Climate and Global Change How humid is it anyway? Introduction Humidity has considerable to do with how we “feel” warmth. The more humid the air the warmer we feel. From a climate prospective, humidity is an important parameter when considering clouds and rain. Recall from class that we had several ways of describing atmospheric moisture. The various measures of atmospheric water vapor content and their units included the following: • Absolute Humidity Units = Mass of water vapor / Volume of air => grams / meter3 (g / m3) • Mixing Ratio Units = Mass of water vapor / Mass of dry air => grams / kilogram (g / kg) • Specific Humidity Units = Mass of water vapor / Mass of moist air => grams / kilogram (g / kg) • Vapor Pressure Units = Part of the pressure caused by water vapor molecules => inches of mercury or millibars (in of Hg or mb), • Relative Humidity Units = (actual vapor pressure) 100 / ( saturation vapor pressure ) => % • Dewpoint Temperature = Temperature at which dew (saturation) forms when air is cooled without addition or subtraction of water vapor Units => °F, °C and K • Wet-bulb Temperature = Units Temperature a thermometer can be cooled by evaporative cooling => °F, °C and K Dewpoint Temperature Measurement In this experiment we are going to use a simple, and maybe not the most accurate, “instrument” to measure the room’s dewpoint temperature. Take a shiny aluminum can (a clean silver soda can will work) and fill it partially (about half to two-thirds) full of water that is slightly warmer than the room air temperature. First, measure the room air temperature. Next, measure the temperature of the water. Is the water slightly warmer than the air temperature? If not, find some water that is warmer than the room air temperature. Climate and Global Change Now add ice to the water in the can. Stir the ice-water mixture slowly while looking at the outside of the can. Record the temperature of the ice-water mixture when the can begins to become hazy, i.e., dew or condensate starts to form on the can. This temperature is an estimate of the room’s dewpoint temperature. If the ice melts before dew starts to form add more ice. Why is this maybe not the most accurate measure of the dewpoint temperature? What if we had used an iron can instead of the aluminum can? Would our “instrument” have been more or less accurate? Hint: Think conduction (see table below). Would a copper can work better? Material Iron Aluminum Copper Heat Conductivity ( cal / s - cm - °C ) 0.161 0.50 0.918 What would it tell you if dew did not form on the can and you had cooled the water to near freezing? Relative Humidity Calculation To get an idea how the dewpoint temperature relates to relative humidity, convert the room’s dewpoint temperature you measured into relative humidity. Recall relative humidity is defined as 100 times the actual vapor pressure divided by the saturation vapor pressure, i.e., Climate and Global Change RH (%) = 100 ( actual vapor pressure ) / ( saturation vapor pressure ). Climate and Global Change As was stated in class, the saturation value depends on the temperature (for example, see the graph below, which relates the saturation specific humidity to temperature), warmer air has a higher saturation value than cooler air. One can substitute the appropriate specific humidity or mixing ratio values into the definition of relative humidity with little or no error. To determine the saturation vapor pressure of the room air, we will use the table on the next page to look up the saturation vapor pressure corresponding to the room temperature. This table is comparable to the graph only for saturation vapor pressure and it is easier to select an exact value. From the Table below, enter the saturation vapor pressure corresponding to the room’s temperature ______________ . Climate and Global Change T (°C) -40 -38 -36 -34 -32 -30 -28 -26 -24 -22 -20 Saturation T Saturation T Saturation T Saturation Vapor (°C) Vapor (°C) Vapor (°C) Vapor Pressure Pressure Pressure Pressure (mb) (mb) (mb) (mb) 0.189 -18 1.49 4 8.13 26 33.61 0.232 -16 1.76 6 9.35 28 37.79 0.284 -14 2.08 8 10.72 30 42.43 0.346 -12 2.44 10 12.27 32 47.55 0.420 -10 2.86 12 14.02 34 53.20 0.509 -8 3.35 14 15.97 36 59.42 0.613 -6 3.91 16 18.17 38 66.26 0.737 -4 4.54 18 20.63 40 73.77 0.883 -2 5.27 20 23.37 1.05 0 6.11 22 26.43 1.25 2 7.05 24 29.83 Saturation vapor pressure over water in mb versus temperature in °C The dewpoint temperature of a parcel of air represents the temperature at which the air would become saturated. Thus, to determine the actual vapor pressure, we use the table to look up the vapor pressure corresponding to the dewpoint temperature we measured. Enter the actual vapor pressure corresponding to the room’s dewpoint temperature __________ . Calculate the room’s relative humidity using the equation above. ___________ Feel the Effect of Latent Heat Predict what will happen to your hands’ temperature as you wave your hands back and forth in the air eight times. Wave your hands eight times and compare the difference in how the temperature of your hands feel. For this part of the experiment be sure your hands are dry. Soak a paper towel in room temperature water. Place the wet towel over your right hand. Predict what will happen to each hand’s temperature when you wave both hands in the air. Climate and Global Change Conduct the test and record what each hand feels. Is it cooler or warmer? Hold your arms still. Do you feel a difference in the temperatures of your hands? Explain the interactions between the heat energy from your body, i.e., the temperature of your hands, the water molecules on your hand and the air during these activities. Relative Humidity with a Sling Psychrometer Recall from lecture that when an object is wet, energy (the latent heat of vaporization) is removed from the object by evaporation. If we place a “sock” over the end of a thermometer and ventilate the thermometer, we can measure the difference between the “drybulb” (ordinary) temperature and the web-bulb temperature. This difference is referred to as the wet-bulb depression. The difference between these two temperatures is related to relative humidity of the room air. If the room is near saturation, then there will be very little evaporation from the wet-bulb thermometer. Thus, the wet-bulb and the dry-bulb will be similar, i.e., the wet-bulb depression will be small. If the room air is very dry, then there will be considerable difference between the two temperatures, i.e., the wet-bulb depression will be large. Climate and Global Change Using a table or in this case the “slide rule” on the psychrometer you will be able to obtain the relative humidity. How does this relative humidity compare to the value you calculated above? If they don’t agree, why do you suppose they are different? Cloud Bottle Demonstration This experiment demonstrates two basic principles: the Ideal Gas Law and the relationship between saturation and temperature. Place a small amount of warm water (use water heated in the teapot) in the bottom of the cloud bottle. Let the water set for a few minutes so it can come to equilibrium with the air in the bottle. Measure the temperature of the air in the bottle. Connect the pump to the bent glass tubing of the apparatus and increase the pressure inside the bottle by squeezing the hand pump (about 15 times). Measure the temperature of the air in the bottle again. Did the temperature change? –––––––––– If so, how did it change, increase or decrease? ––––––––––––––––– Using the Ideal Gas Law explain why the temperature might have changed. Now turn off the lights and shine a flashlight through the bottle. Disconnect the pump from the apparatus - you should hear a hiss as the pressure in the bottle is released and becomes the same as the pressure in the room. Did anything happen inside the bottle? If so, what? ______________________________________ Climate and Global Change Measure the temperature in the bottle once more. Did it change again? ________ If so, how did it change (increase or decrease)? _____________ Why? If the temperature of the air in the bottle changed by increasing and decreasing the pressure inside the bottle, what happened to the relative humidity of the bottle's air - did it change? If so, how did it change (increase or decrease) in relation to the temperature and pressure?