NCEA Level 1 Chemistry (90172) 2009 — page 1 of 2 Assessment Schedule – 2009 Chemistry: Describe atomic structure and bonding (90172) Evidence Statement Q ONE (a) (b) Evidence Achievement Achievement with Merit Achievement with Excellence Isotopes are atoms of the same element that have different masses / mass numbers / numbers of neutrons in their nuclei. THREE correct, must be from at least 2 parts (a), (b), (c). THREE correct, must be one from each of (a), (b), (c). Correctly defines the term isotope Carbon-12 has an atomic structure made up of 6 protons, 6 electrons and 6 neutrons. Carbon-13 and carbon-14 also have 6 protons and 6 electrons, but C-13 has 7 neutrons and C-14 has 8 neutrons. Correctly defines the term isotope. Methane Carbon monoxide (c) The particles in methane are molecules. The particles are held together by weak intermolecular forces / bonds. It takes very little energy to break these forces. This results in the low melting point. The particles in calcium carbide are ions. They are held together in a lattice by strong ionic bonds. These bonds require a lot of energy / are harder to break. This results in the high melting point. The different melting points of these two carbon-containing substances occur because of their different forms of bonding. OR Correctly identifies the full atomic structure of 2 of the carbon isotopes / correct number of neutrons for 3 isotopes. OR Correctly draws one Lewis Diagram. OR Correctly names the particles in each substance. OR Correctly names the type of bonding between particles in each substance. OR Correctly names particles and bonding for one substance. Correctly defines the term isotope. OR Correctly identifies the full atomic structure of 2 of the carbon isotopes / correct number of neutrons for 3 isotopes. AND Correctly draws one Lewis diagram. AND Links type of particle AND type of bonding for ONE substance, to melting point / energy to break bond. AND Correctly identifies the atomic structure of 2 of the carbon isotopes / correct number of neutrons for 3 isotopes AND Correctly draws Lewis Diagram for carbon monoxide AND Discusses type of particle AND type of bonding for BOTH substances in relation to each of their melting points / energy to break bonds. NCEA Level 1 Chemistry (90172) 2009 — page 2 of 2 TWO (a) (b) Fluorine and chlorine both have 7 valence electrons / are both in Group 17. F: 2,7 Cl: 2,8,7 Gives correct electron configurations for all 4 elements Neon and argon both have a full valence shell / are both in Group 18. Ne: 2,8 Ar: 2,8,8 OR Describes F and Cl as reactive AND Ne and Ar as unreactive Neon and argon both have full valence shell / are already stable so both are unreactive. Fluorine and chlorine, however, are not stable / they both require 1 electron to become stable. This makes them both very reactive. OR Correctly explains the boiling and melting points / energy to break bonds of EITHER Ne or Cl. The intermolecular forces between neon atoms are small / weak. (The amount of energy required to break the attractive forces / to change state is small.) Solid MgCl2 is ionic (magnesium is present as magnesium ions, Mg2+, and chlorine is present as chloride ions, Cl–). These ions are held tightly in an ionic lattice when solid, there is no movement of ions, and so solid MgCl2 does not conduct electricity. In molten MgCl2, the chloride and magnesium ions are free to move. Since current is carried by charged particles that are free to move, molten MgCl2 can conduct electricity. In gaseous chlorine, the chlorine atoms form molecules of Cl2. Molecules are not charged particles so cannot carry an electric current. Though the chlorine molecules are free to move, chlorine gas is not a conductor of electricity. AND Correctly links the boiling and melting points / energy to break bonds of EITHER Ne or Cl. OR All (a) correct Gives correct electron configuration AND makes links to the reactivity for Cl,F AND Ne,Ar. Must state that F, Cl both require 1 electron. AND Correctly discusses the boiling and melting points / energy to break bonds of BOTH Ne and Cl. OR All (b) correct. The intermolecular forces between chlorine molecules are larger / stronger than for neon. (The amount of energy required to break the attractive forces / to change state is more than neon.) THREE Gives correct electron configuration AND makes links to the reactivity for F, Cl OR Ne, Ar. Must state that F, Cl both require 1 electron. Describes 1 point Links 2 points Discusses 3 points Conductivity of ONE of: MgCl2(s) / MgCl2(l) / Cl2(g) described in relation to particles. Conductivity of TWO of: MgCl2(s) / MgCl2(l) / Cl2(g) fully described and linked to particles. Conductivity of THREE: MgCl2(s), MgCl2(l),Cl2(g) discussed in relation to particles. Must show understanding of how electricity is conducted (electrons carrying charge negates) Must show understanding of how electricity is conducted (electrons carrying charge negates) Must show understanding of how electricity is conducted (electrons carrying charge negates) Must state molecules for Cl2 and ions / ionic substance for MgCl2. Must state molecules for Cl2 and ions / ionic substance for MgCl2. Must state molecules for Cl2 and ions / ionic substance for MgCl2. Judgement Statement Achievement Achievement with Merit Achievement with Excellence 2A 2M+1A 2E+1M OR 2E