Revision 2003-04-04 Page 1/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ 1. Identification of the product and of the company --------------------------------------------------Identification of the product: Beer Pipe Cleaner Chlorinated detergent sanitiser Company/undertaking identification: Ecolab Ltd David Murray John Building Swindon Wiltshire SN1 1NH Telephone: 01793 511221 2. Composition/information on ingredients ----------------------------------------Declaration according to recommendation 89/542/EEC: Less than 5 %: chlorine-based bleaching agents, phosphonates Declaration of ingredients: 1 - 5 % Sodium hypochlorite Symbol: C R-phrase: 31-34 EINECS: 231-668-3 5 – 10 % Sodium hydroxide Symbol: C R-Phrases: R35 EINECS: 215-185-5 3. Hazards identification of the product ---------------------------------------R 31: Contact with acids liberates toxic gas R 35: Causes severe burns 4. First aid measures --------------------after inhalation: Fresh air, consult doctor if complaint persist. In case of unconsciousness bring patient into stable side position for transport. Revision 2003-04-04 Page 2/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ after skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes. after eye contact: Immediately flush eyes with copious amounts of running water (for 10 minutes), put on a bandage with sterile gauze, see an oculist. after ingestion: Rinse out mouth, drink 1-2 glasses of water. Do not initiate vomiting; instantly call for medical help. 5. Fire-fighting measures ------------------------Suitable extinguishing media: Non-combustible - danger of decomposition if exposed to heat. suitable for all regular extinguishing materials Extinguishing media which must not be used for safety reasons: none known Special exposure hazards arising from the product itself, from combustion products or from resulting gases: Can be released in case of fire: chlorine gas. Special protective equipment for firefighters: Put on breathing apparatus. 6. Accidental release measures -----------------------------Personal precautions: Avoid contact with skin and eyes. Ensure adequate ventilation. Escaping product causes danger of slipping. Environmental precautions: The product may not be allowed to enter water without prior treatment (biological waste treatment plant). Do not allow to enter in surface / ground water. Do not allow to enter the ground/soil. Methods of cleaning up/of removing: Remove with liquid-absorbing material (sand, peat, sawdust). wash away residue with plenty of water; Dispose of contaminated material as waste according to item 13. 7. Handling and storage ----------------------Handling: Open and handle container with care. Ensure good ventilation/suction at the workplace. Revision 2003-04-04 Page 3/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ Storage: Store in a cool, dry place, protected from heat. Do not keep together with acids in one container. Do not store together with oxidants. 8. Exposure controls / personal protection -----------------------------------------Information on the system design: Ensure good ventilation/suction. Components with specific control parameters: Sodium hydroxide OES (15 min.) 2mg/m3 Exposure at the working place can be excluded in normal processing procedures. Personal protection: Wash hands before work breaks and after finishing work. keep away from food, beverages and animal feed; Immediately remove soiled or soaked clothing. Respiratory protection: suitable breathing mask when there is inadequate ventilation Hand protection: Wear Category III (EN 374) chemical protective gloves made of butyl rubber or nitrile rubber. Please observe the glove manufacturer's instructions on permeability and rupture times as well as the specific workplace conditions. Eye protection: goggles which can be tightly sealed Skin protection: suitable protective clothing Safety shoes or closed footwear. 9. Physical and chemical properties ----------------------------------Physical state: Colour: Odour: liquid yellow chlorine pH: (undiluted) (20'C) > 13 Flash point: not applicable Relative density: (20'C) 1.18 g/cm3 Solubility: Soluble in water (20 'C) unlimited Revision 2003-04-04 Page 4/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ 10. Stability and reactivity ---------------------------Conditions to avoid: No decomposition if used according to specifications Materials to avoid: Do not use together with other cleaning agents. Cleanings agents containing hypochlorites release toxic gases which may damage the respiratory system. Reacts with acids: heat generated and chlorine released Hazardous decomposition products: In case of fire chlorine will be generated. 11. Toxicological information ----------------------------In case of appropriate application no adverse effects have been reported up to now. Skin contact: The product causes corrosion on skin and mucous membranes. Eye contact: strong corrosive effect Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach. 12. Ecological information -------------------------Based on the components contained in the product and/or structurally comparable substances the following ecological data are to be expected: Persistence and degradability: not pertinent: inorganic product The product contains active chlorine or active chlorine carriers, respectively. Locally set limits in sewage have to be observed. 13. Disposal considerations --------------------------Dispose of in accordance with Local Authority requirements e.g. delivery to designated station for disposal of chemical waste. Verify that procedure complies with local regulations. Revision 2003-04-04 Page 5/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ 14. Transport information ------------------------Transport over land ADR/RID: Class: 8 PG: III Classification Code: C5 1st numbering of tanks panel: 80 2nd numbering of tanks panel: 3266 Designation of goods: UN 3266 Corrosive liquid, basic, inorganic, n.o.s. (contains Sodium hydroxide and Sodium hypochlorite) Transport over sea IMDG: Class: 8 UN-No.: 3266 PG: III EmS: F-A, S-B Proper shipping name: Corrosive liquid, basic, inorganic, n.o.s. (contains Sodium hydroxide and Sodium hypochlorite) Transport by air ICAO/IATA: Class: 8 UN/ID-No.: 1791 PG: III Pkg-Instr. (passangerair.): 819 Pkg-Instr.(cargo air. only): 821 Proper shipping name: Corrosive liquid, basic, inorganic, n.o.s. (contains Sodium hydroxide and Sodium hypochlorite) 15. Regulatory information -------------------------Classification and labelling according to CHIP: Symbols of danger: C Corrosive Ingredients: Sodium hydroxide, Sodium hypochlorite solution R-phrases: R 31: Contact with acids liberates toxic gas R 35: Causes severe burns S-phrases: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S 28: After contact with skin, wash immediately with plenty of water and soap S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Revision 2003-04-04 Page 6/ 6 Safety Data Sheet according to 91/155/EEC - ISO 11014-1 Beer Pipe Cleaner ________________________________________________________________________ National prescriptions: The Control of Substances Hazardous to Health Regulations Health and Safety at Work Act 16. Other information --------------------The product is provided for the professional user. This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Full text of the R-phrases indicated by codes in this safety data sheet. The product code/identification/designation is indicated in Section 15. R 31: Contact with acids liberates toxic gas. R 34: Causes burns R 35: Causes severe burns