science world 2 – chapter 1 investigating reactions REACTION RATE Chemical reactions take place at different speeds. For example, fireworks react quickly once lit, but the rusting of a car will take years. The speed of a chemical reaction is called its reaction rate. You can speed up or slow down a reaction by changing the conditions under which they occur. These include: the temperature at which the reaction occurs. Higher temperatures cause faster reactions. the concentration of the reacting substances. More concentrated reactants cause faster reactions. the size of the reacting particles. Smaller particles react faster than big pieces. the presence of a catalyst. Catalysts are substances that speed up the reaction, but are not used up in the reaction. EXPLAINING REACTION RATES Chemical reactions can be explained in terms of the particle theory of matter. This theory says that: 1. All matter is made up of microscopic particles. 2. There are spaces between particles. 3. There are attractive forces between particles, which become weaker the further apart the particles are. 4. The particles are always moving. 5. At high temperatures the particles move faster than at low temperatures. A chemical reaction can only occur when the particles of the reacting substances come into contact with each other (i.e. they collide). According to the particle theory, higher temperatures cause particles to collide more often and more violently (more energetically) than at lower temperatures. For these two reasons, reaction rate increases with temperature. 1 Concentration is a measure of how much solute is dissolved in a solution, compared to the amount of solvent. A higher concentration of a reactant usually increases the reaction rate. This is because the reacting particles are closer together and collide more often. The rate of a reaction is also affected by the size of the reacting particles. Smaller particles have a greater surface area available to react and therefore react more quickly than big pieces that have a small surface area. For example, kindling (wood chips) burns a lot quicker than a big log. CATALYSTS & ENZYMES Catalysts are chemicals that can increase the rate of a reaction but are not actually used up in the reaction. They are used in industry to control the speed of reactions and to cut down the costs of producing chemicals. Though catalysts are mostly used to speed up reactions, they can also be used to slow them down. A catalyst that slows down the rate of a reaction is called an inhibitor. There are many chemical reactions that occur in living things. These reactions need biological catalysts called enzymes to control them, otherwise they would occur much too slowly to keep the organism alive. Your body contains thousands of enzymes, each one controlling the speed of one particular reaction. EXOTHERMIC & ENDOTHERMIC Whenever there is a chemical reaction an energy change occurs. Energy is produced in some reactions, and is needed to start others. An exothermic reaction is one that releases energy. This energy is usually in the form of heat, but other forms of energy can also be produced. One of the most important exothermic reactions is combustion, or burning. 2 An endothermic reaction is where some form of energy must be supplied before the reaction will occur. They often result in the temperature of the reaction decreasing (i.e. it gets colder). An important endothermic reaction is photosynthesis, where plants need energy from the sun in order to make food for themselves. LAW OF CONSERVATION OF MASS The Law of Conservation of Mass states that “the total mass of the reactants is always equal to the total mass of the products”. What this means is that the number of atoms that take part in a chemical reaction is equal to the number of atoms in the products. No atoms are lost in the reaction – they are simply rearranged. For example when hydrogen peroxide decomposes into water and oxygen the following reaction occurs: 2H2O2 hydrogen peroxide 2H2O water + O2 oxygen There are 4 hydrogen atoms and 4 oxygen atoms on both sides of the equation, indicating that the law of conservation of mass has held true. SPELLING WORDS EASY 1 2 3 4 5 6 7 8 9 10 rate rusting burning product matter spaces forces faster contact energy EASY 11 12 13 14 15 16 17 18 19 20 area piece powder speed reactant change increase surface mass equal 1 2 3 4 5 6 7 8 9 10 3 HARD investigating reaction explosion temperature photosynthesis particles theory attraction collision energetically 11 12 13 14 15 16 17 18 19 20 HARD concentration combustion dilute catalyst inhibitor industry enzyme exothermic endothermic conservation