Groundwater Issues in the Karst Terrane of Kentucky Gregory Eck Applied Hydrology Karst terrane is a problematic area for groundwater, wellhead and aquifer contamination. Typical karst hazards also include sinkhole flooding and sinkhole formation.1 In Kentucky as elsewhere the country side is being impacted by continued urbanization, as population increases and former rural areas are domesticated.2 Just over 30% of Kentucky drinking water is from groundwater sources.3 Karst terrane is usually identified as having carbonate bedrock such as limestone or dolomite.4 Approximately 55 percent of Kentucky has carbonate karst forming rock, of which 25% is mature karst. A terrane is a landscape or a region that is under laid by similar rocks or sediment to those on surface. Mature karst terrane is identified as land with little or no above ground drainage which typically has exposed outcroppings of carbonate rock, sinkholes, springs and caves. Karst terrane includes integrated groundwater conduits which are joints and fissures in the rock or sediment which have been enlarged due to dissolution of carbonate rocks. Carbonate rocks are dissolved via the interaction of these carbonate rocks with carbon dioxide, the more CO2 the more carbonate reaction. 5 In the karst environments the carbonate rock is continuously changing as the groundwater moves through it. Over time the flow patterns and the rock porosity are also being modified.6 Carbonate rock permeability has three sources: the primary porosity of limestone, the permeability due to the formation of dissolution joints and conduit formation.7 These conduits and solution cavities that rapidly transport groundwater are what make karst aquifers different from others. The conduits result in rapid and turbulent flow.8 Within karst terrane there are two types of recharge, autogenic when precipitation falls directly on a karst region and allogenic when water drains via streams and overland flow into karst aquifers.9 The location of caves or enlarged dissolution openings via sampling is often required to verify that a region includes karst. However, this definition is far too simplified and takes into account only part of the karst terrane definition. One article suggested this was equivalent to someone purchasing a large number of lottery tickets (large sample size) but failing to win concluding that no ‘jackpot” exists.10 The most reliable method requires groundwater tracing to establish where the flow pattern of water in karst areas. The reliable and time tested calculations that provide accurate data in confined aquifers can not be used in the karst terrane.11 Non toxic fluorescent dyes which are highly detectable and low cost of analysis are the most common methods of tracing.12 There are five tests for defining the bounds of groundwater source protection areas distance, drawdown, time of travel, flow boundaries and assimilative capacity. All except flow boundaries which have been established via dye tracing are invalid in karst areas. Karst areas are by definition unconfined or partially unconfined aquifers and do not meet the assumptions of the Darcy equation.13 For example, in a karst area water and contaminants time of travel t over a x distance may be made of traveling through 1% of x made of soil and non-carbonate rock in 99% of t, then encountering a carbonate fissure or stream in a cave and traveling 99% of x in 1% of t.14 The result can be that contaminates could slowly filter through a locally existing matrix taking far longer than the assumed time in a karst area and perhaps well after monitoring is ended, then “rocket” through a conduit under turbulent flow conditions to a groundwater source days, weeks, months after the initial event.15 Conversely, using typical distance tests that work well in non karst areas involving a 300m distance may be traveled in a few hours in a karst area. Drawdown, pumping influence and pumping rate calculations are based on assumptions that are invalid in the unconfined, turbulent flow of a karst terrane conduit. Discharge springs are usually identified are being the result of either conduit flow ie underground streams or diffuse flow ie ground water seepage through the primary permeability of the rock. In karst regions variation in flow and water quality are more readily explainable by examining the recharge area rather than the discharge flow.16 Normalized Base Flow (NBF) is measured by dividing the base flow of a spring by the area of the drainage basin the result is flow measured in cubic feet/second/square mile. Discharge spring NBF can then be used to estimate the size, characteristics and boundaries of a recharge area, as well as study their hydrogeology.17 The Fort Knox Military Reservation is over 100,000 acres in size. Numerous hazardous materials are used and stored throughout the base. As a result there was a need for a through understanding of the groundwater flow patterns and baseline measurement of the groundwater quality. An important goal was the creation of a groundwater monitoring program for the base.18 The groundwater basins at the base were studied using dye injection into monitoring wells, sinkholes and sinking streams.19 The Fort Knox studies used eight different dyes which were collected in automatic water samplers. These tracings were conduced in both wet and dry periods. During the study daily and weekly flow rate measurements, ph measurements and temperature were used in the calculation of normalized base flow. The dye tracings indicated that groundwater flow is controlled by geologic structure and stratigraphy.20 The geologic structure limits the formation of conduit, which follows the path of least resistance. 21 These controls can then be used to develop a model of the groundwater flow. At Fort Knox the springs typically occurred were the soluble St Louis limestone made contact with one below it known as the Salem Limestone that acted as an aquitard. This forced the groundwater to flow horizontally because vertical movement was highly limited. The horizontal flow resulted in the creation of conduit as well as addition springs. In the eastern section of the military reservation these conduits resulted in dye traces being recovered 4 kilometers to the west of a injection site rather than at a spring less than half a km away.22 The Fort Knox study incorporated geologic study, spring identification, dye tracing to determine groundwater flow and direction. This allowed the determination of groundwater basin boundaries. When normalized base flow calculations were added to the model the extent of the groundwater basins could be determined. The NBF indicated that the basin was recharged visa autogenic means. Having estimated the recharge basins, areas of concern for groundwater contamination could be matched with maps of known hazardous waste site, allowing for the better groundwater management. 23 The Safe Water Drinking Act mandates that all states have a wellhead protection plan in order to safeguard water supply wells and springs. Kentucky’s EPA approved plan requires that recharge areas for groundwater basins be determined and potential hazards within the recharge areas identified.24 As a result of this type of study the Kentucky Geological Survey has undertaken the development of a statewide atlas of groundwater basins to be available as a GIS database. The data collected is from 50 years of dye tracing. These dye tracing records were studied to determine groundwater flow patterns and watershed boundaries. The watershed boundaries are difficult to determine in karst areas because the majority of surface drainage drops into underground conduits and caves. Existing databases from geological and water agencies were used to locate springs and karst features.25 Dye tracing also establishes groundwater flow so that the source of pollution in a discharge spring can be more readily located. The maps created were 30 x 60 minute quadrangles. The basin maps are key to the state of Kentucky being able to understand and protect groundwater resources. The atlas includes a series of maps identifying karst areas that are likely to flood. The majority of these are sinkholes which fill and flood during heavy of frequent storms, damaging structures in and around the sinkhole plain26 These maps are created by using GIS analysis comparing aerial and satellite images taken during dry and flood conditions in order to identify the areas of change 27 The karst atlas will also map places were sinkhole collapses have occurred. When used in conjunction with land use and groundwater flow map areas of concern can be identified. The purpose of the atlas does not include any sinkhole prediction, just the identification of sinkhole prone areas. Roads and buildings that lie within these areas can then be identified for continued monitoring.28 The following page is a map of the Karst Groundwater Basin for the Bowling Green 30 x 60 quadrangle from the atlas. For example the Mammoth Cave area includes a large sink hole plain recharge area. Here thousands of sinkholes recharge the aquifer almost immediately and directly from precipitation. 29 In areas with sandstone caprock, streams run along the surface and then upon reaching the karst edge drop into the aquifer via vertical shafts. These sinking streams usually have fast infiltration into the groundwater 30 this can result in flood conditions when sinkholes can not take in the volume of water in the recharge area. Flood waters pond and build up in the vadose zone, resulting in increased hydraulic head. These flood conditions result in the deposit of both sediments and contaminants in the floodplain. Sinkholes form in places were there is depression in the underlying bedrock which is covered by soil or unconsolidated material, and finally a vertical drain path for the groundwater. As the carbonate rock is dissolved the bedrock collapses and the materials are carried away in the conduit. The resulting dome works its way up until the surface collapses into the dome.31 Sinkholes force water into the aquifer at localized points, increasing head and resulting in conduit formation along resistant aquitard formations.32 As groundwater conduits and springs form the potentiometric surface is lowered in places, resulting in little or no water and the resulting caverns which karst terrane is so well known for.33 The hydrology of the karst terrane is unique. The techniques and methodologies used elsewhere often do not provide adequate basis for the study of this unique environment. Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.85. 2 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.88. 3 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 527 4 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 526 5 Hess, John W; Wells and White, William B. “Chemical Hydrology”. Karst Hydology p 156 6 Hess, John W; Wells and White, William B. “Chemical Hydrology”. Karst Hydology p 145 7 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 47 8 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 47 9 Quinlan, James F, Ray, Joseph E ”Normalized base-flow discharge of groundwater basins: Auseful parameter for estimating recharge areas of springs and for recognizing drainage anomalies in karst terranes” Karst Geohazards p151 10 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 526 11 Quinlan, James F, , Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 530 12 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 527 13 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 527 14 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 528 15 Quinlan, James F, Ray, Joseph E, Schindel, Geary M. “Intrinsic limitations of standard criteria and methods for groundwater-source areas in carbonate terrranes:Critical review, technically sound resolution of limitations and case study in Kentucky Karst” Karst Geohazards, p 528 16 Quinlan, James F, Ray, Joseph E ”Normalized base-flow discharge of groundwater basins: Auseful parameter for estimating recharge areas of springs and for recognizing drainage anomalies in karst terranes” Karst Geohazards p151 17 Quinlan, James F, Ray, Joseph E ”Normalized base-flow discharge of groundwater basins: Auseful parameter for estimating recharge areas of springs and for recognizing drainage anomalies in karst terranes” Karst Geohazards p151 18 Conner,Dennis, Engel,Sott and Murrary, Brain S. “Karst groundwater basin delineation in Fort Knox Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.287 19 Conner,Dennis, Engel,Sott and Murrary, Brain S. “Karst groundwater basin delineation in Fort Knox Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.288 20 Conner,Dennis, Engel,Sott and Murrary, Brain S. “Karst groundwater basin delineation in Fort Knox Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.288 21 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 49 22 Conner,Dennis, Engel,Sott and Murrary, Brain S. “Karst groundwater basin delineation in Fort Knox Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.288 1 Conner,Dennis, Engel,Sott and Murrary, Brain S. “Karst groundwater basin delineation in Fort Knox Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.291 24 Harker, Kay and Ray, Joseph E ”Status of Kentucky’s regulatory programs that address karst” Karst Geohazards p507 25 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.86 26 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p 87. 27 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.88. 28 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.88. 29 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 29 30 Currans, James and Ray, Joseph, “Karst Atlas for Kentucky”, Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999, p.85. 31 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 34 32 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 50 33 Hess, John W; Wells, Stephen; Quinlan, James F.; White, William B. “Hydrogeology of the SouthCentral Kentucky Karst”. Karst Hydology p 51 23 Source Works: Hydrogeology and Engineering Geology of Sinkholes and Karst- 1999 edited by Barry F. Beck, Aurthur J Pettit, J. Gayle Herring. AA Balkema Rotterdam, Netherlands, 1999. Karst Geohazards edited by Barry F. Beck. AA Balkema Rotterdam, Netherlands, 1995. Karst Hydrology edited by William B White, Elizabeth L White. Van Nostrand Reinhold, New York, 1989