Notes Name: Atomic Structure ATOM ELEMENT An ________________ is the smallest, complete part of an ________________that retains all of the properties and characteristics of the element (like ionization energy, reactivity, and electronegativity.) At atom is NUCLEUS neutral, meaning it has no charge. There are two parts of an atom, the _______________________ and the ELECTRON CLOUD All of the mass of the atom is in the ____________________ NUCLEUS ____________________. while all of the space of ELECTRON CLOUD the atom is in the _________________________. The atom is made up of 3 things: Finding # of protons, neutrons, and electrons Protons: ____charge, + mass =____, 1 are in To find the: the nucleus. Protons = Atomic # # protons: Look at the atomic number 1 Neutrons: NO ____ charge, mass =____, in the # neutrons: Subtract the two numbers from nucleus. Neutrons are the peacekeepers of periodic table the nucleus. # electrons: Electrons: ____charge, mass =____, 0 are in same as # protons. For a neutral element it is the the electron cloud. Atomic Mass Unit (AMU): is the definition for what the mass of an atom is. AMU gives meaning to what 1 means in the periodic table. 1 AMU is the mass of Carbon-12 divided by 12 Ex: complete the table for the elements below: Atom Mass # Atomic # Protons + Look in the How do you periodic table calculate/find Neutrons this? 59 27 Cobalt-59 Sulfur-32 32 Date: _________________________ 16 # Protons Same as atomic # # Neutrons Mass – protons # Electrons Same as protons in neutral atom 27 32 27 16 16 16 Page # ______ Notes Name: Ionic Structure CHARGED ATOM An ion is a __________________________. Atoms will give up or loose electrons in order to have a stable electron configuration like the noble gases. CATIONS + charged atoms are called ________________ ANIONS - charged atoms are called _____________ To find the number of electrons for a + CATIONS element (________________) you To find the number of electrons for a – ANIONS element (________________) you ADD SUBTRACT the charge from # protons. the charge to the # protons ex: Ca+1 = 20 -1 = 19 electrons Ex: F-1 = 9+1 = 10 electrons Notes Name: Atomic History ___________________: all matter is made up of atoms DEMOCRITUS DALTON ___________________: tiny solid ball theory, 3 Laws: The Law of Conservation of Mass _______________________________________________________ THOMSON ___________________: used cathode rays to discover the electron, Plum Pudding Model ___________________: discovered the nucleus & protons, Planetary Model RUTHERFORD Rutherford’s Gold Foil Experiment: The atom has a small nucleus that has all the mass and a large empty electron cloud around it. BOHR ___________________: Energy Level Model ELECTRON CLOUD current model, electrons orbit the nucleus is set pathways called orbitals. ___________________: THEORY Notes Name: Periodic Table Basics The periodic table is made of groups (columns) and periods (rows). Elements in the same group have the same: # valence e-, have same # of dots on a Lewis dot structure, have similar chemical properties ATOMIC NUMBER The periodic table is organized by increasing ___________________________. Types of atoms: DUCTILE Metals: Groups 1-3 including the transition metals and lanthanides/ actinides. Are ________________, malleable, will always give up an electron for a + charge Non-Metals: Groups 4-7, exist as gases at room temperature, always ________________ an electron to TAKE get a – charge STAIRS Metalloids/Semi-Metals: Elements on the ________________. Have properties of both metals and non-metals Date: _________________________ Page # ______ Notes Name: Valence Electrons & Noble Gas Configurations Periodic law states: ELEMENTS ARE ARRANGED ACCORDING TO INCREASING _________________________________ ATOMIC NUMBER A valence electron is: THE OUTERMOST S AND P ELECTRONS. YOU CAN HAVE A MAXIMUM OF 8 VALENCE a. Germanium:_1s22s22p63s23p64s23d104p2____________________________________________ ELECTRONS What are the configurations for: b. Chlorine: __1s22s22p63s23p 5__(shown above in bubble diagram) Group Group 1: Group 2: Group 3: Group 4: Group 5: Group 6: Group 7: Group 8: Name Alkali Metals Alkaline Earth Metal Boron Group Carbon Group Nitrogen Group Oxygen Group, Halogens Noble gases Date: _________________________ Charge +1 +2 +3 +4 or -4 -3 -2 -1 no charge e config s1 s2 2 1 sp s2 p 2 s2 p 3 s2 p 4 s2 p 5 s2 p 6 Valence e-/ dots 1 2 3 4 5 6 7 8 # e- available to bond 1 2 3 4 3 2 1 0 Page # ______ Notes Name: Periodic Trends Ionization Energy: FLOURINE has the highest KEEP The ability to ________________ electrons. ________________ FRANCIUM ionization energy and therefore will not give away any electrons. ________________ has the lowest ionization energy and will therefore give up an electron to any element. DOWN LEFT a. Ionization Energy decreases as you travel ________________ and to the ______________ IF THEY LOSE 1 ELECTRON THEY HAVE b. Why are the alkali metals so reactive? ________________________________________________ NOBLE GAS CONFIGURATION Electronegativity: TAKE FLOURINE The ability to ________________ electrons. ________________ has the highest electronegativity and will therefore take electrons from any element (other than noble gases). ________________ FRANCIUM has the lowest electronegativity and therefore cannot take an electron from any element. DOWN LEFT a. Electronegativity decreases as you travel ________________ and to the ______________ b. Why are the halogens so reactive? Atomic Size/Radii: IF THEY TAKE 1 ELECTRON THEY HAVE ________________________________________________ NOBLE GAS CONFIGURATION FRANCIUM How big the atom is. ________________ has the largest atomic size and radius. As you AS YOU ADD MORE ELECTRONS travel towards the noble gases, atomic radii gets smaller because_______________________________. THEY GET PULLED CLOSER TO THE ATTRACTIVE NUCLEUS UP RIGHT a. Atomic size/radii decreases as you travel ________________ and to the ______________ Notes Name: Spectra When you put metals in a flame, the flame will glow a specific color, depending on the metal. Excited valence electrons will jump out of their orbital and into a higher energy orbital. When they calm down PHOTON and go back to where they belong, they release a ________________ which is a ray of light. If you look at the emission spectra of an element, it will show you the photons of light the atoms give off. The EMISSION SPECTRA __________________________ is like a fingerprint of the element. Date: _________________________ Page # ______ Standard 11 Nuclear Chemistry Notes Date Chemical Reactions vs. Nuclear Reactions Chemical reactions: Nuclear reaction: happen because of changes in _number of happen because of changes in the nucleus electrons (either the protons or neutrons) Stable atoms go through chemical reactions __Unstable___________ atoms go through Small amounts of energy released (think of the nuclear reactions until they becomes stable heater in the classroom) 99% of chemistry involves chemical reactions Follow the Law of Conservation of Mass and Energy, which states you must have the again same number of the same atoms on BOTH sides of the equation 2KClO3 → 2KCl + 3O2 K, Cl, and O on BOTH sides LARGE amounts of energy released (think of the sun or a nuclear bomb) The 1% exception to the rule Partially follows the Law of Conservation of Mass and Energy, you must make sure that the mass on both sides of the reaction are the same. Violates the energy part! 40 40 0 19 20 1 K Ca Isotopes Isotopes are the same element, but they have a different number of ___neutrons__________. Isotopes will always have the _____same________ number of protons. Ex: All isotopes of Carbon will have the same number of: a. neutrons b. electrons c. protons Stability Graphs Not all isotopes of an element are radioactive. To be radioactive, the isotope must be unstable. To be radioactive, the atom must have either too many neutrons or not enough neutrons. There are 2 ways to determine if an isotope is unstable: 1. Use a stability curve: a. This is the most _____accurate________way to determine if an isotope if radioactive. For your element, plot the # neutrons against the # of protons. b. If element is ___on__________ the curved band of stability, then it is stable. c. If the element is ___above__________ or ___below__________ the band, then it is unstable and radioactive. Ex: is the isotope Cobalt-111 stable? ____no_______ 2. Calculate the # neutrons : # protons ratio. You should do this __calculation___________ if you are not provided with a stability graph. (Study tip: Neutrons come before Protons because N is before P) a. For elements #1-20: If the #neutrons : #protons is 1:1 the isotope is stable. b. For elements #21-82: If the #neutrons : # protons is 1:1½ , then the isotope is stable. c. For elements # 83 and above: the isotope is always unstable and radioactive. Date: _________________________ Page # ______ Radiation & Nuclear Reactions __Radiation___________ is the matter and energy emitted from the nucleus of an unstable isotope. (Think of it as the crazy cat lady throwing her cats out!) There are 3 types of nuclear reactions: Type Alpha Symbol 4 2 He Beta 0 1 gamma or 0 0 0 1 Blocked By Paper e Aluminum foil Heavy lead, concrete Isotopes will continue to go through nuclear decay until they reach a _____________ isotope. For each reaction below, determine if is an alpha, beta, or gamma reaction. a. b. 14 14 0 233 229 6 7 1 93 91 Np* Pa 24He 00 C N B c. 210 84 4 Po206 Pb 82 2 He For each reaction below, determine what the missing isotope is: a. 40 19 K Ca 40 20 264 c. 84 Po 0 β -1 b. U Ca 238 92 40 20 0 0 198 72 Hf 4 260 Ca 82 2 He Date: _________________________ Page # ______ Balancing Reactions Notes According to the Law of Conservation of Mass and Energy, matter and energy cannot be created or destroyed. We must account for this fact when we are writing equations. # Atoms of Each element & Energy → # Atoms of Each element & Energy To balance chemical reactions: 1. Calculate the number of each atom on both sides of the reaction by multiplying the coefficient by the subscript for each element. a. If the same polyatomic appears in both the reactants and the products, you may balance the polyatomic as one item. If the polyatomic breaks up, you have to balance each element separately. 2. You may use coefficients to balance the reactions. Coefficients go in front of the formula and multiply each atom in the formula. You cannot change any subscripts. You cannot change, add, or subtract anything from the reactions to balance them. Ex: 4 KNO3 How many K? ____4_______ N?_____4_______ O?________12_______ 3. When you think that you have balanced the reaction, look at the coefficients. If all of the coefficients can be reduced, then do so. Helpful hint: If something does not balance, odd numbers will never work. Try multiplying the odd number by 2 to make it even! Examples: ___2__NH4OH(s) + _____LiS(s) → _____Li(OH)2 (s) + _____ (NH4)2S (s) ___2__ZnS + __3___O2 →___2__ ZnO +___2__ SO2 Molecular Mass Notes In the beginning of the year, we used the periodic table to determine the atomic mass. To review, find the atomic masses for the following: a. H ____1.01_______ b. Cu ___63.55________ c. F _____19______ d. Cl ___35.45_____ Molecular mass is the mass of a molecule. To find the molecular mass, you add up the atomic masses for every atom in a molecule. In our class, we will only use whole numbers (no decimals!!) 1. Write the formula. 2. Substitute the atomic mass for the atomic symbol. When you move from symbol to symbol, ADD the masses. 3. Use the order of operations to solve. (PEMDAS) Ex1: What is the molecular mass of NaCN? 49.01g/mol Ex2: What is the molecular mass of F2O? 35g/mol Ex3: What is the molar mass of Sr(OH)2? 121.64g/mol Ex4: What is the molar mass of Ga2(CO3)2 189.7 g/mol Mole Maps Date: _________________________ Page # ______ For a chemist, the mole is the universal translator, meaning that we can translate from one unit to another, if we first use moles. When a mole problem does not have moles in it, you must first convert to moles, then convert to what the problem tells you to. Conversion factors: 1 mole = 6.02 x 1023 atoms/molecules 1 mole = 22.4 L 1 mole = molecular mass grams FOR THE REMAINDER OF STOICHIOMETRY, PLEASE REVIEW THE PRACTICE PROBLEMS I HAVE ATTACHED. FOR MORE STOICHIOMETRY PRACTICE, PLEASE REFER TO THE EXAM 5 TAB ON MY TEACHER SITE. Page # 8