Applied Science A4 Harnessing chemicals Technicians’ advance planning sheets This table shows items that may need to be ordered in advance for this module. It does not list standard items, such as test-tubes and OHT pens. Full details of the resources needed for each activity are given in the Requirements section of the Teacher & Technician notes published by OUP, which also include safety information for the activity. Activity Item(s) Quantity per student / group of students, or for the teacher Notes AA4.1 Selection of containers of healthcare products OTC medicines 1 Prescription medicines 1 e.g. antiseptics, iron tablets. e.g. aspirin, cough linctus, antacids. A local pharmacy may be able to provide suitably labelled empty containers. AA4.2 Range of containers for commercial paints and cosmetics 1 Include a range of mixtures that include solutions, solid mixtures and emulsions. Include sunblocks and sunscreens. AA4.3 Range of food packets 1 Make sure ingredients are listed. AA4.4 Sand damp with sea water or salty water Dilute nitric acid (less than 0.4 mol/litre) Dilute silver nitrate (about 0.1 mol/litre or 2 g in 100 cm3. AA4.5 Copper sulfate AA4.6 Plant material (lavender and orange rind) 1 Few drops Few drops See safety information in the Teachers notes. 6g Harvest lavender blooms and stalks in July, hang to dry for future use. Use only the outer orange coloured rind which needs to be fresh. 1 A4 Harnessing chemicals advance planning page 2 Activity Item(s) Quantity per student / group of students, or for the teacher AA4.8 2 indicators in dropping bottles selected from:methyl orange, bromothymol blue, litmus or phenolphthalein Universal indicator & charts Limewater (calcium hydroxide), dilute sodium hydroxide, dilute potassium hydroxide, dilute hydrochloric acid, dilute nitric acid, dilute sulfuric acid 2-3 drops Small pieces of magnesium Black copper oxide 2 AA4.9 Small marble chips Dilute hydrochloric (2 mol/litre) Dilute ethanoic acid AA4.10 AA4.11 Notes 2-3 drops 2 cm3 of each Small spatula measure 4 15 cm3 15 cm3 Silver nitrate (1 g in 100 cm3) Sodium Nitrate (2 g in 100 cm3) Lead Nitrate (6.5 g in 100 cm3) Barium chloride (5 g in 100 cm3) Copper sulphate (5 g in 100 cm3) 2-3 cm3 Selection of containers with hazard labels 1 2-3 cm3 2-3 cm3 2-3 cm3 2-3 cm3 2 Use solutions of alkali that are 0.4 mol/litre or below. See safety information in the Teachers notes. A4 Harnessing chemicals advance planning page 3 Activity Item(s) Quantity per student / group of students, or for the teacher Notes AA4.13 Large marble chips (20 g) 1 Small marble chips (20 g) 1 See technical notes regarding treatment of marble chips prior to use. See technical notes regarding treatment of marble chips prior to use. Dilute hydrochloric acid, (2 mol/litre labelled 75 g/litre) 80 cm3 Magnesium ribbon (30 mm strip) Small piece of emery paper Dilute hydrochloric acid (2 mol/litre) 2 Sodium thiosulfate solution (40 g/litre) Dilute hydrochloric acid (2 mol/litre) 60 cm3 Potassium iodide solution (33 g/litre) Sodium thiosulfate solution (2.5 g/litre) Fresh starch solution (0.5 g in 250 cm3 solution) Potassium peroxodisulfate (persulfate) saturated solution Copper sulphate solution (2.5 g in 100 cm3) Iron (II) sulphate solution (3 g in 100 cm3 of 1.0 mol/litre sulphuric acid) 40 cm3 Iron (III) chloride solution (3 g in 100 cm3 of water acified with dilute hydrochloric acid 3 drops AA4.14 AA4.15 AA4.16 AA4.16 1 75 cm3 40 cm3 40 cm3 20 cm3 80 cm3 3 drops 3 drops 3 A4 Harnessing chemicals advance planning page 4 Activity Item(s) Quantity per student / group of students, or for the teacher AA4.17 Magnesium carbonate (basic) 4g Zinc oxide AA4.18 AA4.19 Pigments 5g Dilute sulphuric acid (1.0 mol/litre, 50 cm with measuring cylinder) 50 cm3 Potassium hydroxide solution, 2 mol/litre (112 g/litre) 1 litre for class Hydrochloric acid, 2.0 mol/litre (73 g/litre) 1 litre for class Indicator solution in dropper bottle (methyl orange or phenolphthalein) Class set Charcoal powder 1 container Copper (II) sulphate-5water 1g Sodium hydrogen carbonate Hydrated iron (III) chloride Notes Provide sample in 100 cm3 beaker 2.7 g Potassium hexacyanoferrate (II) 2.1 g AA4.19 Cobalt (II) chloride 2.0 g Pigments Sodium 1.3 g hydrogenphosphate AA4.19 Calcium chloride-6-water 5 g Antacids crystals Magnesium sulphate-76g water crystals Sodium carbonate, 10 g anhydrous AA4.22 Glucose Brewers yeast 5g 1g 4 Fresh or dried brewers’ yeast(saccharomyces cerevisiae) may be used, a general wine- making strain. A4 Harnessing chemicals advance planning page 5 Activity Item(s) Quantity per student / group of students, or for the teacher AA4.23 Ethanol Ethanoic acid (concentrated) Concentrated sulphuric acid Sodium carbonate solution (3 g in 10 cm3 water) Calcium chloride solution (5 g in 10 cm3 water) 1 1 AA4.23 1 1 1 Anhydrous calcium chloride Selection of 4 or 5 primary alcohols Selection 4 or 5 pure carboxocylic acids AA4.26 Notes Small beaker with a dropping pipette Small beaker with a dropping pipette Concentrated Sulphuric acid Small beaker with a dropping pipette 10 % sodium carbonate solution 90 cm3 Solid citric acid crystals 30 cm3 Solid tri-sodium citrate 30 cm3 Full range indicator solution in dropper bottle 1 Dilute hydrochloric acid (0.01 mol/litre) Dilute sodium hydroxide (0.01 mol/litre) See requirements list for suggestions of primary alcohols and carboxylic acids. Few drops Few drops Examples need to show that they contain an acidity regulator (e.g. pHbalanced shampoos, eyecare products). Selection of food packets, household cleaners and health products 5 A4 Harnessing chemicals advance planning page 6 Activity Item(s) Quantity per student / group of students, or for the teacher AA4.27 Sodium chloride 1 beaker Potassium chloride 1 beaker AA4.28 Part A A range of packs of antacid tablets, suspensions, or powders AA4.28 Part B Magnesium carbonate 1 beaker Calcium carbonate 1 beaker Magnesium sulphate crystals 1 container AA4.28 Part C Sodium hydroxide pellets Notes Sample salt made in Activity AA4.18 can be used. Sample salt made in activity AA4.19 can be used. 1 container Light magnesium oxide Barium chloride solution (0.1 mol/litre in dropper bottle) 1 container several Dilute nitric acid (0.4 mol/litre) AA4.28 Part D Dilute hydrochloric acid (0.5 mol/litre) Methyl orange (or screened methyl orange in dropper bottle AA4.29 Iron (III) oxide, zinc oxide, charcoal, yellow sand or crushed yellowish dried clay, synthetic malachite, prussian blue, cobalt violet PVA glue Enough to fill a burette 1 Small sample of each in a 100 cm3 is sufficient Sample in 250 cm3 beaker 6 May use a commercial antacid tablet, one tablet made from part B or a 10 cm3 dose of magnesium hydroxide mixture from part C. Synthetic malachite, Prussian blue and cobalt violet are pigments saved from AA4.19. A4 Harnessing chemicals advance planning page 7 Activity Item(s) Quantity per student / group of students, or for the teacher AA4.30 Part A Magnesium sulphate (or Epsom salts) Sodium hydrogencarbonate (or baking soda) Sodium chloride (or cooking salt) Selection of food colours Selection of perfumes 1 measure Detergent solution, 27 % solution of sodium lauryl ether sulphate (laureth sulphate) Sodium chloride Selection of food colours Selection of perfumes 50 cm3 Stearic acid Glycerol (propan-1-2-3triol) Potassium hydroxide solution, 1 g in 100 cm3 Sample of perfume, greasepaint, cotton wool 15 g 8g Potassium hydroxide pellets Phthalic anhydride Narrow-range indicator or pH sensor and meter Burette with hydrochloric acid (0.1 mol/litre) Burette with sodium hydroxide solution (0.1 mol/litre) Chemical catalogue or a list of prices 7g AA4.30 Part B AA4.30 Part C AA4.31 2 measures 1 measure Small sample 76 cm3 18.5 g 7 Notes A4 Harnessing chemicals advance planning page 8 Activity Item(s) Quantity per student / group of students, or for the teacher Notes AA4.34 50 cm3 syringe barrel with a short tube and tube clip Mineral wool or circle of green kitchen scourer Immobilised glucose isomerase enzyme (sweetzyme) Glucose solution (4 %, 50 cm3 in a container Semi-quantitive glucose test strips (e.g. clinistix) 1 This experiment can alternatively be carried out as a demonstration. Refer to guidance AA4.34. Samples of the following containers for teacher only: Hexane, methanol, ethanol, methanoic acid, ethanoic acid, ethyl ethanoate 1 IA4.3 1 5g 10 cm3 5 Sweetzyme obtained from NCBE (01189 873743). © in this format University of York (UYSEG) and Nuffield Foundation 2006 8