CACHE Modules on Energy in the Curriculum Fuel Cells Module Title: Natural Convection Cooling of a Fuel Cell Module Author: Zachary Edel and Abhijit Mukherjee Author Affiliation: Michigan Technological University Course: Heat Transfer Text Reference: Incropera et al., 2007, Fundamentals of Heat and Mass Transfer, Sixth Edition. Concepts: Newton’s Law of Cooling, Natural Convection Correlations Problem Motivation: Fuel cells are a promising alternative energy technology. One type of fuel cell, a proton exchange membrane fuel cell reacts hydrogen and oxygen together to produce electricity. Fundamental to the design of fuel cells is an understanding of heat transfer mechanisms within fuel cells. Heat removal from fuel cells is critical to their scaleup for large power applications. Consider the schematic of a compressed hydrogen tank feeding a proton exchange membrane fuel cell, as seen in the figure below. The electricity generated by the fuel cell is used here to power a laptop computer. We are interested in analyzing heat transfer within the fuel cell, which involves the determination of heat transfer coefficients, thermal conductivities, and temperatures at certain locations within the fuel cell. Computer (Electric Load) H2 feed line Air in Anode Gas Chamber Cathode Gas Chamber Air / H2O out H2 out H2 tank 1st Draft Fuel Cell Z.J. Edel Page 1 December 21, 2009 Problem Background: Empirical correlations for free convection are generally of the form: hL n C Ra L k NuL Where the Rayleigh number is given by: g Ts T L3 Ra L And L is the characteristic length of the flow geometry and depends on the orientation of the convecting surface. All fluid properties are evaluated at the film temperature: Tf Ts T 2 The Vertical Plate: Typically for laminar flow ( 104 ≤ RaL ≤ 109 ), C = 0.59 and n 1 4 and for turbulent flows ( 109 ≤ RaL ≤ 1013 ), C = 0.10 and n 13 . Slightly better accuracy can be achieved for laminar flow, however, if the following correlation is used: hL 0.670Ra L 4 NuL 0.68 4 492 16 9 k 9 1 0.Pr 1 RaL ≤ 109 The characteristic length scale for this orientation is the vertical height of the plate. The Horizontal Plate: The characteristic length scale for a horizontal plate is defined as Lc As P Where As is the plate surface area and P is the plate perimeter. The Nusselt number correlations for the horizontal plate depend upon both the orientation of the surface in question and whether the surface is hotter or colder than the ambient medium. For the top surface of a cold plate, the flow descends over the plate much like a flat surface in a wind tunnel. For the bottom surface of a cold plate, the fluid circulates due to the descending air near the plate displacing volume and drawing ambient air into the region close to the plate. The conditions are exactly reversed for a hot plate in a cool atmosphere; the top surface circulates air due to the rising of the heated fluid and the bottom surface pushes air past it like the top surface of a cool plate. Upper Surface of Hot Plate or Lower Surface of Cold Plate: NuL 1st Draft 1 hL 0.54 Ra L 4 k Z.J. Edel Page 2 ( 104 ≤ RaL ≤ 107 ) December 21, 2009 NuL 1 hL 0.15Ra L 3 k ( 107 ≤ RaL ≤ 1011 ) Lower Surface of Hot Plate or Upper Surface of Cold Plate: NuL 1 hL 0.27 Ra L 4 k ( 105 ≤ RaL ≤ 1010 ) Problem Information Example Problem Statement: The temperature of a 7-Watt, single fuel cell is regulated by natural convection heat transfer to surrounding air at 20oC. The fuel cell consists of a Membrane Electrode Assembly (MEA) and two gas distribution plates. Each square, graphite plate has an active area of 50 cm2; the MEA can be neglected for this problem. The fuel cell operates at a steady-state temperature of 80oC. A) B) What is the average heat transfer coefficient? What is the total heat dissipation due to natural convection from the distribution plates when the fuel cell is oriented vertically? Example Problem Solution: Fluid: Air, T∞ = 20oC, Tss = 80oC Film Temperature: T T 353K 293K Tf s 323K 2 2 Properties of Air at 323 K: ν = 18.20 x 10-6 m2/s α = 25.9 x 10-6 m2/s Pr = 0.704 k = 28.0 x 10-3 W/m-K β = 1/323K = 0.003096 K-1 Characteristic length for vertical plate: Lc = Aside1/2 = 7.071 cm A) Ra L g Ts T L3 9.81 0.003096K 353K 293K 0.07071m 1 3 s2 18.20 106 m s 25.9 106 m s < 109 → Laminar Flow Ra L 1.366 x 106 2 NuL 0.68 1st Draft m 0.670 Ra L 1 0.492 Pr 9 1 0.6701.366 106 4 1 4 4 16 2 9 0.68 Z.J. Edel Page 3 1 0.492 0.704 9 4 16 9 December 21, 2009 NuL hnat hL 18.24 k NuL k 18.24 28.0 103 W mK 0.0707 L hnat 7.224 W mK B) qtot hnat Atot Ts T 7.224 W m2K 2 50cm 100m2 cm2 353K 293K 2 qtot 4.334W 1st Draft Z.J. Edel Page 4 December 21, 2009 Home Problem Statement: The temperature of a 25-Watt, single fuel cell is regulated by natural convection heat transfer to surrounding air at 20oC. The fuel cell consists of a Membrane Electrode Assembly (MEA) and two gas distribution plates. Each square, graphite plate has an active area of 150 cm2; the MEA can be neglected for this problem. The fuel cell operates at a steady-state temperature of 80oC. A) What is the average heat transfer coefficient due to natural convection from the top surface and the bottom surface of the distribution plates when the fuel cell is oriented horizontally? B) Calculate the heat transfer rate in Watts for the top and bottom surfaces of the distribution plates. 1st Draft Z.J. Edel Page 5 December 21, 2009