DEP05-0170 STATE OF FLORIDA DEPARTMENT OF ENVIRONMENTAL PROTECTION IN RE: Phosphoric Acid Fertilizer Manufacturing Facilities OGC File No. 04-1590 FOURTH AMENDED IMMEDIATE FINAL ORDER Under sections 120.569(2)(n), 373.026(7), 373.119(2), and 373.119(3) of the Florida Statutes, and rule 62-330.200(3)(b) of the Florida Administrative Code, which incorporates by reference rule 40D-1.907 of the Florida Administrative Code, the Department of Environmental Protection (Department), hereby makes findings of fact and conclusions of law, and enters this Fourth Amended Immediate Final Order as follows: FINDINGS OF FACT 1. Phosphate Fertilizer Manufacturing Facilities ("Facilities") are responsible for phosphogypsum stack systems (Systems) whose operation or closure is permitted under a Department Wastewater Facility Permit. The phosphogypsum stack systems consist of the phosphogypsum stack.(s), together with all pumps, piping, ditches, drainage conveyances, water control structures, collection pools, cooling ponds, surge ponds and any other collection or conveyance system associated with the transport of phosphogypsum from the fertilizer manufacturing plant to the phosphogypsum stack, its management at the stack, and the process wastewater return to the phosphoric acid production or other process. The Systems hold process wastewater before the wastewater is treated and released to various surface water bodies in this state. The Facilities are required to have process wastewater containment systems designed pursuant to 40 CFR 41.8 to contain the run-off from the 25-year/24-hour storm event, which is approximately 8.5 inches of rain in Polk County. 2. Due to heavy, cumulative rainfall amounts in the second half of 2004, including the rainfall associated with Hurricanes Charley, Frances, and Jeanne, some Facilities are no longer capable of containing the run-off from a 25-year/24-hour storm. As a result, water levels in their containment systems now exceed the "must treat" level specified in 40 CFR 418 and Chapter 62-672 of the Florida Administrative Code. On September 10, 2004, the Department entered an Immediate :Final Order, OGC No. 04-1590. This order was subsequently amended on November 2, 2004, January 10, 2005 and February 10, 2005, and will expire at 11:59 pm, March 10, 2005, unless otherwise amended or extended. 3. Review of the hydrological reports prepared by the Southwest Florida Water Management District (District) indicates that in January 2005, the District's Central region received an average of 1.14 inches of rain, which was classified as drier than normal for the month of January. However, preliminary information, including precipitation data collected by the United States Geologic Survey for the Bartow and Fort Meade vicinities of the Peace River, indicates that rainfall for February will exceed the monthly mean which is 2.96 inches across the District's Central region. The cumulative rainfall during the 12-month period through January 31, 2004 for the Central Region averaged 65.44 inches. This cumulative annual rainfall amount was 12.75 inches above the yearly normal of 52.69 inches. This rainfall average is equivalent to the 92th percentile of historical cumulative rainfall readings for the annual period and is classified as "very wet." 4. The Facilities have utilized the provisions of this Order to maximize discharge of treated process water and reduce process water inventory. However, five of the thirteen phosphate chemical plants in Central Florida remain in "must treat" status as of March 7, 2005. A sixth facility, U. S. Agri-Chemicals Corporation at Fort Meade, is also in "must treat" status as of March 7, 2005, after experiencing localized heavy rainfall of 5.8 inches during the two-day period preceding February 28, 2005. 5. Despite near normal rainfall during the most recent months of November 2004, through January 2005, the cumulative rainfall amounts during the recent 12-month period, including localized heavy rainfall during February, have resulted in continued unacceptably high process water levels at these facilities. 6. Representatives of Mosaic Fertilizer, LLC and Mosaic Phosphates, MP, Inc. (Mosaic), and U.S. Agri-Chemicals Corporation (USAC) have provided updates on their efforts to reduce process water levels at their facilities. On February 28, and March 7, 2005, representatives of USAC and Mosaic, respectively, requested authorization to resume or continue discharges under this order from the three facilities listed below in order to further reduce process water :inventories to below must treat levels. These facilities are identified as: •FL0001589, Mosaic Bartow located at 3200 Highway 60 West, Bartow, Florida •FL0000752, Mosaic Green Bay located at 4390 CR 640 West, Bartow, Florida •FL0001902, USAC Fort Meade located at 3225 State Road 630, Fort Meade, Florida 7. The Department has determined that the current water levels and the condition of the dikes and berms, due to heavy rainfall events at the three facilities identified in Paragraph 6, create an imminent threat of a catastrophic release of untreated process wastewater if immediate action is not taken to reduce the amount of wastewater being stored. A catastrophic release of process wastewater from any of the systems at these Facilities could result in personal injury or severe property and environmental damage. 8. Daily stream discharge values provided by the U.S. Geological Survey (USGS) for the North Prong of the Alafia River and the Peace River were reviewed at the following locations: • The North Prong of the Alafia River at Keysville Road (USGS 02301000) • The Peace River at Fort Meade (USGS 02294898) Review of stream discharge values in the North Prong of the Alafia River indicates that streamflow has remained near the long-term median values during the early and mid parts of February followed by increased flows in response to regional rainfall at the end of February. As of March 6, 2005, the mean daily discharge was 120 fl3/s, which is just above the historical median daily streamflow reported based on the long-term record for this location in the Alafia River. Review of stream discharge values in the Peace River at Fort Meade indicates streamflow was above the long-term median values during the early part of February; however, streamflow decreased to levels below the long-term median value for approximately a three day period immediately prior to the rainfall on February 27. As of March 6, 2005, the mean daily discharge was 755 ft3/s, which is greater than the 20% exceedance historical daily streamflow reported based on the long-term record for the Peace River at this location. 9. The Department is entering this Fourth Amended Immediate Final Order to protect human health and safety and to protect the environment from a catastrophic failure of the containment systems at the Facilities specified below. CONCLUSIONS OF LAW 10. The Department is empowered to administer and enforce chapters 373 and 403 of the Florida Statutes and the rules adopted thereunder. 11. Under section 120.569(2)(n) of the Florida Statutes, the Department is authorized to issue emergency orders when it determines that an immediate danger to the public health, safety, or welfare requires an immediate final order. In addition, subsection 373.119(2) of the Florida Statutes directly authorizes a water management district, when it finds that an emergency exists, to issue an order, without prior notice, reciting the existence of such an emergency and requiring that such action be taken as the Executive Director deems necessary to meet the emergency. Subsection 373.026(7) gives the Department the authority to exercise any power under chapter 373 of the Florida Statutes that may be exercised by a water management district. Under rule 62-330.200 (3) (b) of the Florida Administrative Code, the Department has adopted, by reference, rule 40D-1.907 that authorizes the issuance of emergency orders under these conditions. Therefore, the Department has the authority to issue this immediate final order. ORDER 12. This Order applies only to those three Facilities that are identified in Paragraph 6 and which have water levels exceeding the "must treat" level as specified in Chapter 62-672 of the Florida Administrative Code on the effective date of this Fourth Amended Immediate Final Order. All references to "Facilities" hereafter are intended to apply only to these Facilities. 13. Each Facility is hereby authorized to take immediate action as necessary to continue the process of stabilizing all system dikes and berms to prevent a catastrophic release of untreated wastewater, and to continue to treat and release wastewater from the System so as to reduce the amount of wastewater below the "must treat" levels specified in rule. All effective period of this Fourth Amended Immediate Final Order. BAT discharges authorized under this Fourth Amended Immediate Final Order are from the Mosaic Green Bay facility to the Alafia River watershed, and from the Mosaic Bartow facility (including any water transferred from the Mulberry facility, FL0000671) and the USAC Fort Meade facility to the Peace River Watershed. Discharges to surface water, other than those specifically authorized by this paragraph, may continue where in compliance with each wastewater facility's authorizing permit. 14. During the effective period of this Fourth Amended Immediate Final Order, Mosaic shall continue weekly monitoring for Outfalls 003 and 004 located at Mosaic Phosphates MP, Inc. Noralyn Mine (FL0000230): • Outfall 003, discharges to Six Mile Creek, then to the Peace River • Outfall 004, discharges to Barber Branch, then to the Peace River. For the purposes of this Fourth Amended Immediate Order, discharges to the Peace River through Outfalls 003 and 004, as described above and authorized under Paragraph 13, include upstream discharges of treated process water from the Bartow facility identified in Paragraph 6 above. 15. During the effective period of this Fourth Amended Immediate Final Order, Mosaic shall continue weekly monitoring for BAT discharges under this Order from the Mosaic Green Bay facility (FL0000752). 16. During the effective period of this Fourth Amended Immediate Final • Peace River Upstream location, Peace River at Bartow (Highway 60 crossing) at or near Latitude N 27° 54'8.5", Longitude W 81' 49'3.4" Order, Mosaic shall continue weekly monitoring for surface water samples for the locations described below: Peace River Downstream location, Peace River at Fort Meade (Highway 98 crossing) at or near Latitude N 27° 45' 6.1", Longitude W 81° 46' 54.8" 17. Alafia River Downstream, Alafia River at Bell Shoals Road at or near N 27°period 51' 26.4", Longitude W 82° 16'Immediate 9.2" DuringLatitude the effective of this Fourth Amended Final Order, companies that are authorized and which discharge to the Alafia River under this Immediate Final Order shall monitor and record daily stream discharge values at 3:00 p.m., and historical 20 percent exceedance daily streamflow values, for the day prior to the discharge, in the North Prong of the Alafia River as reported by the U.S. Geological Survey (USGS) at Keysville Road (USGS 02301000). 18. During the effective period of this Fourth Amended Tmmediate Final Order, companies that are authorized and which discharge to the Peace River under this Immediate Final Order shall monitor and record daily stream discharge values at 3:00 p.m., and historical 20 percent exceedance daily streamflow values, for the day prior to the discharge, in the Peace River as reported by the U.S. Geological Survey (USGS) at Fort Meade (USGS 02294898). 19. The weekly monitoring required under Paragraphs 14, 15, and 16 shall continue or, where new, commence within 7 calendar days of the effective date of this Fourth Amended Immediate Final Order. Such monitoring shall be performed for the following parameters: arsenic, total phosphorus, orthophosphate, nitrate/nitrite, TKN, total ammonia as N, fluoride, specific conductance, pH, and temperature. The results shall be transmitted to the Department's Phosphate Management Office of the Bureau of Mine Reclamation upon receipt by Mosaic. Monitoring data that is generated in accordance with paragraphs 14, 15 and 16 above, shall be submitted as a separate report, independent of the reporting requirements per the Noralyn Mine permit (FL0000230). 20. Any Facility that discharges wastewater in accordance with Paragraph 13 above shall be required to meet the effluent limits set forth in its permit at such time as the water levels with the system fall below the "must treat" level, or this Order expires, whichever is earlier. All such Facilities shall provide daily written or oral reports to the Phosphate Management Office of the Department on the progress of compliance with this emergency order. The reports must include the most recent water levels and storage capacities, rainfall, the amount of treated wastewater discharged, and any measures taken to stabilize the dikes and berms of the system. 21. Discharges under this Fourth Amended Immediate Final Order shall cease upon notification from the Department. Furthermore, discharges of treated process wastewater to the Alafia River, in accordance with Paragraph 13 above, shall cease if monitoring results indicate that concentrations of nitrate from samples collected from the Alafia River at Bell Shoals Road are 4 mg/L or greater. Discharges under this order may resume following Department approval of results showing that nitrate levels have fallen below 4 mg/L. 22. Discharges of treated process wastewater to the Alafia River, pursuant to Paragraph 13 above, are not authorized during any calendar day where the streamflow discharge, at 3:00 pm on the preceding day, is less than the historical 20 percent exceedance streamflow value on that preceding day, as reported by the USGS for the North Prong of the Alafia River at Keysville Road (USGS 02301000). 23. Discharges of treated process wastewater to the Peace River, pursuant to Paragraph 13 above, are not authorized during any calendar day where the streamflow discharge, at 3:00 pm on the preceding day, is less than the historical 20 percent exceedance streamflow value on that preceding; day, as reported by the USGS for the Peace River at Fort Meade (USGS 02294898). 24. Facilities authorized to discharge treated process wastewater in accordance with Paragraph 13 above shall continue to submit a weekly report on the status of implementation of its Action Plan, previously submitted to the Department under the First Amended Immediate Final Order, which includes the following information: a) A summary of all activities performed thus far to minimize process water inventory; b) The projected storage gain associated with each activity and the actual storage gained at the end of each reporting period; c) Remaining storage volume to reach each "level" at the end of each reporting period; d) Updated water balance for the Facility; and, e) The status of its contingency preparedness plan for emergency management of process water to minimize harm to human health and the environment. 25. This Fourth Amended Immediate Final Order shall take effect at 11:59 pm, March 10, 2005, and shall expire at 11:59 pm, April 14, 2005, unless modified or extended by further order. NOTICE OF RIGHTS Any person substantially affected by this order has the right to seek judicial review of it under section 120.68 of -the Florida Statutes, by filing a notice of appeal under rules 9.110 and 9.190 of the Florida Rules of Appellate Procedure, with the Clerk of the Department in the Office of General Counsel, Mail Station 35, 3900 Commonwealth Boulevard, Tallahassee, Florida 32399-3000, and by filing a copy of the notice of appeal accompanied by the applicable STATE OF FLORIDA DEPARTMENT OF ENVIRONMENTAL PROTECTION ALLAN BEDWELL Deputy Secretary for Regulatory Programs 3900 Commonwealth Boulevard Tallahassee, Florida 32399-3000 FILED ON THIS DATE PURSUANT TO § 120.52, FLORIDA STATUTES, WITH THE DESIGNATED DEPARTMENT CLERK, RECEIPT OF WHICH IS HE ACKNO EDGED. 3-9-05 DATE