Woodhouse Chemistry Ions, Formulae and Equations 1. Relationship between the charges on simple ions and their position in the Periodic Table 2. Understanding a Charge Table See attached 3. Writing formulae using ions To write the formula of a compound the charges on the ions must cancel out. Using the ‘Charge table’, you can turn the name of a compound into its formula. Name of compound Sodium chloride Ions Balance charges Iron (III) oxide Lithium sulphate (VI) Exercise 1: Work out the formulae of the following simple compounds. a b c d e f Sodium fluoride Lithium iodide Magnesium sulfide Calcium oxide Aluminium nitride Iron (III) phosphide g h i j k l Magnesium chloride Sodium sulfide Aluminium iodide Lithium nitride Magnesium nitride Aluminium oxide Formula Exercise 2: Work out the formulae of the following compounds which contain polyatomic ions. a b c d e f Potassium nitrate Sodium hydroxide Magnesium sulfate (VI) Calcium carbonate Aluminium phosphate Ammonium chloride g h i j k l. Iron(II) sulfate (VI) Hydrogen chloride Silver nitrate Sodium hydrogencarbonate Lead (II) carbonate Ammonium hydroxide Exercise 3: In this exercise you may need to use brackets in the formulae. We use brackets around polyatomic ions whenever we need two or more of them. e.g. sodium hydroxide, NaOH copper hydroxide, Cu(OH)2 aluminium hydroxide, Al(OH)3 a b c d e f Copper (II) nitrate Sodium sulfate (VI) Calcium hydroxide Sodium hydrogensulfate Aluminium nitrate Potassium hydrogen phosphate g h i j k l Iron (III) sulfate (VI) Copper (II) ethanoate Ammonium carbonate Calcium phosphate Iron (III) carbonate Ammonium sulfate (IV) 4. Balancing some simple equations Write the word equation and the write in the formulae underneath it: Sodium hydroxide + hydrochloric acid sodium chloride + water NaOH + HCl NaCl + H 2O In a balanced equation there will be the same number of atoms of each element on both sides of the arrow. In this example there is one sodium atom in the sodium hydroxide and one in the sodium chloride. There is one atom of hydrogen on each side also. Count the hydrogens and the chlorine. Exercise 4 I. Calcium carbonate calcium oxide + carbon dioxide II. Hydrochloric acid + sodium hydroxide sodium chloride + water III. Magnesium + sulfuric acid magnesium sulfate (VI) + hydrogen gas IV. Copper sulfate (VI) + zinc zinc sulfate (VI) + copper V. Iron (II) oxide + calcium calcium oxide + iron 5. More difficult equations: you need to multiply some of the formulae to balance the elements Start with what changes……. there are 2 O’s in O2 and only one in CuO. To balance it you need 2 O’s in the products. Don’t be tempted to write CuO2, you have found the formula and you can’t change it. Instead double the CuO Now you have balanced the oxygen, you have 2 O’s in O2 and in the 2CuO But you now have 2Cu’s in the products but only one in the reactants, so double the Cu Copper + oxygen gas copper oxide Cu + Cu + 2Cu 2. Aluminium + oxygen gas aluminium oxide 3. Zinc + hydrochloric acid zinc chloride + hydrogen gas 4. Copper oxide + nitric acid copper nitrate + water O2 + O2 CuO 2CuO 2CuO Quickly double check each element, all done! Exercise 5: Try these harder ones (Remember…. hydrogen gas is H2, oxygen gas is O2) 1. Magnesium + oxygen gas magnesium oxide O2 5. Calcium carbonate + hydrochloric acid calcium chloride + water + carbon dioxide gas 6. Sodium + oxygen gas sodium oxide 7. Sodium hydroxide + sulfuric acid sodium sulfate + water 8. Sodium + water sodium hydroxide + hydrogen gas 9. Aluminium + Iron (III) oxide aluminium oxide + iron 10. Magnesium nitrate magnesium oxide + oxygen gas + nitrogen dioxide (NO2) The last one is difficult, if you can’t balance it first time through, try starting with two magnesium nitrates. To prepare for September Enjoy yourself and relax Learn the ‘Charge Table’ off by heart! (we will be testing you on this) Have a go at balancing the equations in exercises 4 & 5 Read up on ‘Atomic structure’ which is the first topic we will be studying. (AQA Chemistry A level) 1+ Lithium Sodium Potassium Rubidium Caesium Silver Hydrogen Copper (I) 2+ + Li Na+ K+ Rb+ Cs+ Ag+ H+ Cu+ 3+ Beryllium Magnesium Calcium Strontium Barium Copper (II) Iron (II) Lead Zinc 2+ Be Mg2+ Ca2+ Sr2+ Ba2+ Cu2+ Fe2+ Pb2+ Zn2+ Boron Aluminium Gallium Iron (III) 33+ B Al3+ Ga3+ Fe3+ Nitride Phosphide 23- N P3- Oxide Sulfide Selenide 12- O S2Se2- Fluoride Chloride Bromide Iodide Hydride FClBrIH- Simple ions Polyatomic ions 1+ 3- Ammonium NH4+ Hydronium/oxonium H3O+ Phosphate (III) / phosphite Phosphate (V) 2PO43- Carbonate PO33- Sulphate (VI) 1CO32SO42- Sulphate (IV) / Sulphite Chromate (VI) SO32- Dichromate (VI) Ethandioate Cr2O72- CrO42- C2O42- Hydrogen carbonate Hydrogen sulphate Nitrate (V) HCO3- Nitrate (III) / Nitrite Hydroxide NO2- Manganate (VII) Ethanoate MnO4- HSO4NO3- OH- CH3COO-