UNIT: DEMONSTRATE AN UNDERSTANDING OF CHEMICAL IDEAS RELATING TO ACIDS AND BASES ACHIEVEMENT STANDARD: Science 1.5 ACHIEVEMENT OBJECTIVES: Material World Properties and changes of matter Identify patterns and trends in the properties of a range of groups of substances, for example, acids and bases, metals, metal compounds and hydrocarbons. Explore factors that affect chemical processes. The structure of matter Distinguish between atoms, molecules, and ions (includes covalent and ionic bonding). Link atomic structure to the organisation of the periodic table. Use particles theory to explain factors that affect chemical processes. Chemistry and society Investigate how chemical knowledge is used in a technological application of chemistry. TEXTS: New Directions in Science (ND) Year 11 Acids & bases SciPAD (SP) Pd Content 1 Periodic Table Periodic tables Activity: Shade metals, non-metals, solids, liquids, gases, halogens, inert gases, Group 1, Group 2 Show video “The Periodic Table" or Youtube clip 2 3 What is the world made of? Nature of Science: Understanding Science Alchemy to present day overview of the development of chemistry and the famous scientists involved. Structure of atoms Resources ND p34-37 Ex 1A, 1B Prac1 p1, Prac5 p2 SP p11 Photocopy of periodic table. Periodic table song: http://www.privatehand.com/flash/elements.html Element election DVD Mendeleev: http://www.youtube.com/watch?v=nsbXp64YPRQ Nature of Science: Understanding Science DVD The Story of Science (Episode 2) SP p9 ND p42 Ex 1E Describe arrangement and nature of protons, neutrons, and electrons. Calculate number of protons, neutrons and electrons from atomic number and mass number. Define and explain isotopes. Show two Powerpoints. 4 Electron arrangement Discuss stability of electron arrangement. Write electron arrangements for atoms and ions of the first 20 elements. Define what an ion is. Cover ion formation in the next lesson. Relate charge of monatomic (1 atom) ions to position in periodic table (Groups 1, 2, 16, 17 only). 5 How ions form Use Ionic bond/covalent bonding Powerpoint to explain the following concepts: 1. Transfer of electrons. 2. How the charge on the ion is related to how many electrons are gained or lost. 3. Ionic bond formation. 6 - Writing formulae of ionic compounds 7 Balancing charges when forming salts. Write formulae for AB, A2B, AB2, AB3 and salts that require brackets e.g. Ca(OH)2. 8 Balancing equations Write word and symbol equations. Use molymods to make models of H2, O2 and H2O and show how equations are balanced. Draw particle pictures. (see BU) 9 Making acids and bases Introduce litmus and universal indicator as acid-base indicators. Practical: Burn Mg and dissolve ash in small amount of water. Test with a few drops of Universal Indicator solution. Demonstration: Burn sulphur in gas jar of oxygen/or air. Gas jar should have a few cm of water with a few drops of Universal indicator. Test gas with damp litmus. Shake up water to dissolve SP p8, p10 & p12 ‘Atomic structure’ & ‘Isotopes’ Powerpoints K:\_2011 Science\Yr 11 Science\Powerpoints ND p44 Ex 1F SP p13 - 14 ND p46 Ex 1G SP p15 - 16 K:\2010 Science\Yr 11 Science\Chemistry\Powerpoints\Ion formation and ionic bonds Model of sodium chloride crystal lattice in storeroom with molymods. ND p48-51 Ex 1H-1I Prac10 p3 Ion table to stick in notes. SP p17 - 23 SP p24 – 27 Molymods ND p53 Ex2A ND p55 Ex2B ND p61 Ex2E ND p65 Ex2G Prac21 p6 SP p54 - 55 10 11 12 gas. Observe colour change. OHTs (metal oxides, non-metal oxides). Save water from sulfur exp. for later lesson. Explain what the colour change for each indicator means. Write equations for each of the reactions. Mg burning to produce MgO, MgO reacting with water to make Mg(OH)2, Mg(OH)2 dissolving in water (albeit only slightly) to give OH- ions. S burning to make sulfur dioxide, sulfur. Acid rain — oxides of sulfur and nitrogen. T Acid Rain Recognise acid nature of H+ ions and basic nature of OH- ions Conclusion: Metal oxides are basic & Non-metal oxides are acidic. pH Compare pH of different solutions. Write equations for dissociation of different acids Soil pH For achieved: word equations For merit: word and symbol equations For excellence: write a balanced symbol equation What can react with an acid? Reactions (1) Metal and acid (acids are limited to HCl and H2SO4) React metals (not calcium or lithium) with dilute hydrochloric acid Write word equations [METAL + ACID —> SALT + HYDROGEN] Reactions (2) Acid and base Metal hydroxides / oxides + acids [ACID + BASE —> SALT + WATER] Practical: Add 2M acid to 2M base and record temp. change (prove reaction has taken place). Practical: Add U.I to ethanoic acid and add ammonia drop by drop. U.I changes to green then purple. Proves neutralisation. Practical: Add sulphuric acid to copper(II) oxide and leave over night. Copper sulphate solution produced. Proves oxides act as bases. Boil off some water and allow the crystallize. U.I solution Variety of household and lab solutions ND p54-55 Prac 14 & 15 p4 SP p56 - 59 ND p74 Ex3C Prac32 p9 Hmwk: ESA p228 ND p74 Ex 3C ND p66 Ex 2H Prac12 p4 SP p65 13 14 15 16 17 18 19 Practise equations: Acid and base Write word and balanced symbol equations for a variety of reactions. Reactions (3) Acid and carbonate/hydrogen carbonate Metal carbonate / hydrogen bicarbonate + acid: observe reaction of calcium carbonate (marble chip) and hydrochloric acid. Identify gas produced (limewater). [ACID + CARBONATE —> SALT + WATER + CARBON DIOXIDE] Practise equations: Acid and carbonate Write word and balanced symbol equations for a variety of reactions. Antacid investigation Carry out investigation into which antacid tablet neutralizes the most acid. This involves a simple titration or add acid bit by bit to tablet and then measure total volume used. Follow the method on sheet/OHT in folder. Students fill in results etc in workbook 140-141. Reaction rate Effect of increasing concentration. Compare time taken to fill a boiling tube with gas at different concentrations. Discuss concentration as number of particles in a given volume. Increase conc. = more particles so more collisions. Effect of increasing temperature. Carry out thiosulfate/HCl clock reaction at different temperatures (see BU) or do ND Prac34. Discuss temperature as being the average Ek of particles, so higher temp. = faster moving particles so more collisions. Effect of increasing surface area. Compare time taken for Mg to disappear when reacted with HCl (single strip vs cut up pieces). Or do ND Prac19. Discuss increased surface area = more chance of a collision. Graphing a reaction curve Carry out reaction of Mg with acid measuring volume of gas produced over time. Graph the results. SP p62 - 64 ND p56 Ex 2C Prac18 P5 SP p66 - 68 ND p56 Ex2H SP p60 - 61 ND Prac33 p10 SP p38 - 43 45ml 0.25M thiosulphate + 5ml 2M HCl. Stopwatches. ND Prac34 p10 Dust explosions: http://videos.howstuffworks.com/discovery/35516howstuffworks-show-episode-7-explosive-wheatvideo.htm ND Prac19 p6 P34 - 37 20 21 22 23 Explain shape of graph. Collision theory Particles need to collide with enough energy (to overcome activation energy barrier) and with correct orientation for a successful collision to occur. Real life applications Discuss, complete problems or research any of the following: Acid rain effect on buildings Treating stings from various organisms. Using kindling to start fires. Revision Practise questions from old exam papers. Exam paper at the back of the SciPAD. Test ND p76 3D SP p33 SP p69 SP p72 - 79 On K-drive or from NZQA website