Chemistry 200 Exam 1 Review Problems Email me if you find an error! 1.08 x 1023 atoms 1. Calculate the number of atoms in 10.0 grams of Fe. 2. Calculate the percent (by mass) of oxygen in H2O to three significant figures. 88.8 % 3. Calculate the number of moles of carbon in 50.0 g of benzene C6H6 3.84 mol C 4. A substance is found to be 38.7 % C, 9.7 % H and 51.6 % O by mass. mass is 62.1 g/mole. What is its molecular formula? C2H6O2 5. a) b) c) d) e) 6. Name the following: Ca(OH)2 calcium hydroxide KCN potassium cyanide HClO4(aq) perchloric acid FeSO4 iron (II) sulfate Na2O sodium oxide Its molar f) SF6 sulfur hexafluoride g) MgSO4 2H2O magnesium sulfate dihydrate h) Na2O2 sodium peroxide What are the formulas of the following compounds? a) sodium sulfite Na2SO3 b) potassium permanganate KMnO4 c) calcium sulfide CaS d) aluminum hydroxide Al(OH)3 e) mercury (II) phosphate Hg3(PO4)2 f) tetraphosphorus trisulfide P4S3 g) nitrous acid HNO2 7. Which of the following is not an example of a chemical change? a) b) c) d) e) converting gasoline to carbon dioxide and water digesting starch to give glucose grinding sucrose crystals into powdered sugar smoking tobacco generating carbon dioxide from baking soda and vinegar 8. The density of ethyl alcohol is 0.789 of ethyl alcohol ? 45.0 mL 9. How g/mL. What is the volume of 35.5 grams many significant figures are in the mass measurement 0.050 gram? 2 10. If an automobile engine has a volume of 155 in3, what is the volume in cm3 ? ( 2.54 cm = 1 in exactly) 2.54 x 103 cm3 11. Convert 25 μL into milliliters 0.025 mL 12. If 5.58 g of powdered iron react with powdered sulfur to produce 8.79 g of iron sulfide, what is the mass of reacting sulfur? 3.21 g 13. Sodium chloride, table salt, melts at 801C. the Fahrenheit scale ? 1474F 14. Express this number in scientific notation: What is the melting point on 0.00104 centimeter 1.04 x 10-3 cm 15. What is the mass in kilograms of a beaker that weighs 101 grams? 16. Convert 12 gcm2/s2 to Joules (kgm2/s2) 1.2 x 10 –6 0.101 kg J 17. A 1.013 g sample of a hydrate, ZnSO4 X H2O is dissolved in pure water and the sulfate ion is precipitated by adding an excess of barium chloride solution. The mass of pure dry barium sulfate obtained is 0.8223 g. What is the formula of the zinc hydrate? ZnSO4 7H2O hint: “7” is the ratio of moles of water to moles of zinc sulfate in the hydrate. mol Zn sulfate = mole of sulfate = mole Ba sulfate. To get mole of water you need to first get g water: subtract g Zn sulfate (you have moles) from g sample. Now you can calc the mole ratio. 18. 0.01981 g of an acid containing only C, H, and O undergoes combustion (reaction with O2) to yield 0.04198 g carbon dioxide and 0.00645 g water. What is the empirical formula of the acid? C4H3O2 19. The maximum allowable concentration of carbon monoxide in urban air is 10 mg/m3 over an eight-hour period. At this level, what mass of CO in grams is present in a room measuring 8.0 x 12.0 x 20.0 ft ? 0.54 g 20. An English unit used in pharmaceutical work is the grain (gr). There are 15 grains in 1 gram. An aspirin tablet contains 5.0 gr of aspirin. A 145 lb person takes two aspirin tablets. Calculate the dosage of aspirin, which is the number of milligrams of aspirin per kilogram of body weight. (1 lb = 453.5 g) 10.1 mg/kg 21. The dosage of an arthritis medicine for dogs is given as 1.5 – 1.7 mg / kg body weight. If my dog weighs 70. lbs and the drug comes as 100 mg tablets, how many tablets should my dog get? (1 lb = 453.5 g) half of a tablet (50 mg) True or False 22. A compound is a pure substance that cannot be broken down any further by ordinary chemical reaction. false 23. Li2O is dilithium oxide. false 24. The nucleus of one atom of 25. The name of the family of potassium is “alkali metal". true 18O contains 18 neutrons and 8 protons. 26. Sodium chloride is a mixture. 27. All atoms of an element have the same mass. false false false More Calculations: 28. Given the reaction: 2C2H6 + 7O2 ─────> 4CO2 + 6H2O How many moles of O2 will react completely with 12.00 moles of C2H6 ? 29. Given the equation: 4FeS2 + 11O2 ─────> 2Fe2O3 + 8SO2 If you react 85 grams of FeS2 with excess O2 , how many grams of get? 57. g 30. 42.00 mol Given the reaction: 2C2H6 + 7O2 Fe2O3 should you 4CO2 + 6H2O If 28.0 grams of C2H6 are reacted with excess oxygen, and 70.0 grams of CO2 produced , what is the percent yield of the reaction? ? 85.4 % 31. Given the reaction: If 15.00 g of H2 16.9 g 2 H2 + are mixed with 15.0 g of O2 O2 are 2 H 2O what mass of water is produced? 32. What is the molarity of a HCl(aq) solution made by dissolving 0.20 moles of HCl(g) in enough water to make 40.0 mL of solution? 33. 5.0 M What mass of NaOH(s) is required to prepare 250 mL of 50.0 mM NaOH(aq)? 0.50 g 34. How many mL of 12 M HCl(aq) do you need to prepare 150.0 mL of 1.5 M HCl(aq)? 19 mL 35. If 75.0 g of Na2SO4 are dissolved in water to make 1.50 L of solution, what are the concentrations (molarity) of all the ions in the final solution? 0.704 M Na+, 0.352 M SO4236. skip 37. skip 38. Element X has three naturally occurring isotopes. The masses (amu) and % abundances of the isotopes are given in the table below. The average atomic mass of the element is _41.54____ amu. 39. – 41. See notes in packet for chp 2. 42. Provide the products of the following reaction and balance: 2C6H10 + 17O2 CO2 + 10H2O What type of reaction is this? combustion 43. Give the mass number, #protons, #neutrons and #electrons for the isotope strontium-88 Mass # 88; 38 protons; 50 neutrons; 38 electrons.