Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product Name
Product No
Internal Id
Aydos
®
Frost OC
BK.010
(1.19)
Special liquid containing salts
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Standards
Concrete admixture
Antifreeze concrete admixture (easily concrete pouring in cold weather )
Conforms to the requirements of TS EN 934 –2 Tables 6 / ASTM C 494 Type C
Consistent With the Ministry of Public Works Pos. No: 04.613/7
1.3. Details of the supplier of the safety data sheet
Supplier AYDOS YAPI KIMYASALLARISAN. TIC. LTD. STI.
Büyükbakkalköy Çobançesme Mevki Maltepe / Istanbul-TURKEY
TEL: +90 216 6613232
FAX: +90 216 6613107
Contact Person www.aydos.com.tr
Erdal Kara / erdalkara@aydos.com.tr
1.4. Emergency telephone number
AYDOS :+90 216 661 3232 (office hours)
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) C;R35.
2.2. Label elements
Contains Sodium Hydroxide, Formaldehyde
Labelling
Corrosive
Risk Phrases R35 Causes severe burns.
Safety Phrases
S24/25
S26
Avoid contact with skin and eyes.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection. S36/37/39
S45
S60
In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
This material and its container must be disposed of as hazardous waste.
2.3. Other hazards
This product does not contain any PBT or vPvB substances.
1 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
NITRIC ACID 10-25 %
CAS-No.: 1310-73-2 EC No.: 231-714-2
Classification (EC 1272/2008)
Ox. Liq. 3 - H272
Skin Corr. 1A - H314
SODIUM NITRITE
Classification (67/548/EEC)
O;R8
C;R35
< 1 %
CAS-No.: 7632-00-0 EC No.: 231-555-9
Classification (EC 1272/2008)
Ox. Sol. 3 - H272
Acute Tox. 3 - H301
Aquatic Acute 1 - H400
Classification (67/548/EEC)
O;R8
T;R25
N;R50
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown are in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
General information
Remove victim immediately from source of exposure. Chemical burns must be treated by a physician.
Inhalation
Remove victim immediately from source of exposure. Keep the affected person warm and at rest.
Get prompt medical attention.
Ingestion
Never give liquid to an unconscious person. Rinse mouth thoroughly. Get medical attention immediately!
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing.
Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing.
Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation
Upper respiratory irritation.
Ingestion
May cause chemical burns in mouth and throat.
Skin contact
Severe irritation.
2 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
Eye contact
May cause severe irritation to eyes.
4.3. Indication of any immediate medical attention and special treatment needed
No specific treatment. Treat symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing media
Data not available.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
During fire, toxic gases (CO, CO2) are formed.
Unusual Fire & Explosion Hazards
No unusual fire or explosion hazards noted.
Specific hazards
In case of fire, toxic and corrosive gases may be formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Avoid breathing fire vapours. If possible, fight fire from protected position. Dike and collect extinguishing water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin and eyes.
Wear protective gloves and, in case of splashes, goggles/face shield too.
In case of spills, beware of slippery floors and surfaces.
6.2. Environmental precautions
Do not discharge into drains, water courses or onto the ground.
The product should not be dumped in nature but collected and delivered according to agreement with the local authorities.
6.3. Methods and material for containment and cleaning up
DO NOT TOUCH SPILLED MATERIAL! Stop leak if possible without risk.
Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area.
6.4. Reference to other sections
For personal protection, see section 8.
See section 11 for additional information on health hazards.
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Do not handle broken packages without protective equipment.
Read and follow manufacturer's recommendations. Do not eat, drink or smoke when using the product.
Eye wash facilities and emergency shower must be available when handling this product.
Do not puncture the packaging. Contaminated clothing and shoes must be discarded.
Observe good chemical hygiene practices. Container must be kept tightly closed.
3 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
Keep away from food, drink and animal feeding stuffs. Protect from direct sunlight.
Storage Class
Corrosive storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Name Std TWA - 8 hrs STEL - 15 min Notes
NITRIC ACID WEL 2 ppm 5.2 mg/m 3 4 ppm 10 mg/m 3
Ingredient Comments
WEL = Workplace Exposure Limits
8.2. Exposure controls
Protective equipment
Process conditions
Provide eyewash, quick drench.
Engineering measures
Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists.
Hand protection
Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Polyvinyl chloride (PVC). Rubber (natural, latex). Viton rubber (fluor rubber). Chemical resistant gloves required for prolonged or repeated contact.
Eye protection
If risk of splashing, wear safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Wear rubber footwear.
Provide eyewash station and safety shower.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet.
Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated.
Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke.
Skin protection
Wear apron or protective clothing in case of contact.
Environmental Exposure Controls
Please act in accordance with local and national laws.
4 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
99.1. Information on basic physical and chemical properties
Appearance Liquid
Colour
Odour
Solubility
Dark Brown.
Characteristic.
Soluble in water.
Initial boiling point and boiling range
Melting point (°C)
Relative density pH-Value, Conc. Solution
Water Soluble Chloride (%)
Na
2
O- equivalent %
Critical Temperature
Not available.
Not available.
1. 19 kg/l ± 0.02
8 .5 ± 0.02
Max. 0.1
%
Max. 6 %
-15 °C
Vapour pressure
Flash point
Partition Coefficient
Viscosity
Decomposition temperature (°C)
Not available.
Not available.
Not available.
Not available.
(N-Octanol/Water) Not available.
9.2. Other information
No information required.
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use. Stable under the prescribed storage conditions.
10.3. Possibility of hazardous reactions
Not available.
10.4. Conditions to avoid
Avoid exposure to high temperatures or direct sunlight.
10.5. Incompatible materials
Materials To Avoid
None known.
10.6. Hazardous decomposition products
None under normal conditions.
Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
5 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxicological information
Any product-specific data is not recorded.
Inhalation
Harmful by inhalation. May cause damage to mucous membranes in nose, throat, lungs and bronchial system.
Ingestion
Harmful if swallowed. May cause burns in mucous membranes, throat, oesophagus and stomach.
Skin contact
Causes burns. Harmful in contact with skin.
Eye contact
Causes burns.
Toxicological information on ingredients.
NITRIC ACID (CAS: 7697-37-2)
430 mg/kg (human - acute oral) Toxic Dose 1 - LD 50
SODIUM NITRITE (CAS: 7632-00-0)
Toxic Dose 1 - LD 50
Toxic Conc. - LC 50
SECTION 12: ECOLOGICAL INFORMATION
85 mg/kg (oral - rat)
5.5 mg/l/4h (inh.- rat)
Ecotoxicity
Not regarded as dangerous for the environment.
12.1. Toxicity
Ecological information on ingredients.
LC 50, 96 Hrs, Fish
NITRIC ACID (CAS: 7697-37-2)
72 mg/l (Gambusia affinis)
LC 50, 96 Hrs, Fish
EC 50, 48 Hrs, Daphnia
SODIUM NITRITE (CAS: 7632-00-0)
360 mg/l (Leiciscus idus)
IC 50, 72 Hrs, Algae
12.5-100 (method: daphnientest nach EG-Norm)
1230 mg/l/8d (Scenedesmus quadricauda)
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
6 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
Partition coefficient
Not available.
12.4. Mobility in soil
Mobility
The product is miscible with water. May spread in water systems.
12.5. Results of PBT and vPvB assessment
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects
No information required.
SECTION 13: DISPOSAL CONSIDERATIONS
General information
The packaging must be empty (drop-free, when inverted). Do not puncture or incinerate even when empty.
13.1. Waste treatment methods
Empty containers, dispose of waste and residues in accordance with local authority requirements.
Environmental manager must be informed of all major spillages. Do not allow runoff to sewer, waterway or ground.
Please recycle empty pack. Do not re-use empty containers.
SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN)
UN No. (IMDG)
UN No. (ICAO)
14.2. UN proper shipping name
Proper Shipping Name
14.3. Transport hazard class(es)
ADR/RID/ADN Class
ADR/RID/ADN Class
ADR/RID/ADN Subsidiary Risk
ADR Label No.
IMDG Class
IMDG Subsidiary risk
ICAO Class/Division
ICAO Subsidiary risk
Transport Labels
3093
3093
3093
CORROSIVE LIQUID, OXIDIZING, N.O.S. (NITRIC ACID, SODIUM HYDROXIDE)
8
Class 8: Corrosive substances.
5.1
8 & 5.1
8
5.1
8
5.1
7 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
14.4. Packing group
ADR/RID/ADN Packing group
IMDG Packing group
ICAO Packing group
14.5. Environmental hazards
II
II
II
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
EMS
Emergency Action Code
Hazard No. (ADR)
Tunnel Restriction Code
F-A, S-Q
2W
85
(E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No information required.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations.
Statutory Instruments
Export of Dangerous Chemicals Regulations.
Approved Code Of Practice
Safety Data Sheets for Substances and Preparations.
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006 with amendments.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTION 16: OTHER INFORMATION
Information Sources
This SDS is prepared based on the information received from the product owner.
Revision Comments
The SDS is generated in accordance with the REACH regulation.
Issued By
Bülent Özdemir /
CRAD
Çevre Risk Analiz Denetim ve Eğitim Hizm. Ltd.Şti. www.crad.com.tr
----
Tel: 0216 335 4600
Revision Date
Revision Date
Preparation date
05.10.2012
13.10.2012
Revision 1.0
Safety Data Sheet Status Approved.
8 / 9

Revision Date: 06.10.2012
Preparation date: 13.01.2011
Risk Phrases In Full
R35
R8
R25
R50
Hazard Statements In Full
H314
H272
H301
H400
SAFETY DATA SHEET
Aydos
®
Frost OC
(1.19)
Revision: 1.0
Supersedes date: 13.01.2011
According to Regulation (EC) No 1907/2006 and (EU) No 453/2010
Causes severe burns.
Contact with combustible material may cause fire.
Toxic if swallowed.
Very toxic to aquatic organisms.
Causes severe skin burns and eye damage.
May intensify fire; oxidiser.
Toxic if swallowed
Very toxic to aquatic life
H351Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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