MATERIAL SAFETY DATA SHEET Product Name: Ritiram Captan 1. Product and Company Identification Supplier: Telephone No: Fax No: Email: Natrol cc P.O. Box 1137 Delmas 2210 South Africa +27 (0) 82 738 0080 or +27 (0) 82 921 8428 +27 (0) 86 547 6711 jonathan@mbfi.co.za 2. Composition/Information on Ingredients Product description: A liquid fungicide for the protection of seed during storage, sowing, germination and emergence. Dangerous ingredients: None Identification: CAS No: 133-06-2 EEC No: None Index No: None 3. Hazards Identification Important hazards: None 4. First Aid Measures General Advice: Skin Contact: Eye Contact: Ingestion: Inhalation: Other information: Advice to physician: Keep out of reach of children and store in original containers only Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison center or doctor for treatment advice. Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call poison center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to by the poison center or doctor. Do not give anything by mouth to an unconscious or convulsing person. Remove patient to fresh air. See a doctor if an allergic reaction noticed. If a person is not breathing, call an ambulance and give artificial respiration, preferably mouth-to-mouth, if possible. Call a doctor immediately for treatment advice. None Probable mucosal damage may contraindicate the use of gastric lavage. 1 5. Fire Fighting Measures Type of material: Noncombustible liquid Extinguishing Media: Water, Foam, Carbon dioxide, etc Hazardous Decomposition Products: Not applicable 6. Accidental Release Measures Environmental precautions: Personal precautions: Destruction and clean up: Avoid infiltration of large volumes into drains, surface water, groundwater and soil. Respiratory protection, safety goggles, chemical-resistant gloves, long-sleeved shirt and long pants, shoes plus socks and a chemical-resistant apron are recommended. Sweep into a suitable container for disposal and wash area with soap and water. Pick up with oil absorbent material and place into containers for proper disposal. 7. Handling and Storage Handling: Storage: Ensure adequate ventilation when handling. Respiratory protection is recommended. Stored under cool 10 and 25oC, dry conditions (preferably 15oC). 8. Exposure Controls/ Personal Protection TLV: None Technical measures/precautions: Adequate ventilation Personal protection Respiratory Protection: Respiratory protection is recommended. Inhalation may cause risk of pulmonary aspiration. Hand protection: The product may cause slight skin irritation. Eye Protection: The product may cause slight eye irritation. Safety goggles are recommended. Skin and body protection: The product may cause slight skin irritation and an allergic reaction may occur in sensitive people. Hygiene recommendations: Wash hands after contact with the product. 9. Physical and Chemical Properties Physical state: Colour: Odour: Solubility: Vapour pressure: Boiling point: Melting point: Decomposition temperature: Miscibility: UV/Visible light absorption: Auto-ignition temp: Liquid concentrate Clear Characteristic slightly rotten odour Not applicable < 1.3 mPa at 25 ºC Not applicable 178 ºC (tec 160 – 170 ºC) Stable Not applicable Not applicable Not applicable 2 10. Stability and Reactivity Reactivity: Hazardous decomposition products: Materials to avoid: Conditions to avoid: Not reactive None identified Alkaline compounds Avoid very low or high temperatures and direct sunlight. 11. Toxicological Information ≥9000 mg/kg (M+F) Unknown > 5.0 mg/Litre Non-carcinogenic, non-teratogenic, and nonmutagenic or reproductive May cause eye and skin irritation, diarrhea, headache, vomiting. Avoid ingestion. LD 50 Acute Oral (Rat): LD 50 Acute Dermal (Rat): LC 50 Inhalation (Rat): Chronic toxicity: Effects of overexposure: 12. Ecological Information EC 50 Acute toxicity (Fish): EC 50 Acute toxicity (Daphnia): EC 50 Acute toxicity (Algae): Toxicity to birds: Toxicity to bees: Biodegradability: Extremely toxic to fish Not available Not available Not toxic Virtually not toxic The products constituents are biodegradable 13. Disposal Considerations The product may safely be disposed of by qualified local specialist companies. 14. Transport Information There are no transport regulations for this product. 15. Regulatory Information EEC Classification: Hazard Symbol / Labelling: S-phrases: National Regulations: Other Regulations: None None None None None 16. Other Information The purpose of the above information is to describe the product only in terms of health and safety requirements. The information given should not, therefore, be construed as guaranteeing specific properties or as a specification. Customers should satisfy themselves as to the suitability and completeness of such information for their own particular use. Contact Person: Mr. Jonathan Etherington +27 82 921 8428 3