EXAM 1 – CHEM 1211 – SECTION A NAME(1 point)___KEY Answers are highlighted_ 100 points total Dr. Gosnell Sept. 16, 2005 Multiple Choice (33 questions; 3 points each 1. The boiling point of liquid helium is 4 K. What is this temperature in Celsius? Subtract 273 a) -294 ºC b) -277 ºC c) -269 ºC d) -255 ºC e) -169 ºC 2. Which one of the following is a homogeneous mixture? Looks uniform a) baked beans b) sugar dissolved in water c) chocolate chip ice cream d) chicken noodle soup 3. The density of acetic acid is 1.05 g/mL. What is the volume of 327 g of acetic acid? d mass volume a) 2.91 10-3 mL volume 327 g mass 311ml density 1.05 g / ml b) 3.21 10-3 mL c) 2.62 102 mL d) 3.11 102 mL e) 3.43 102 mL 4. What is the name of the element with the symbol B? a) boron b) beryllium c) bismuth d) bromine e) barium 5. Which of the following is an extensive property? Depends on sample size a) volume b) density c) melting point d) boiling point e) both melting and boiling point 6. Which one of the following is an example of physical change? No change in chemical identity a) the evaporation of water d) the tarnishing of silver b) the rusting of iron c) the combustion of hydrogen e) both the rusting of iron and the tarnishing of silver 7. Two electronic balances are tested using a standard weight. The true mass of the standard is 1.3111 g. The results of 5 individual measurements on each balance are recorded below. Balance A Balance B 0.8888 g 1.3110 g 0.9959 g 1.3109 g Balance A has scattered data and 1.1182 g 1.3111 g the average is not close to the standard. 1.0033 g 1.3110 g Balance B has data that are close to 0.9938 g 1.3110 g each other and close to the standard. average mass = 1.0000 g 1.3110 g Which statement best describes the results? a) A: good precision, good accuracy. B: good precision, good accuracy. b) A: good precision, good accuracy. B: poor precision, poor accuracy. c) A: poor precision, good accuracy. B: good precision, good accuracy. d) A: poor precision, poor accuracy. B: good precision, good accuracy. e) A: poor precision, poor accuracy. B: good precision, poor accuracy. 8. A student determines the density of a bar of silver by measuring its dimensions (2.00 cm by 1.15 cm by 1.00 cm) and determining its mass (25.3 g). If the true density of silver is 10.5 g/cm3, what is the percent error in the student’s measurement? Volume = (length)x(width)x(heighth) = (2.00 cm)x(1.15cm)x(1.00cm)=2.30cm3 d 25.3g mass 11g / cm 3 3 volume 2.30cm %error exp exerimental true true b) 3% a) 1% X 100 11g / cm 3 10.5 g / cm 3 10.5 g / cm 3 d) 10% c) 5% x100 5% 9. An atomic mass unit (u) is defined as a) the mass of one hydrogen-1 atom. b) 1/8 the mass of one oxygen-16 atom. c) 1/12 the mass of one carbon-12 atom. d) 1.99 10-23 g. e) the sum of the masses of one proton, one neutron, and one electron. 10. The wavelength of light emitted from a green laser pointer is 5.32 102 nm. What is the wavelength in meters? 1x10 9 m 5.32 x10 7 m 5.32 x10 2 nm 1 nm -9 a) 5.32 10 m b) 5.32 10-7 m c) 5.32 10-5 m d) 5.32 10-3 m e) 5.32 10-1 m 11. Beta (β) particles are identical to ________. a) neutrons b) electrons c) helium nuclei d) light e) protons 12. What is the correct answer to the following expression: (72.61 – 68.59) 18.76? Carry out the subtraction operation first. a) 7 × 101 b) 75 c) 75.4 d) 74.542 e) 75.5415 13. A typical volumetric flask holds a volume of 0.250 L. What is this volume in cubic centimeters? 1000mL 1cm Definition-1mL=1cm 0.250 L 1L 1mL a) 0.25 cm3 b) 2.50 cm3 c) 250 cm3 3 3 250cm 3 d) 2.50 × 103 cm3 14. Which of the following postulates of Dalton’s atomic theory are now known to be incorrect? 1. Matter is made up of atoms. 2. All atoms of a given element are identical……..We now know about isotopes. 3. Atoms combine in whole number ratios to make compounds. a) 1 only b) 2 only c) 3 only d) 2 and 3 e) 1, 2, and 3 15. Which does not describe Tellurium (Te)? a) metalloid b) chalcogen c) main group element d) halogen 16. From the results of his gold foil experiment, Ernest Rutherford concluded that a) electrons have a charge of –1.602 10-19 C. b) atoms contain equal numbers of protons and electrons. c) uranium ores emit a form of radiation that affect photographic plates. d) alpha particles are helium nuclei. e) atoms are composed of a small, dense nucleus surrounded by a cloud of electrons. 17. What is the correct name for PF5? Two non-metals, use molecular naming rules. a) phosphorus pentafluoride b) phosphorus pentafluorine c) phosphorus(V) fluoride d) phosphorus fluorate e) phosphorus fluoride 18. What is the atomic symbol for an element with 28 protons and 31 neutrons? a) 59 28 Ni b) 31 28 Ni c) 59 31 Ga d) 28 59 Pr e) 31 3 Li 19. What is the correct formula for cobalt(III) oxide? a) CoO b) Co3O c) Co3O2 d) Co2O3 e) CoO3 20. Isotopes of a given element have the same number of ________, but different numbers of ________ in their nucleus. a) neutrons, electrons b) electrons, protons c) protons, electrons d) neutrons, protons e) protons, neutrons 21. Calculate the number of moles in 39 g silicon. 1mol 1.4mol 39 g 28.0855 g a) 9.1 × 10-4 mol b) 0.72 mol c) 1.4 mol d) 11 mol e) 1.1 103 mol 22. An element consists of two isotopes. The abundance of one isotope is 95.72% and its atomic mass is 114.9041 u. The atomic mass of the second isotope is 112.9043 u. What is the average atomic mass of the element? AW .9572x114.9041u 0.0428x112.9042u 114.8u a) 113.9 u b) 113.0 u c) 113.9 u d) 114.8 u e) 115.1 u 23. The molar mass of silver is 107.9 g/mol. What is the mass of a single silver atom? 107.9 g / mol massatom 1.792 x10 22 g 6.02 x10 23 atoms / mol a) 1.539 × 10-26 g b) 1.792 × 10-22 g c) 1.079 × 10-20 g d) 1.901 × 10-18 g 24. Which three elements are likely to have similar chemical and physical properties? Same column a) sodium, lithium, and potassium b) sodium, magnesium, and aluminum c) nitrogen, oxygen, and neon d) nickel, copper, and zinc e) uranium, plutonium, and americium 25. Which of the following formulas is not correct? Ba is 2+ and O is 2- so they form BaO a) Al2(SO4)3 b) NaClO3 c) Ba2O3 d) Mg(NO3)2 e) KH2PO4 d) NaCH2O2 e) NaCHO 26. What is the correct formula for sodium acetate? a) Na2CH3O b) NaCH3CO2 c) NaCH3O 27. All of the following are named correctly EXCEPT Should be Iron(II) sulfate a) NiCl2·6H2O; nickel(II) chloride hexahydrate. c) TiBr4; titanium(IV) bromide. e) FeSO4; iron(I) sulfate. b) MnO2; manganese(IV) oxide. d) AuI; gold(I) iodide. 28. Benzene, an organic solvent, has the empirical formula CH. If the molar mass of benzene is 78.11 g/mol, what is the molecular formula of benzene? molarmass 78.11g / mol 6 empiricalf ormulamass 13g / mol a) C4H30 b) C5H18 This means the molecular formula is 6 times the empirical c) C6H6 formula. d)C7H8 29. What is the mass percent of chlorine in iron(II) chloride? FeCl2 Formula weight = 126.7504 g/mol %massCl a) 14.0% masschlorine 2 x35.5g / mol x100 x100 55.9% FW 126.7504 g / mol b) 28.0% c) 44.1% d) 55.9% e) 66.7% 30. What is the molar mass of cobalt(II) iodide hexahydrate? CoI26H2O Add masses of 1 Co, 2 I, 12 H and 6 O a) 212.8 g/mol b) 293.9 g/mol c) 312.7 g/mol d) 420.8 g/mol 31. How many oxygen atoms are in 1.50 mol of SO3? 3molO 6.02 x10 23 atomsO 2.7 x10 24 atomsO 1.50mol 1 molSO 1 molO 3 a) 7.71 × 1021 atoms d) 9.03 1023 atoms b) 1.12 1022 atoms c) 3.01 1022 atoms e) 2.71 1024 atoms e) 465.1 g/mol 32. A 2.000 g sample of CoCl2·xH2O is dried in an oven. When the anhydrous salt is removed from the oven, its mass is 1.565 g. What is the value of x? Mass of water = mass before drying – mass after drying = 2.000 g – 1.565 g = 0.435 g water Molar mass of water 18 g/mol formula mass of anhydrous CoCl2 = 129.9 g/mol 1mol 0.012mol molCoCl 2 1.565 g 129.9 g 1mol .024mol molH 2 0 0.435g 18 g molH 2 O 0.024 2 molCoCl2 0.012 a) 1 b) 2 c) 3 d) 4 e) 6 33. Toluene is composed of 91.25% C and 8.75% H. Determine the empirical formula for toluene. A 100 g sample would have 91.25 g C and 8.75 g H. Find moles of each in 100 g sample. 1mol 7.60molC 91.25 gC 12 . 011 g ratio 1molH 8.68molH 8.75 gH 1 . 0079 g molH 8.68mol 1.14 molC 7.60mol Find matching ratio in the answer selections. a) CH ratio =1 b) CH3 ratio = 3 c) C4H5 ratio =5/4=1.25 d) C7H8 ratio=8/7=1.14 BONUS POINT – 3 POINTS EACH 34. Which of the following statements are correct? 1. Metals generally lose electrons to become cations. 2. Nonmetals generally gain electrons to become anions. 3. Group 2A metals form ions with a 2+ charge. a) 1 only b) 2 only c) 3 only 35. How many grams are in 0.0751 mol Br2? a) 4.70 × 10-4 g 36. b) 0.0833 g d) 1,2, and 3 159.8 g 0.0751mol 12.0 g 1mol c) 2.13 g d) 6.00 g e) 12.0 g What is the common name for NH3? a) ammonia b) nitrogen trihydride c) trihydrogen nitride d) ammonium ion