Introduction - Big Concepts in Geology 1) Scientific Method 2) Geologic Time 3) Interior of the Earth 4) Plate Tectonics 1) - Scientific Method Ask question about natural world Collect data Propose hypothesis to explain data Testing of hypothesis - If hypothesis fails any tests = rejected Hypothesis repeatedly confirmed = Theory Durable Theory = Scientific Law 2) - Geologic Time How long did it take for the sediments to be deposited? Can be determined using Relative Dating - Law of Superposition Time to Deposit Sediments at a rate of 1 mm/year Convert 25’ to equivalent number of millimeters (25’ x 12 inches/foot x 2.54 cm/inch x 10 mm/cm) = ~ 65,000 mm = 65,000 years Age of Earth = 4.6 Billion Years = 4,600,000,000 Years Age established using Absolute Dating Radioactive Decay of Uranium to Lead - 238U > 206Pb Carbon 14 Dating - produced by cosmic radiation in upper atmosphere - half of 14C decays to 14N in 5,730 years - method good for material up to ~50,000 years old (e.g. 15,000 year old moccasins from Missouri cave) - - Ice Layers in Glaciers - glaciers in Greenland, Antarctica are 3,000 m thick (2 miles) - glaciers are built up by annual deposition of snow - there is a nearly continuous record over 65,000 years and a composite record extending back 165,000 years 3) - Interior of the Earth How do we know what the interior of the Earth looks like ? Seismic Waves from big Earthquakes (+ atomic explosions) Seismic Waves can be used to study the interior of the Earth just like ultrasonic waves are used to study the human body - Refraction and reflection of seismic waves are caused by changes in velocity with depth and the existence of layers 4) Plate Tectonics - Plate Tectonic Theory is a unifying theory that explains most of the geological features and events on Earth. - It is as important to Geology as the Theory of Evolution is to Biology - Sea Floor Spreading - proposed after Asthenosphere discovered - There are three types of plate boundaries - 1) Divergent / Spreading - 2) Convergent / Subduction - 3) Transform Fault Minerals - Why are Minerals Important to Us? - Civilization as we know it would not exist without Agriculture and Minerals - Minerals are used for: Building construction (cement, stone) Metals (steel, copper, aluminum) Glass production (bottles) Medicine (toothpaste, kaopectate) Food (salt, salt substitute, cereal) Industry (polish lenses, mirrors) Gems (diamonds) A mineral is: (1) (2) (3) (4) naturally occurring inorganic solid substance, has an orderly internal arrangement of atoms particular physical properties and chemical composition N.B. - This definition is not the same as the one in your book ATOMS + ELEMENTS Basic Atomic Structure - all matter is composed of atoms - atoms are the smallest part of an element - atoms are made up of neutrons, protons and electrons - There are 92 naturally occurring elements on earth - Is that all there is to atoms? No – there are Quarks, Gluons and other subatomic particles - Atomic Number = # protons in element (defines element) Atomic Weight = # protons + # neutrons Isotopes - # neutrons vary Electrons = electric charge + chemical behavior of elements - Atoms commonly have too few or too many electrons - Most atoms have positive or negative charge and are called Ions Common Ions: Na 11P (+) 11N (0) 10e (-) Cl 17P (+) 17N (0) 18e (-) Na+ Cation Cl- Anion Na+ + Cl- = NaCl (halite/rock salt) electrically neutral compound Compounds - formed by bonding of oppositely charged ions - organic - formed by life processes - inorganic - all others - Atoms are most stable when the outer most electron shells (electron orbits) are filled to capacity with electrons. Filling the shells can be done by the Bonding atoms together. - How can we fill the outer electron shell? - We can fill the shells by donating, exchanging, or sharing (with all) an atom Bonding types - Ionic bonds (donate one e-) - Oppositely charged Na + Cl ions join together to make NaCl (halite). - Most minerals have Ionic Bonds - Covalent bonds (share an e-) - shared electrons orbit both nuclei (the electrons are not lost or gained by an ion) - Metallic bonds (share e-’s with all) - each atom contributes 1 or more electrons to form a “sea” of electrons that move around freely (weaker bond) - Intermolecular bonds - due to uneven distribution of electrons - van der Walls bonds - electrostatic bonds (very weak) Identification of Minerals - The internal atomic structure and chemical composition determine mineral properties. I. Crystal Form - External shape reflects internal arrangement of atoms – Euhedral, Subhedral, Anhedral - Crystal Size - Polymorphs - Minerals with the same chemical composition but with different crystal structure 2. Hardness - the measure of resistance of a smooth mineral surface to abrasion – Mohs Hardness Scale 3. Specific Gravity - the ratio between weight of a mineral and the weight of an equal volume of water at 4°C - Specific Gravity increases with the atomic weight of the elements in a minerals as well as their density (packing of atoms). 4. Cleavage - tendency of a mineral to break parallel to planes of weak bonding 5. Fracture - Breakage other than along cleavage planes (e.g. breaking of bonds in a mineral that the same strength of bond in all directions) 6. Color - may vary widely (due to trace element content) - NOT VERY DIAGNOSTIC 7. Streak - color of a finely powdered mineral - Although the color of a mineral varies, the streak is constant 8. Luster - appearance of light reflecting from a mineral surface (reflects the bonding) 9. Other Properties a) diaphaneity - the ability to transmit light b) tenacity - resistance to bending, breaking, crushing, bending, or tearing c) taste d) odor e) reaction to acid f) magnetism g) radioactivity h) fluorescence i) X-ray diffraction Silicates - Independent Tetrahedra - Si:O = 1:4 - Single Chain - Si:O = 1:3 - Double Chain - Si:O = 1:2.75 - Sheet - Si:O = 1:2.5 - Framework - Si:O = 1:2 Common Non-Silicates - sulfides, oxides, carbonates, sulfates, native metals Mineral Composition of Continental Crust Feldspars 58 % Pyroxene + Amphibole 13 % Quartz 11 % Mica + Clay 10 % Most common elements in the crust of the Earth – Si, O Most common element in the entire Earth – Fe IGNEOUS ROCKS - Rock - A consolidated mixture of minerals (not fixed) - Igneous rocks form from magma, a hot, molten rock material • liquid pasty • contains molten silicates, dissolved water + gases • magma crystallizes in Earth to form igneous rocks • lava crystallizes on surface of Earth to form igneous rocks - Igneous rocks are the most abundant rock type on Earth CLASSIFICATION OF IGNEOUS ROCKS 1 - Mineral Content 2 - Color (Felsic or Mafic) 3 - Specific Gravity 4 - Texture - size, shape, arrangement + distribution of minerals - Phaneritic - coarse-grained - Aphanitic – very fine-grained - Glassy - Porphyritic - Pegmatitic - Pyroclastic Intrusive (plutonic) and Extrusive (volcanic) Rocks Intrusive (plutonic) - magma intruded into existing rocks - Types - Concordant and Discordant - Concordant - parallel to layers of pre-existing rocks - laccolith - lens-shaped - sill – tabular - Discordant - cross-cuts layers in pre-existing rocks - batholith - huge (100’s km) - stock - pipe-shaped - dike - tabular Extrusive (volcanic) - magma extruded on Earth’s surface = lava - Types - Flows and Volcanoes Igneous Rock Classification – Fig. 3.4 Why Do Igneous Rocks Have Different Compositions? A. Magmatic Differentation B. Assimilation C. Magma Mixing Order of Crystallization There is a definite temperature range over which certain minerals crystallize out of a magma. - As magma cools, minerals with simple silicate structures (less polymerized - isolated SiO4 tetrahedra) crystallize first. - as crystallization proceeds, magma becomes enriched in SiO2 and other elements (K, Na, Al). The later minerals contain more Si, and are more highly polymerized silicates (e.g. framework silicates). - Bowens Reaction Series - started with a Basalt Why do Magmas Form? - lower pressure - water addition Where do Magmas Form? 1) Mid-Ocean Ridge -melting of ferromagnesian silicate minerals in Upper Mantle produces Fe + Mg-rich magma at a 20 to 30 km depth - Cooling of a Fe + Mg-rich magma causes a rock rich in ferromagnesian silicate minerals to form (e.g. Basalt (Gabbro)). 2. Subduction Zones - Melting of continental crust + ocean crust + sediments + mantle + H2O produces a magma that is poor in Fe + Mg - This process forms igneous rocks rich in non-ferromagnesian silicates (e.g. Granite) 3) Hot Spots - probably caused by a stationary plume rising through the mantle - Magma produced at depths of 30 to 50 km by decreasing pressure as plume rises Volcanoes and Volcanic Activity I . Modern occurrences - Circum-Pacific (“Ring of Fire”) - Mediterranean Region - Mid-Ocean Ridges (Atlantic and Pacific) - Rift Valleys / Fractures in the crust (East Africa) - “Hot Spots” - anomalous unexplained areas (Hawaii) II. Volcanic Products - tephra - pyroclastic material - lava - pahoehoe - fluid lava that cools to a “ropy” texture - Lava - aa - thick viscous lava that cools with a rough, jagged, angular texture - pillow lava - extruded beneath sea, ~1m in diameter III. Rock Types - ash - <1 mm - tuff - fine-grained rock of volcanic fragments, <4mm (characteristic of ash falls and is generally welded) - breccia - angular fragments, > 4 mm - pumice - low density rock formed by frothing of lava by escaping gases - scoria - vesicular basalt flow (cavities form by expanding gas) - Blocks - Coarse, angular - Bombs - Hot lava thrown into the air and cooled to form spiral-shaped bombs IV. Eruptive Styles - quiet and effusive - explosive - dissolved gases (H2O,CO2) can’t escape causing pressure buildup + leads to an explosion - explosive nature depends on viscosity of the magma and this in turn is a function of its SiO2 content 1) explosive siliceous rocks such as rhyolite, obsidian, tuff + pumice (high SiO2 content - low viscosity) 2) less explosive andesite (Mt. St. Helens) (intermediate SiO2 content + viscosity) 3) least explosive basalt (Hawaii) (low SiO2 content + high viscosity) Types of Volcanoes I. Basalt flows (through fissures) II. Shield Volcanoes - basaltic lava erupts from a single vent or fissure. III. Composite Cone / Strato- Volcano - alternating lava flows and beds of pyroclastic rocks IV. Cinder Cone Volcanic Features Crater - depression above vent caused by lava cooling and sinking back into vent after eruption Plug Dome - viscous lava that solidified above volcanic vent Caldera - collapse feature formed around vent after the magma chamber is emptied Columnar Jointing – Lava Caves and Tubes – VOLCANIC ACTIVITY ALERT CODE - Green, Yellow, Orange and Red