Name_______________________ Chem 111 Quiz Chapt 5 Winter, 2004 Potentially useful information: Show all work, including any unit conversions for full credit. Use correct number of sig figs. 1. Give oxidation numbers for each and every atom in all of the following molecules: HNO3 H +1, O -2, N +5 C2H2 H +1, C -1 MnO4- O -2, Mn +7 2. Balance the following reactions. 1 Ag2S (s) + 2 HCl (aq) 1 BaCl2(aq) + 1 Na2CO3(aq) 6 CO2 (g) + 6 H2O (l) 2 HCl (aq) + 1 CaCO3 (s) 2 AgCl (s) + 1 H2S (g) 1 BaCO3 (s) + 2 NaCl (aq) 1 C6H12O6 (s) + 6 O2 (g) 1 CaCl2 (aq) +1 CO2 (g) + 1 H2O (l) 3. In the following redox reaction: CuSO4 (aq) + Zn (s) Cu (s) + reactant ox. #: Cu +2, S +6, O -2, Zn 0 ZnSO4 (aq) product ox. #: Cu 0, Zn +2, S +6, O -2 What is being oxidized? What is reduced? What is the oxidizing agent? Explain your answers. copper goes from +2 to 0 → it is reduced, therefore it is oxidizing agent zinc goes from 0 to +2 → it is oxidized, therefore it is reducing agent 4. Examine the following reaction (the burning of an acetylene torch). 2 C2H2 (g) + 5 O2 (g) 4 CO2 (g) + 2 H2O (g) If one burns 65.0 g of acetylene (C2H2) in the presence of 192 g of diatomic oxygen, which reactant is in excess? g acetylene → moles acetylene → moles oxygen →g oxygen 65.0 g x 1 mole/24.04 g x 5 oxygen/2 acetylene x 32.00 g/ mole = 216 g oxygen oxygen is limiting reagent since we only have 192 g so acetylene is in excess Which reactant is the limiting reagent? oxygen is limiting reagent How many moles of CO2 are produced (theoretical yield)? 192 g oxygen x 1 mole/32.00g x 4 CO2/ 5 O2 x 44.01 g/mole = 211 g CO2 How many grams of H2O are produced (theoretical yield)? 192 g oxygen x 1 mole/32.00g x 2 H2O/ 5 O2 x 18.02 g/mole = 43.2 g H2O