Metamorphic rocks are the second of the three major rock-type groupings. As described in the discussion of igneous rocks, the most general classification system is based upon processes of rock formation. In this case, the word metamorphic describes the process responsible for the origin of these rocks – meta means change, while morph means shape. Thus, metamorphic rocks are those who’s shape has been changed by geologic processes. The question remains, however, what is the “shape” that is changed by metamorphism? In order to understand the types of changes that occur during metamorphism, it is necessary to recall the two criteria by which all rocks are classified within three broad process-based groupings. The two classifying criteria are mineral (or chemical) composition and the texture of the crystals or mineral grains within the rock. Changes that occur during metamorphism are driven by changes in the physical parameters temperature and pressure. Thus, as temperature and pressure conditions change, alterations in mineral composition and texture ensue. Importantly, these are changes that occur below the melting point of the rock. Thus, all metamorphic reactions involve solid-state transformations of minerals. The role of Temperature Changes in temperature conditions during metamorphism causes several important processes to occur - first, temperature is a measure of energy. With increasing temperature, and thus higher energy, chemical bonds are able to break and reform. Thus, the breaking and making of crystal bonds drive the chemical reactions that change a rock's chemistry during metamorphism. Secondly, increasing temperature results in the growth of crystals. Within a rock, a small number of large crystals have a higher thermodynamic stability than do a large number of small crystals. As a result, increasing temperature during metamorphism, even in the absence of any chemical change, will generally result in the amalgamation of small crystals to produce a coarser grained rock. Thirdly, individual minerals are only stable over specific temperature ranges. Thus, as temperature changes, minerals within a rock become unstable and transform through chemical reactions to new minerals. This property is very important to our interpretation of metamorphic rocks. By observing the mineral assemblage (set of minerals) within a metamorphic rock, it is often possible to make an estimate of the temperature at the time of formation. That is, minerals can be used as thermometers of the process of metamorphism. Finally, increasing temperature tends to cause chemical reactions to occur at a faster rate such that those reactions that are chemically favorable will occur with greater speed during metamorphism. The Role of Pressure Pressure, the second of the two physical parameters controlling metamorphism, occurs in two forms. The most widely experienced type of pressure is lithostatic. This “rock-constant” pressure is derived from the weight of overlying rocks. Lithostatic pressure is experienced uniformly by a metamorphic rock. That is, the rock is squeezed to the same degree in all directions. Thus, there is no preferred orientation to lithostatic pressure and there is no mechanical drive to rearrange crystals within a metamorphic rock experiencing lithostatic conditions. Conversely, directed pressure, the second type of pressure associated with metamorphism, is the pressure of motion and action. Plate tectonics provide the underlying mechanical control for all forms of directed pressure. Thus, metamorphism is closely linked to the plate tectonic cycle and many metamorphic rocks are the products of tectonic interactions. As was the case with changes in temperature, changes in pressure, either lithostatic or directed, have important impacts upon the stability of minerals. Every mineral is stable over a range of pressures, if pressure conditions during metamorphism exceed a mineral’s stability range the mineral will transform to a new phase. Many of these solid-state reactions involve polymorphic transformation – changes between minerals with the same chemistry and different crystallographic structures. Just as with temperature, mineral assemblages within a metamorphic rock can be used as a barometer to measure pressure at the time of formation. Additionally, the application of directed pressure to a metamorphic rock results in the alignment of grains. Such alignment will occur when mineral grains are either elongate or platy in form. As we will learn, this alignment is responsible for producing the textures observed in a large group of metamorphic rocks. Metamorphic Grade Geologists describe the intensity of a metamorphic event through the use of the concept of metamorphic grade. With increasing depth in the Earth, ambient temperature and pressure conditions rise steadily. Thus, within the continental crust, temperatures vary from approximately 200 °C at 5 kilometers to 800 °C at 35 kilometers. While these temperatures are extreme relative to our everyday experiences, they are significantly below the melting point of most rocks. Likewise, lithostatic pressure increases with increasing depth. At 5 kilometers the pressure is approximately 2 kilobarrs, or about 2000 times atmospheric pressure. Deeper within the crust, at about 35 kilometers, the pressure increases to some 10 kb. This trend of increasing temperature and pressure within the Earth is defined by a region of commonly encountered metamorphic conditions. Geologists describe low temperature and pressure setting as low-grade metamorphism, while high temperature and intense pressure is known as highgrade metamorphism. This characteristic of varying intensity of physical conditions results in the production of a variety of metamorphic rocks. Textures of Metamorphic Rocks As was the case with igneous rocks, the primary parameter of classification among the metamorphic rocks is texture. Textures exhibited by metamorphic rocks are broadly defined as either foliated or non-foliated. Those rocks described to possess a foliated texture are formed from aligned mineral grains. Such alignment of elongated or platy grains will only occur under the influence of directed pressure. Thus, foliated metamorphic rocks are the product of the interaction of lithospheric plates and as such compose a significant part of the Earth’s major mountain chains. Non-foliated metamorphic rocks are formed from mineral grains lacking any particular alignment. Such random arrangement of minerals occurs during metamorphism in two ways. First, when rocks are exposed to elevated temperatures – in the absence of any directed forces – mineral grains are free to grow with any orientation. Thus, non-foliated rocks are always produced by lithostatic pressure. However, non-foliated rocks can also form in another way. If the precursor rock consists of equant sized grains – grains with shapes that have similar lengths, widths, and heights – then the application of directed force fails to produce any preferential orientation. Thus, rocks containing largely spherical or cubical shaped grains will not produce a foliated texture, no matter the intensity of the directed pressure. This is a critical difference. Foliated metamorphic rocks only form under conditions of directed pressure. Lithostatic pressure will only produce non-foliated metamorphic rocks. However, non- foliated metamorphic rocks can also form under conditions of directed pressure, when the precursor grains are equant in shape. Foliated Metamorphic Rocks Temperature and pressure are the two controlling physical parameters responsible for altering the texture and composition of a metamorphic rock. However, there is a third critical factor that determines a rock’s lithologic characteristics – the texture and composition of the precursor rock. All metamorphic rocks are formed from some preexisting rock – either sedimentary, metamorphic, or igneous. As such, the physical and chemical characteristics of the original rock have a profound influence upon the nature of the rock after metamorphism. The largest and most important groupings of metamorphic rocks are those displaying a foliated texture. Formed under conditions of directed stress, foliated metamorphic rocks exhibit four distinct types of aligned textures. At the lowest metamorphic grade is the foliated metamorphic rock slate. Slate generally forms by the realignment of clay minerals in the precursor rock shale at low temperatures and pressures. Slate is denser, and more resistant to erosion, than is shale. Additionally, the alignment of the clay crystals causes the rock to break along extremely flat and smooth surfaces – a property described as rock cleavage. In order of increasing metamorphic grade, the second rock type is phyllite. These chlorite-rich foliated rocks are commonly dark green in color, with a slight sheen or luster due to the cleavages of the sheet silicate mineral cholorite. One of the most abundant and important foliated metamorphic rocks is schist. Schist consists predominantly of micas but also commonly contains several important accessory minerals useful as thermometers and barometers of metamorphic conditions. Finally, at highest metamorphic grade is the rock gneiss. This foliated rock consists of alternating bands of quartz, feldspar, and micas. There are two important trends within these foliated metamorphic rocks. With increasing metamorphic grade the intensity of the foliation increases. Likewise, at higher grade, the rocks are typically coarser grained. Non-foliated Metamorphic Rocks As previously described, non-foliated metamorphic rocks can form either under conditions of lithostatic or directed stress. Perhaps even more than any other type of metamorphic rock, the non-foliated rocks are highly dependent upon the composition of their precursor. The most well known of all metamorphic rocks is marble. This commonly used architectural and decorative stone is composed of the carbonate minerals calcite or dolomite. In either case, marble’s precursor rock is limestone, a common type of sedimentary rock. The equant shape of the carbonate crystal structure results in a homogeneous (non-foliated) texture even under conditions of directed stress. Similarly, the rock type quartzite is formed from the sedimentary rock sandstone. In this case, the quartz sand grains are nearly spherical in shape and as such, produce a dense, hard, non-foliated metamorphic rock. The third common and important type of non-foliated metamorphic rock is formed only during the metamorphism of shale under conditions of lithostatic pressure. The product of metamorphism under these conditions is a dense, brittle rock known as hornfels. This rock is generally similar in appearance and analogous in origin to pottery or porcelain created by the firing of clay. Types of Metamorphism Processes of metamorphism – changes in temperature and pressure – occur in a variety of geologic settings. There are two major processes, and a several important, but less common secondary processes. The most important largescale metamorphic process is known as regional metamorphism. First described and studied in northern Scotland, this form of metamorphism is the product of directed pressures generated during convergent tectonics. Commonly exhibiting regionally extensive bands of foliated metamorphic rock of varying grade, regional metamorphic terrains form the cores of major mountain chains. The second major process is known as contact metamorphism. Generally constrained to small geographic areas, this form of metamorphism occurs under conditions of elevated temperature and lithostatic pressure. The emplacement of intrusive igneous rock bodies (batholiths or stocks) results in the formation of a strong temperature gradient between the molten magma and the surrounding country rock. As heat is conducted from the magma chamber to the rocks in contact with the magma, chemical reactions occur. Contact metamorphism is characterized by concentric zones displaying high metamorphic grade close to the magma chamber. As is the case with all metamorphism under conditions of lithostatic pressure, contact metamorphism only results in the creation of non-foliated metamorphic rocks. There are three other significant, yet less common, forms of metamorphism, each with its own unique set of characteristics. Cataclastic metamorphism occurs along fault planes when rocks grind against each other. This is the only type of metamorphism that results in a reduction of grain size. Faults are regions of high fluid flow, and the fine grain sizes produced by grinding along the fault during cataclastic metamorphism allows for the chemical alteration of the rock. Perhaps the most pervasive of the secondary processes is hydrothermal metamorphism. During the emplacement of a magma chamber fluids within the surrounding country rock to begin to circulate. The temperature gradient between the hot batholith and the cold country rock creates a convection cell that moves fluid from colder regions to warmer regions. This circulation of rock, along with the subsequent increase in temperature as it approaches the batholith, causes numerous mineral-water chemical reactions. This process is responsible for the formation of much of the worlds precious metal deposits as well as many economically significant metal sulfide ore deposits. The third minor metamorphic process occurs as sedimentary rocks are slowly buried. Burial metamorphism occurs at relatively low temperature and under lithostatic pressure. Thus, all burial metamorphic transformations are classified as lowgrade and produce non-foliated rocks. Metamorphic Facies One of the most significant concepts to be drawn from the study of metamorphic rocks is the notion of metamorphic facies. A facies (face – ees) is a grouping of metamorphic rocks of various compositions that have formed under the same grade of metamorphism. By evaluating the changes in texture and composition within metamorphic rocks it is possible to delineate regions of high and low metamorphic grade. That is, the geometries of similar metamorphic rocks provide insights to the processes of metamorphism. There are two key points to be drawn from the analysis of metamorphic facies. First, different kinds of metamorphic rocks are formed from different parent rocks at the same grade. Thus, compositional variation in the precursor rocks is inherited by the metamorphic rocks. Second, different kinds of metamorphic rocks are formed from the same precursor at different metamorphic grades. Through the application of the concept of metamorphic facies, the compositions and textures of metamorphic rocks can be utilized to estimate temperature and pressure at the time of metamorphism. Changes in the precursor rock occur as temperatures and pressures increase. Yet, it is important to consider how it is geologists are able to evaluate the maximum conditions of metamorphism. The answer lies in the fact that metamorphic reactions are generally irreversible. Changes in texture and mineralogy generally occur only as the temperature and pressure increases during metamorphism. That is, changes get locked into the rock at the maximum conditions. Occasionally, however, reverse (retrograde) reactions occur during the cooling or depressurization of a metamorphic rock. Geologists study the properties of metamorphic minerals through experimentation. From laboratory studies it is possible to understand the responses of minerals to changes in temperature and pressure during metamorphism. As previously described, minerals are stable over limited ranges of temperature and pressure. When metamorphic conditions exceed those limits, mineral transformations occur. One of the most important forms of mineralogical changes that occurs within rocks is the transformation among mineral polymorphs. Three polymorphs of the alumino-silicate composition Al2SiO5 are commonly used as pressure-temperature indicators within metamorphic rocks. The high pressure – low temperature polymorph of Al2SiO5 is Kyanite, the low pressure phase is Andalusite, while the high temperature polymorph is Sillimanite. Each of these minerals occur naturally over specific ranges of temperature and pressure. The boundaries between the mineral stability fields are pressure-temperature combinations where both adjoining phases are stable. At the center of the phase diagram is a single combination of temperature and pressure where all three polymorphs are stable. This triple junction is never sustained in nature, but is an interesting theoretical aspect of phase relationships within metamorphic rocks.