One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 1 of 8
MATERIAL SAFETY DATA SHEET (MSDS)
SECTION1 - PRODUCT INFORMATION
Product under
brand:
ONE-COMPONENT Polyurethane Insulating Foam Sealant
ONE-COMPONENT – HIGH YIELD Polyurethane Insulating Foam Sealant
ONE-COMPONENT - REUSABLE Polyurethane Insulating Foam Sealant
ONE-COMPONENT-PRO Polyurethane Insulating Foam Sealant
WINDOW AND DOOR Polyurethane Insulating Foam Sealant
TYTAN 65 HIGH YIELD – QUICK CURE Polyurethane Insulating Foam Sealant
WINTER - FOAM Polyurethane Insulating Foam Sealant
Date prepared 11/27/00
1.Manufacturer:
Orion Sp. z o. o. , 58-200 Dzierżoniów, ul. Pieszycka 4, Poland
2.Distibutor:
Selena Co. S.A. , ul. Powstańców Śl. 95, 53-332 Wrocław, Poland
3.Emergency and MSDS
+48 71/ 780 51 90
4.MSDS prepared by :
Selena Co. S.A. ul. Powstańców Śl. 95, 53-332 Wrocław, Poland
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 2 of 8
SECTION 2 –COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT
WT.%:
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
MDI
4,4 diphenylmethane diisocyanate
9016-87-9
30-40
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
Polyether Poly Blend
Polyether Poly Blend
confidential
20-40
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
Propan
Propan
74-98-6
3-10
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
Butan
Butan
106-97-8
3-10
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
Izobutan
Izobutan
75-28-5
3-10
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
dimethyl ether
DME
115-10-6
5-15
CHEMICAL NAME:
COMMON NAME:
CAS NUMER:
1,1,1,2 tertafluoroethane
tetrafluoroethane
811-97-2
5-10
SECTION 3 – HAZARDS IDENTIFICATION
Primary route(s) of exposure: inhalation, skin contact, eye contact, ingestion.
INHALATION:
Prolonged inhalation may lead to mucous membrane irritation, fatigue,
dizziness and/or lightheadedness, headache, nausea,
vomiting, chest pain, central nervous system depression,
difficulty of breathing, allergic responds, asthmatic reaction,
convulsion, loss of consciousness, asphyxiation, death.
Possible sensitization to respiratory tract.
SKIN CONTANT
Irritation of skin. Prolonged or repeated contact can cause blistering,
allergic response, severe skin irritation or burns. Possible sensitization
to skin.
EYE CONTACT
Irritation of eyes. Prolonged or repeated contact can cause
conjunctivitis, blurred vision, tearing of eyes, redness of eyes,
corneal injury.
INGESTION
Ingestion may cause mouth and throat irritation, mucous
Membrane irritation, nausea, vomiting, diarrhea, abdominal
pain, blood abnormalities.
MEDICAL CONDITION AGGRAVATED BY EXPOUSURE NOT AVAILABLE
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 3 of 8
SECTION 4 – FIRST AID MEASURES
INHALATION:
SKIN CONTACT:
EYE CONTACT:
INGESTION:
Remove to fresh air. Restore or support continued breathing.
Get emergency medical help. Have trained person give oxygen if
necessary .Get medical help in any breath difficulty.
Use a cloth to remove excess foam from skin and remove
contaminated clothes immediately. Use a mild solvent, such as
acetone or mineral spirits, to facilitate removing uncured foam
residue from clothing and other surfaces (avoid contact with
eyes). Cured foam may be physically removed by persistent
washing with soap and plenty of water.
If irritation develops, use mild skin cream. If symptoms persist, in
case of redness seek medical attention.
Flush immediately with large amount of water for at least
15 minutes. If irritation or other under effects persist, obtain
medical treatment.
If swallowed, obtain medical treatment immediately.
SECTION 5 – FIRE-FIGHTING MEASURES
FLASH POINT (SETA)
LOWER EXPLOSIVE LIMIT
UPPER EXPLOSIVE LIMIT
FIRE EXTINGUISHING MEDIA:
-4 F
1.8%
8.4%
Carbon dioxide, dry chemical, foam, water fog.
INUSAL FIRE AND EXPLOSION HAZARDS:
Closed container may explode when exposed to extreme
heat or fire.
Vapors may ignite explosively at ambient temperatures.
Vapor are heavier than air and may travel long distances
to source of ignition and flash back.
May decompose under fire conditions emitting irritant
and/or toxic gases.
FIRE FIGTHTING PROCEDURES:
Water may be used to cool and protect exposed containers.
Firefighters should use full protective clothing, eye protection,
and self-contained breathing apparatus.
HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS:
Carbon monoxide, carbon dioxide, oxides of nitrogen,
hydrogen cyanide.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 4 of 8
SECTION 6 - ACCIDENTAL REALEASE MEASURES
SPILLED OR RELEASED MATERIAL:
Comply with all applicable health and environmental
regulation.
Eliminate all sources of ignition. Ventilate area with
explosion-proof equipment .Spills may be collected with
absorbent materials. Use non-sparking tools. Evacuate all
unnecessary personnel. Place collected material in proper
container. Small spills – use absorbent to pick up residue and
dispose.
CLEANING METHOD:
Uncured foam is very sticky so carefully remove the bulk of the
foam by scraping it up and immediately remove residue with a
cloth and solvents such as mineral spirits, acetone, paint thinner
etc. Once the foam has cured, it can only be removed
mechanically by scraping, buffing etc.
SECTION 7-HANDLING AND STORAGE
HANDLING AND STORAGE:
Store below 104F.Keep away from heat , sparks and open flame.
OTHER PRECAUSTION:
Use only with adequate ventilation. Do not take internally.
Keep out of reach of children. Avoid contact with skin and eyes,
And breathing of vapors. Wash hands thoroughly after handling,
Especially before eating or smoking. Keep containers tightly
closed and upright when not in use.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 5 of 8
SECTION 8 - EXPOSURE CONTROL / PERSONAL PROTECTION
COMMON NAME:
CAS NR:
ACGIH (TWA):
OSHA (SKIN):
MDI
9016-87-9
0.005 PPM
CEILING: 0.02 PPM
SUPP REC STD.: Not available
COMMON NAME:
CAS NUMER:
ACGHI (TWA)
Propan
74-98-6
2500 PPM
OSHA (TWA)
10000 PPM
COMMON NAME:
CAS NUMER:
ACGHI (TWA)
Butan
106-97-8
2500 PPM
OSHA (TWA)
10000 PPM
COMMON NAME:
CAS NUMER:
ACGHI (TWA)
Izobutan
75-28-5
2500 PPM
OSHA (TWA)
10000 PPM
RESPIRATORY PROTECTION:
Respiratory protection is required for use in isocyanate
containing environments. Consider type of application and
environmental concentration when selecting respiratory
protection. Observe governmental regulation for respiratory
use. The us of positive pressure supplied air respirator is
mandatory the airborne isocyanate concentrations are not
known. Note: Isocyanate based materials have been
determined to cause allergic sensation in humans. Avoid
inhalation and dermal (skin) contacts with the uncured
material.
VENTIALTION:
Provide dilution ventilation or local exhaust to prevent
Build-up of vapors. Use explosion- proof equipment.
Non-sparking equipments.
PERSONAL PROTECTIVE EQUIPMENTS:
Eye wash, safety shower, safety glasses or goggles.
Impervious gloves, clothing, apron.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 6 of 8
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Base
Color
Odor
Appearance
pH
Boiling range
Flash point
Self-flammability (solid/gas)
Vapour pressure
Relative density
Solubility in water
% volatile by volume
% solids per volume
aerosol
polyurethane
yellow
odorless when cured
foam
slightly alkaline
not available
-4Fbased on propellant (propane/butane)
over 750F
ca. 350 kPa. / 50 PSI
approx. 1,2 g/cm 3 (water = 1)
insoluble, reacts slowly with water during cure,
liberating traces of CO2.
20
80
SECTION 10 – STABILITY AND REACTIVITY
STABILITY:
REACTIVITY:
Under normal condition stable. See section 5 – FIRE FIGHTING
MEASURES.
Material to avoid: oxidizers, acids, base, amines, aluminum,
copper, alcohols, metal compounds.
Condition to avoid: elevated temperatures, contact with
Oxidizing agent, sparks, open flame, ignition sources.
Hazardous polymerization will not occur.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 7 of 8
SECTION 11 – TOXICOLOGICAL INFORMATION
COMMON NAME:
MDI
CAS NUMER:
9016-87-9
CARCINOGENICITY LISTED BY: NTP:NO IARC:NO OSHA:NO ACGIH:NO
oral rat, LD50: > 5000 mg/kg
Skin rat, LD50: > 5000 mg/kg
Inhalation rat, LD50 > 0,49 mg/l (4 hours)
COMMON NAME:
Polyether Poly Blend
CAS NUMER:
confidential
CARCINOGENICITY LISTED BY: NTP:NO IARC:NO OSHA:NO ACGIH:NO
COMMON NAME:
Propan
CAS NUMER:
74-98-6
CARCINOGENICITY LISTED BY: NTP:NO IARC:NO OSHA:NO ACGIH:NO
COMMON NAME:
Butan
CAS NUMER:
106-97-8
CARCINOGENICITY LISTED BY: NTP:NO IARC:NO OSHA:NO ACGIH:NO
COMMON NAME:
Izobutan
CAS NUMER:
75-28-5
CARCINOGENICITY LISTED BY: NTP:NO IARC:NO OSHA:NO ACGIH:NO
SUPPLEMENTAL HEALTH INFORMATION:
CARCINOGENICITY
Free diisocyanate may cause allergic reaction in susceptible
persons. Contains a polymeric blocked isocyanate. Free isocyanate
may be released at elevated temperatures during baking.Isocyanate
is highly toxic by inhalation. Overexposure to monomeric isocyanate
can cause severe eye and skin irritation, pulmonary and skin
sensitization.
Inhalation studies with polymeric MDI (diphenymethane
diisocyanate monomer) have shown that there is a statistically
significant increase in benign and malignant tumor of the lung
in experimental animals.
SECTION 12- ECOLOGICAL INFORMATION
No ecological testing has been done by Selena CO. S.A. on this product as whole.
SECTION 13 – DISPOSAL CONSIDERATION
WASTE DISPOSAL
Dispose in accordance with all applicable regulations.
Avoid discharge to natural waters.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl
One Component Expanding Polyurethane Foam Sealant
2000-11-27
Page 8 of 8
SECTION 14 – TRANSPORT INFORMATION
DOT
IMDG
ICAO / IATA
TOG
Consumer commodity ORM-D, Aerosol Expanding Foam
Aerosol, class 2.2, UN 1950, limited quantity
N/A
N/A
SECTION 15 - REGULATORY INFORMATION
CAS NR
9016-87-9
COMMON NAME:MDI
SARA
302
SARA
313
CERCLA
302.4
HAZ AIR
MARINE
POLLUTANT POL TNT
NO
YES
NO
NO
NO
As of the date of this MSDS , all of the components in this product are listed on TSCA inventory.
SECTION 16 – OTHER INFORMATION
DISCLAMER:
The information contained herein is based on data available as of the date of preparation of this
MSDS and which we believe to be reliable. However, no warranty is expressed or implied
regarding the accuracy of the data. We shall not be responsible for the use of this information,
or of any product, method, or apparatus mentioned, and the user must his own investigation to
determine the suitability of the information or products for his particular purpose, for the
protection of the environment, and the health and safety of the users of this material.
Selena Co. S.A. 53 332 Wrocław ul. Powstańców Śląskich 95 Poland
Tel. +1148 71 780 51 90 Fax. +1148 71 780 51 91 e-mail:export@selena.pl www.selena.pl