Chem B2A Exam 2A Name:____________________ Section___________________ MULTIPLE CHOICE 1. Which of the following is not a sign that a chemical reaction has occurred? a. gas bubbles forming when two substances are mixed b. the formation of a solid in a clear solution c. heat being released d. the absorption of light e. a change in color 2. Whose elementary atomic theory requires that all chemical equations must be balanced? a. Aristotle’s b. Dalton’s c. Einstein’s d. Lavoisier’ s e. Bohr’s 3. Refer to the chemical equation: ___ C3H8(g) + ___ 02(g) ___ C02(g) + __ H20(l) In the correctly balanced equation, what are the coefficients for C3H8 (g), O2 (g), CO2 (g), and H2O (l), respectively? a. 1, 1, 1, and 4 b. 1, 10, 3, and 4 c. 1, 3, 3, and 4 d. 1, 1, 3, and 4 c. 1, 5, 3, and 4 4. Supply the missing coefficient and chemical formula in the following incomplete chemical equation. 2 PbO (s) 2 Pb (s) + ___ _____ a. 2O(g) b. O(g ) c. 1/2O2(g) d. O2(g) e. 1/3O3(g) P 5. Potassium metal reacts with liquid water to form aqueous potassium hydroxide and hydrogen gas. Which of the following is the balanced chemical equation for this process? a. 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) b. K(s) + H2O(l) KOH(aq) + H2(g) c. K(s) + H2O(l) KOH(aq) + H(g) d. 2P(s) + 2H2O(l) 2POH(aq) + H2(g) e. K(s) + 2H2O(l) K(OH)2(aq) + H2(g) 6. What type of chemical reaction is the following? C5H12(l) + 8 02(g) a. b. c. d. e. 7. combination decomposition single replacement combustion double replacement What type of chemical reaction is the following? 2 AlI3(aq) + 3C12(g) a. b. c. d. e. 8. 5C02(g) + 6H20(l) 2A1C13(aq) + 3I2(s) combination decomposition single replacement combustion double replacement Which of the following is a combination reaction? a. BaCO3(s) BaO(s) + CO 2(g) b. CH4(g) + 2O2(g) CO2(g) + H2O(g) c. N2(g) + 3H2(g) 2NH3(g) d. A12O3(s) + 2Fe(s) 2Al(s) + Fe2O3(s) e. H2S(aq) + 2KOH(aq) K2S(aq) + 2H2O(l) 9. Translate the following into a correct balanced chemical equation. Aqueous silver nitrate and aqueous hydrochloric acid react to form solid silver chloride and aqueous nitric acid. a. b. c. d. e. AgNO3(aq) + HC1(aq) AgNO2(aq) + HC1(aq) AgNO3(aq) + 2HC1(aq) AgN(aq) + HC1(ag) Ag2NO3(aq) + 2HClO(aq) AgCl(s) + HNO3(ag) HNO2(aq) + AgCl(s) AgC12(s) + H2N03(aq) AgC1(s) + HN(aq) Ag(ClO)2(s) + HNO3(aq) 10. What is the definition of the atomic mass unit? a. 1/16 of the mass of an oxygen-16 atom b. 1/12 of the mass of a carbon-12 atom c. the mass of a proton d. the mass of an electron e. the mass of a neutron 11. Hydrogen sulfide is a toxic, foul-smelling gas. How many molecules of H2S are in 3.50 mol H2S? a. 2.11 x 10-24 b. 5.81 x 10-24 c. 2.11 x 1024 d. 2.11 e. 6.02 x 1023 12. What is the molar mass of copper? a. 63.5 g b. 35.0 g c. 12.0 g d. 27.0 g e. 29.0 g 13. How many mol of CaCO3 are contained in 25.0 g of CaCO3? a. b. c. d. e. 0.25 1.00 25.0 0.50 2.00 mol mol mol mol mol 14. A compound was analyzed and found to contain 47.55 percent chlorine and 52.45 percent potassium. What is the empirical formula of the compound? a. KBr b. K2Br c. KBr2 d. K2Br2 e. 2KBr 15. A compound has the empirical formula C5H40 and a molecular weight of about 240 amu. What is the molecular formula of this compound? a. 3C5H40 b. C5H40 c. C15H40 d. C15H1203 16. Phosphorus trichloride, which is used as a starting material in the production of pesticides, is a highly irritating material. PCl3 can be made from the direct reaction of phosphorus and chlorine according to the balanced equation: P4 (s) + 6C12 (g) 4PC13 (g) How many molecules of PCl3 are produced when one molecule of P4 reacts? a. 7 b. 1 c. 4 d. 10 e. 11 17. The balanced chemical equation for the neutralization of hydrochloric acid with magnesium hydroxide is: Mg(OH)2 + 2HC1 2H20 + MgCl2 How many mol of magnesium hydroxide is required to neutralize 0.250 mol of HC1? a. 1.00 b. 0.125 c. 0.500 d. 2.00 e. 8.00 18. Use the balanced chemical equation in the above problem to work the following problem. How many grams of HCl are required to react exactly with 58 g of Mg(OH)2? a. 19. 7.09 b. 70.9 c. 35.5 d. 24.0 e. 18.0 In the reaction in question 17 calculation was made shoing that 25 g of MgCl2 should be produced. When the product was weighed only 22.5 gram was recovered. What is the percent recovery? Show calculations. 20. What is an electron orbital? a. b. c. d. e. a well-defined distance where an electron is found a region in space around the atomic nucleus in which the electron is likely to be found a definite path that the electron follows a region inside the atomic nucleus in which an electron is likely to be found a very definite orbit in which an electron is found 21. Which of the following is the electron configuration for N? a. b. c. d. e. 22. 1s22s22p1 1s22s22p2 1s22s22p3 1s22s22p4 1s22s22p5 How many orbitals are contained in the principle energy shell designated by n = 3? a. 1 b. 9 c. 18 d. 3 e. 32 23. What element has the following electronic configuration? 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p4 a. S b. Se c. Te d. Ge e. As 24. Which element from the following list would have atoms of the largest radius? a. potassium 25. b. sodium c. beryllium d. magnesium e. calcium Explain the Bohr theory of the atom. 25. What is likely to have happened when an electron in an atom undergoes a transition from a lower energy state to a higher energy state? 26. List five signs that a reaction has taken place. 27. List five symbols included in a chemical reaction and tell what they represent? 28. Write the Lewis dot structures of the elements in period 2 of the periodic chart and indicate how many bonds each would be expected to form. 29. Explain how ionic bonding and covalent bonding are different 30 Are you ready for the test to be over? Yes_____ No______ Match the following terms and definitions: 1. Reactant ___ Yields hydrogen ions in water. 2. Product ___ Changes the rate of a reaction 3. Chemical Equation ___ Positively charged ion 4. Combination Reaction ___ Reaction with oxygen, pure or in air. 5. Decomposition Reaction ___ Maximum product that can be recovered in a reaction. 6. Single Replacement Reaction ___ Use of balanced equation for reaction calculations. 7. Activity Series ___ Discrete packet of energy in the form of light. 8. Catalyst ___ Chemical substance involved at the start of a reaction. 9. Precipitate ___ Wave function for an electron in an atom. 10. Double Replacement Reaction ___ Mass of one mole of substance. 11. Insoluble ___ Yields a hydroxide ion in water 12. Acid ___ Reactant that is used up first when a reaction goes to completion. 13. Base ___ Mass standard and basis of Avogadro’s number. 14. Salt ___ Solid formed when a reaction takes place. 15. Combustion Reaction ___ Arrangement of elements according to their chemical activity. 16. Neutralization ___ Reaction represented by AB + C ------> AC + B 17. Coefficients ___ Special double replacement reaction between acid and base. 18. Mole ___ Mass of product actually recovered in a reaction. 19. Avogadro’s Number ___ Exact amount required in a reaction. 20. Formula Weight ___ Reaction represented by AB + CD -----> AC + BD 21. Molar Mass ___Electrons do not pair up until all orbitals have an electron. 22. Empirical Formula ___Set of orbitals of approximately the same size and energy. 23. Molecular Formula ___Material formed along with water in a neutralization reaction. 24. Actual Yield ___ Energy required to remove an electron from an atom. 25. Limiting Reactant ___ Properties of elements arranged in numerical order repeat. 26. Line Spectrum ___ States that an orbital can hold no more than two electrons. 27. Stoichiometry ___ Subset of orbitals with same shape and energy level. 28. Theoretical Yield ___ 6.022 x 1023 molecules. 29. Stoichiometric Quantity ___ Number in front of a formula in a chemical equation. 30. Electron Shell ___ Equation represented by C -------> A + B 31. Electron Configuration ___ Material resulting from a chemical reaction. 32. Subshell ___ Distribution of electrons among the different subshells. 33. Photon ___ Reaction represented by A + B--- > C 34. Hund’s Rule ___ Formula with smallest possible whole number subscripts. 35. Pauli’s Exclusion Principle ___ A material that will not dissolve. 36. Periodic Law ___ Symbolic way of representing a chemical reaction. 37. Ionization Energy ___ Sum of atomic weights of all atoms in a formula unit. 38. Carbon Twelve ___ Negatively charged atom or unit made up of atoms. 39. Cation ___ Elements with similar properties on the periodic chart. 40. Anion ___ A horizontal row of elements on the periodic chart. 41. Period ___One of the allowed energy values an electron can have. 42. Chemical Group ___ Element first discovered on the sun. 43. Energy Levels ___ Mass of material containing Avogadro’s number of units. 44. Helium ___ Sum of the mass of all atoms in a formula in amus. 45. Orbital ___Actual formula of a molecule (multiple of empirical formula).