Date-Issued:
16-Feb-16
MSDS Ref. No:
SV-0001
Date-Revised:
19-11-10
Revision No:
1
MATERIAL SAFETY DATA SHEET
ACETONE
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
REACH Reg. No.
01-2119458049-33-0000
919-446-0
EC No.
APPLICATION
Supplier:
The following uses are addressed through the Chemical Safety Report (CSR) and Generic
Exposure Scenario (GES) library:
Manufacture of substance
Distribution of substance
Formulation & (re)packing of substances and mixtures
Uses in coatings
Use in cleaning agents
Lubricants
Use in metal working fluids / Rolling oils
Agrochemical uses
Use as a fuel
Use as a functional fluid
Road and construction applications
Laboratories
Manufacturer
Rocara Limited
Unit 4
Elmbank
Channel Commercial Park
Queens Road
Belfast
BT3 9DT
Contact
Telephone
Petrochem Carless Limited
Head Office - Cedar Court
Guildford Road, Fetcham
Leatherhead, Surrey
KT22 9RX
administrator@rocara.com
+44 28 90 461742
2. HAZARDS IDENTIFICATION
CLASSIFICATION (67/548)
CLASSIFICATION (EC 1272/2008)
F;R11 Xi;R36 R66 R67
Physical
Health
Environmental
Acetone
Flam. Liq. 2 - H225
EUH066;Eye Irrit. 2 - H319;STOT Single 3 - H336
Not classified.
1
LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008
SIGNAL WORD
Danger
HAZARD STATEMENTS
EUH066
H225
H319
H336
Repeated exposure may cause skin dryness or cracking.
Highly Flammable liquid and vapour.
Causes serious eye irritation.
May cause drowsiness or dizziness.
PRECAUTIONARY STATEMENTS
P210
P240
P243
P305/351/338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Take precautionary measures against static discharge.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P501a Dispose of contents/container to a registered waste disposal company
SUPPLEMENTARY PRECAUTIONARY STATEMENTS
P233
P241
P242
P261
P264
P271
P280
P303/361/353
P304/340
P312
P313
P337
P370/378
P403/233
P403/235
P405
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting/…/equipment.
Use only non-sparking tools.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash … thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Get medical advice/attention.
If eye irritation persists:
In case of fire: Use … for extinction.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
ENVIRONMENT
The product is not expected to be hazardous to the environment.
PHYSICAL AND CHEMICAL HAZARDS
The product is highly flammable and explosive vapours/air mixtures may be formed even at normal
room temperatures. Vapours may be ignited by a spark, a hot surface or an ember. Vapours are
heavier than air and may travel along the floor and in the bottom of containers.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
EC No.
606-001-00-8
EC No.
200-662-2
CAS-No.
67-64-1
4. FIRST AID MEASURES
GENERAL INFORMATION
Move the exposed person to fresh air at once.
Get medical attention if any discomfort continues.
INHALATION
Remove victim immediately from source of exposure.
Place unconscious person on the side in the recovery position and ensure breathing
Get medical attention.
INGESTION
DO NOT INDUCE VOMITING!
When risk of unconsciousness, place and transport the victim in secured side position.
Drink plenty of water.
Do not give victim anything to drink if he is unconscious.
Get medical attention immediately!
SKIN CONTACT
Remove contaminated clothing.
Wash the skin immediately with soap and water.
Get medical attention if any discomfort continues.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids.
Make sure to remove any contact lenses from the eyes before rinsing.
Continue to rinse for at least 15 minutes.
Get medical attention if any discomfort continues.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Stop flow of material to fire.
Fire can be extinguished using:
Water fog or mist.
Alcohol resistant foam.
Carbon dioxide (CO2).
Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Avoid breathing fire vapours.
Use water to keep fire exposed containers cool and disperse vapours.
Keep run-off water out of sewers and water sources. Dike for water control.
UNUSUAL FIRE & EXPLOSION HAZARDS
HIGHLY FLAMMABLE!
Vapours are heavier than air and may spread near ground to sources of ignition.
Solvent vapours may form explosive mixtures with air.
SPECIFIC HAZARDS
The product is flammable, and heating may generate vapours which may form explosive vapour/air
mixtures.
PROTECTIVE MEASURES IN FIRE
Wear full protective clothing.
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6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Protect drains by covering to avoid any spillage entering the drainage system.
SPILL CLEAN UP METHODS
Stop leak if possible without risk.
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate.
Wear necessary protective equipment.
Absorb in vermiculite, dry sand or earth and place into containers.
Disposal should be carried out in accordance with the Hazardous Waste Regulations. If any liquid
enters the drainage system or watercourse inform the local authorities, Fire Brigade and Enviroment
AgencyDisposal should be carried out in accordance with the Hazardous Waste Regulations. If any
liquid enters the drainage system or watercourse inform the local authorities, Fire Brigade and
Enviroment Agency.
7. HANDLING AND STORAGE
USAGE PRECAUTIONS
Do not use in confined spaces without adequate ventilation and/or respirator.
Eliminate all sources of ignition.
Keep away from heat, sparks and open flame.
Avoid inhalation of vapours and spray mists.
USAGE DESCRIPTION
Pump at no greater than 7 metres per second. Avoid static build up by suitable earthing
arrangements.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
Keep away from heat, sparks and open flame.
STORAGE CLASS
Flammable liquid storage.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Name
Acetone
Std
WEL
TWA - 8 hrs
500 mg/m3 - 1210 mg/m3
STEL - 15 min
1500 mg/m3 - 3620 mg/m3
Notes
WEL = Workplace Exposure Limit.
ENGINEERING MEASURES
Must not be handled in confined space without sufficient ventilation.
RESPIRATORY EQUIPMENT
If ventilation is insufficient, suitable respiratory protection must be provided.
HAND PROTECTION
Chemical resistant gloves required for prolonged or repeated contact.
Use protective gloves made of: Impermeable material.
The most suitable glove must be chosen in consultation with the gloves supplier, who can inform
about the breakthrough time of the glove material.
EYE PROTECTION
Wear approved safety goggles.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet.
Wash promptly with soap & water if skin becomes contaminated.
DO NOT SMOKE IN WORK AREA!
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9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
COLOUR
ODOUR
SOLUBILITY
MOL. WEIGHT
MELTING POINT (°C)
VAPOUR Density (air=1)
EVAPORATION RATE
FLASH POINT (°C)
FLAMMABILITY LIMIT LOWER(%)
FLAMMABILITY LIMIT UPPER(%)
SOLUBILITY VALUE
BOILING POINT (°C)
RELATIVE DENSITY
VAPOUR PRESSURE
VISCOSITY
AUTO IGNITION
TEMPERATURE (°C)
Clear Liquid
Colourless
Acetone, ketone.
Soluble in water. Miscible with: Organic solvents
58.09
-94
2.0
2 (EtEt=1)
- 17 CC (Closed cup).
2.5
13.0
(g/100gH2O@20°C)
55.8 - 56.7
0.792 @ 20 °c
24.66 kPa @ 20 °c
0.42 cSt @ 20 °c
540
10. STABILITY AND REACTIVITY
STABILITY
No particular stability concerns.
CONDITIONS TO AVOID
Avoid exposure to high temperatures or direct sunlight. Avoid excessive heat for prolonged periods
of time. Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
MATERIALS TO AVOID
Strong oxidising substances.
HAZARDOUS
DECOMPOSITION
PRODUCTS
In case of fire, toxic gases (CO, CO2, NOx) may be formed.
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No information available.
INHALATION
Gas or vapour is harmful on prolonged exposure or in high concentrations.
SKIN CONTACT
Repeated exposure may cause skin dryness or cracking..
EYE CONTACT
Irritating to eyes.
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12. ECOLOGICAL INFORMATION
ECOTOXICITY
Biodegradeability - fresh water- 76% after 10 days Not regarded as dangerous for the environment.
The product components are not classified as environmentally hazardous. However, this does not
exclude the possibility that large or frequent spills can have a harmful or damaging effect on the
environment.
LC 50, 96 Hrs, FISH mg/l
EC 50, 48 Hrs, DAPHNIA, mg/l
High 2000 (Trout)
High 10
MOBILITY
The product is soluble in water.
BIOACCUMULATION
The product does not contain any substances expected to be bioaccumulating.
DEGRADABILITY
The product is easily biodegradable.
13. DISPOSAL
DISPOSAL METHODS
This material must be disposed of via an Authorised Waste/Disposal Company in accordance with
Local and or National Waste Disposal Regulations.
14. TRANSPORT INFORMATION
UK ROAD CLASS
PROPER SHIPPING NAME
UN NO. ROAD
ADR CLASS NO.
ADR PACK GROUP
3
ACETONE
1090
3
II
HAZARD NO. (ADR)
ADR LABEL NO.
CEFIC TEC(R) NO.
RID PACK GROUP
IMDG CLASS
EMS
AIR CLASS
Acetone
UK ROAD PACK GR.
ADR CLASS Class 3:
TUNNEL RESTRICTION
CODE
II
Flammable liquids.
(D/E)
33 Highly flammable liquid
(flash-point below 23°C).
HAZARD No. (ADR)
33
3
30GF1-I+II
II
3
F-E, S-D
3
HAZCHEM CODE
RID CLASS NO.
UN NO. SEA
IMDG PACK GR.
UN NO. AIR
AIR PACK GR.
•2YE
3
1090
II
1090
II
6
15. REGULATORY INFORMATION
UK REGULATORY REFERENCES
Highly Flammable Liquid Regulations 1972.
CDG Road, The Classification , Packaging and Labelling Regulations 1996.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC.
Dangerous Preparations Directive 1999/45/EC.
STATUTORY INSTRUMENTS
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
GUIDANCE NOTES
Workplace Exposure Limits EH40.
16. OTHER INFORMATION
REVISION COMMENTS
Classification in accordance with REACH registration dossier and HSPA recommendations
Disclaimer
The information contained in this document is intended to describe the product only in terms of health, safety and
environmental requirements for the purposes of its safe handling, use and disposal and is to the best of ROCARA
Limited’s knowledge and belief correct. ROCARA Limited Technical Services will be pleased to give further advice and
assistance, but customers must satisfy themselves (by appropriate testing if necessary) that the product is suitable for their
purposes and conditions of use and that their facilities and arrangements are suitable for handling or using the product.
Accordingly ROCARA Limited disclaims any liability for loss, injury or damage which may result from the use of the
product, this information or from such advice and assistance save as may be expressly agreed under its terms of sale.
This information does not comprise a technical or performance specification for the product and customers are referred to
any relevant product technical information or specification issued by ROCARA Limited.
Customers are also reminded that there may be uses or application for the product which are protected by ROCARA
Limited or third parties' patent rights and nothing herein may be construed as an authority or encouragement to use or
apply the product in contravention of such rights.
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