Equation Stoichiometry Worksheet-1 1. When potassium chlorate is heated, it decomposes to potassium chloride and oxygen gas. a) Write a balanced molecular equation showing this reaction. Include phases. 2KClO3(s) 2KCl(s) + 3O2(g) b) If 0.500 grams of potassium chlorate is decomposed, calculate the moles of potassium chloride and moles of oxygen gas that will be produced. 0.500 g KClO3 x (1 mol KClO3/122.6 g KClO3) x (2 mol KCl/2 mol KClO3) = 0.00408 mol KCl 0.500 g KClO3 x (1 mol KClO3/122.6 g KClO3) x (3 mol O2/2 mol KClO3) = 0.00612 mol O2 c) Calculate the masses of potassium chloride and oxygen gas that will be produced. 0.00408 mol KCl x (74.6 g KCl/1 mol KCl) = 0.304 g KCl 0.00612 mol O2 x (32.0 g O2/1 mol O2) = 0.196 g O2 Or 0.500 = 0.304 + X, x = 0.196 g O2 2. A 4.25 mole sample of molten aluminum chloride undergoes electrolysis. a) write a balanced molecular equation showing this reaction 2AlCl3(l) 2Al(s) + 3Cl2(g) 1 b) calculate the masses of products formed. 4.25 mol AlCl3 x (2 mol Al/2 mol AlCl3) x (27.0 g Al/1 mol Al) = 115 g Al 4.25 mol AlCl3 x (3 mol Cl2/2 mol AlCl3) x (71.0 g Cl2/1 mol Cl2) = 453 g Cl2 3. A sample of magnesium metal reacts pure nitrogen gas. a) write a balanced molecular equation for this reaction 3Mg(s) + N2(g) Mg3N2(s) b) calculate the masses of each of the reactants that would be needed to produce exactly 0.400 mole of magnesium nitride. 0.400 mol Mg3N2 x (3 mol Mg/1 mol Mg3N2) x (24.3 g Mg/1 mol Mg) = 29.2 g Mg 0.400 mol Mg3N2 x (1 mol N2/1 mol Mg3N2) X (28.0 g N2/1 mol N2) = 11.2 g N2 4. A sample of zinc metal is placed in a solution of hydrochloric acid. a) write a balanced molecular equation for this reaction Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g) 2 Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g) If 2.80 g of zinc reacts with excess acid, b) calculate the moles of hydrogen gas produced 2.80 g Zn x (1 mol Zn/65.4 g Zn) x (1 mol H2/1 mol Zn) = 0.0428 mol H2 c) calculate the mass of hydrogen gas produced 0.0428 mol H2 x (2.0 g H2/1 mol H2) = 0.0856 g H2 d) if the solution is allowed to evaporate, determine the mass of salt that will be found in the bottom of the beaker. 2.80 g Zn x (1 mol Zn/65.4 g Zn) x (1 mol ZnCl2/1 mol Zn) X (136.4 g ZnCl2/1 mol Zn Cl2) = 5.84 g ZnCl2 5. Exactly 4.75 grams of copper(II)chloride in solution reacts with excess sodium hydroxide solution. a) Write a balanced molecular equation for this reaction CuCl2(aq) + 2NaOH(aq) Cu(OH)2(s) + 2NaCl(aq) b) Calculate the moles of precipitate that will form 4.75 g CuCl2 x (1 mol CuCl2/134.5 g CuCl2) X (1 mol Cu(OH)2/1 mol CuCl2) = 0.0353 mol Cu(OH)2 c) Calculate the mass of precipitate that will form 0.0353 mol Cu(OH)2 x (97.5 g Cu(OH)2/1 mol Cu(OH)2 ) = 3.44 g Cu(OH)2 3